首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   422篇
  免费   26篇
  国内免费   27篇
化学   225篇
晶体学   13篇
力学   28篇
数学   119篇
物理学   90篇
  2024年   1篇
  2023年   2篇
  2022年   8篇
  2021年   11篇
  2020年   9篇
  2019年   19篇
  2018年   10篇
  2017年   21篇
  2016年   9篇
  2015年   9篇
  2014年   17篇
  2013年   61篇
  2012年   15篇
  2011年   22篇
  2010年   20篇
  2009年   13篇
  2008年   27篇
  2007年   25篇
  2006年   16篇
  2005年   14篇
  2004年   17篇
  2003年   28篇
  2002年   11篇
  2001年   6篇
  2000年   12篇
  1999年   12篇
  1998年   7篇
  1997年   10篇
  1996年   8篇
  1995年   6篇
  1994年   8篇
  1993年   4篇
  1992年   3篇
  1991年   3篇
  1990年   2篇
  1989年   1篇
  1988年   1篇
  1987年   2篇
  1986年   1篇
  1983年   1篇
  1979年   3篇
排序方式: 共有475条查询结果,搜索用时 31 毫秒
131.
基于SEM研究了桥基断裂断层泥的原状显微结构和显微构造、石英碎砾的显微构造、表面刻蚀形貌和结构特征 ,并进一步分析和评价了断裂的抗震和抗断关键问题 ,其对系统论证在断裂带上建设特大型过江桥梁工程的稳定性具有重大实际意义 ,并为镇扬大桥工程的合理设计和安全运行提供了地质依据  相似文献   
132.
By selecting the appropriate spatial and temporal variables, physical abnormalities at the microscale can be limited to the essentials such that effective analytical solutions can be made available and identified with high resolution TEM and SEM micrographs. A catalogue of physical–analytical pairs can be stored electronically for the evolution of material damage from micro (or nano) up to macroscopic failure. High speed digital processing can organize such information and make forecast on potential failure in the cyberspace. The micro/macro line cracking model is used to illustrate the use of the PAM (physical–analytical matching) technique although it is still at the early stage of development. Three essential parameters describing the inhomogeneity of the material serve as the basis of the approach while specific microstructural details can be accounted for by using the incidental variables as programmed by PAM in the future. Demonstration is made by using the dual scale micro/macro line crack model where closed form asymptotic solution can be obtained from singularity representation. No generality is lost from the line crack configuration. This is analogous to taking the shape of an atom to be spherical since the exact shape is not relevant. The essential quantities are the energy density and characteristic length associated with the equivalent crack length defined with reference to the spatial and temporal variables under consideration.For a macroscopic tensile specimen containing a micro/macrocrack, multiple microcracking patterns are generated. A priori assumptions related to the grain geometries and/or cohesive force laws to create branching will not be made. Instead, values of the essential parameters are selected to obtain multiple minima of the volume energy density functions. These minima are very closely spaced. This implies that the initiation of multiple microcracking is probable even though dynamic effects are not present. This is in contrast to macrocrack branching where the crack velocity had to approach that of the Rayleigh wave speed. The formulation also shows that empirical approach blind folds the details of microscopic and scaling effects. The double singularity line crack model is used to illustrate that different multiple microcracking patterns can be predicted from the volume energy density fracture criterion that has been used extensively for examining the initiation of macrocracking. The criterion relies on identifying the locations of the stationary values of the energy density function with the potential threshold sites dominated by dilatation or distortion without assuming that the two energy density components are the linear sum, a condition invoked in linear elasticity. To reiterate, three essential parameters are defined to describe the non-homogeneous behavior of the material while two incidental variables are used for the double singularity line crack to account for specific microstructural effects. It is the ease with which asymptotic closed form solution can be obtained and identified with observed damage patterns that suggests the possibility to develop the PAM technique in the cyberspace.  相似文献   
133.
魏航信  吴伟  职黎光  贺冲 《应用声学》2014,22(6):1881-1883
针对游梁式抽油机平衡装置效果不理想的问题,设计了风光储联合供电的抽油机自动平衡装置;该装置由伺服电机驱动平衡块,根据油井工况实时调节其位置,实现抽油机的最佳平衡;针对平衡装置耗电量大的不足,设计了由风光储联合供电的模式,真正实现抽油机节能;最后,对该装置设计了模糊PD自适应控制器,由模糊控制器在线调节PD控制器参数;在实验室试验10 h,该装置可将抽油机平衡度从1.61减小到1.03以内,白天由太阳能电池供电,夜间由蓄电池供电,其电压从12 V降到9.3 V,表明供电系统完全能满足要求。  相似文献   
134.
Four methods including hydrothermal method, glycol‐hydrothermal method, microwave‐hydrothermal method and glycol‐microwave‐hydrothermal method were used to prepare magnesium oxide precursor by the reaction of MgSO4·7H2O with (NH4)2CO3. The composition, crystallinity, morphology, aspect ratio, yield, functional groups, atom distribution, and interplanar spacing of the sample were investigated by X‐ray diffraction (XRD), Scan Electron Microscope (SEM), Fourier Transform Infrared Spectroscopy (FT‐IR), and High Resolution Transmission Electron Microscope (HRTEM). The properties of Magnesium Oxide precursor were compared with each other. The results of FT‐IR and XRD showed that the crystals were all nesquehonite. However, it was shown by FT‐IR results that the crystals prepared by glycol‐microwave‐hydrothermal method contained OH and HCO3 groups, which indicated that the Mg(OH)(HCO3)·2H2O type crystals would be facilitated by this method. The glycol‐hydrothermal method can create high quality Magnesium Oxide precursor with a high degree of crystallinity, high purity, high aspect ratio, smooth surface, and good dispersibility.  相似文献   
135.
给出了单目标、单约束下三状态串联、并联系统中由选取重要度来提高系统可靠度的有效优化模型及算法,并进行了实例验证.  相似文献   
136.
This paper examines how three eighth grade students coordinated lower and higher dimensional units (e.g., composite units and pairs) in the context of constructing a formula for evaluating sums of consecutive whole numbers while solving combinatorics problems (e.g., 1 + 2 +  + 15 = (16 × 15)/2). The data is drawn from the beginning of an 8-month teaching experiment. The findings from the study include: (1) a framework for understanding how students coordinate lower and higher dimensional units; (2) identification of key learning that occurred as students made the transition between solving two kinds of combinatorics problems; and (3) identification of the links between the way students’ coordinated lower and higher dimensional units and their evaluation of sums of consecutive whole numbers. Implications for research and teaching are considered.  相似文献   
137.
Bifurcations of spatially nonhomogeneous periodic orbits and steady state solutions are rigorously proved for a reaction–diffusion system modeling predator–prey interaction. The existence of these patterned solutions shows the richness of the spatiotemporal dynamics such as oscillatory behavior and spatial patterns.  相似文献   
138.
The surface tension and fluorescence spectra of sodium octyl-[ω-octyloxy-poly(oxyethylene)]-yl-benzene sulfonates (APEnBS) aqueous solutions have been investigated by Wilhelmy plate method and intrinsic probe methods, respectively to study the effect of EO units on their properties. It was discovered that the surface performance of these surfactants was greatly outstanding: the values of critical micelle concentration (CMC) reached to be of the order of magnitude of 10?5 mol/L, the values of surface tension at CMC, γCMC, were between 25.79 to 31.02 mN/m, and the effectiveness and efficiency of surface tension reduction were excellent. The introduction of oxyethylene units to the surfactant molecule evidently improved the solubility of APEnBS. With the increase in EO units, the CMC slightly changed after the first decreased. On the other hand, the surface excess concentration at saturation, Γ max, decreased after the first increased and γCMC increased after the first decreased accordingly. The CMC determined by fluorescence spectra of intrinsic probe method were accorded with the CMC measured by surface tension method. The aggregation number N, characterized by quenching the fluorescence spectra with methyl viologen (MV2+) as the extrinsic quencher, gradually decreased first (from 0 to1) and then slightly changed (from 1 to 4) with increasing EO chain length. So we concluded that the appropriate number of EO units was the key factor to get the best physicochemical properties of APEnBS.  相似文献   
139.
Symmetrical liquid crystal dimers bis{2-alkyl-(S)-(+)-2-(6-[4-4′-decyloxyphenylazo)-benzoyloxy]-2-naphthyl)propinate} have conveniently been designed, synthesised and their mesomorphic properties were investigated. These dimers possess two identical mesogenic units with each of them attached to the terminal end of a flexible spacer (–C n H2n ; where n = 6–10). The respective mesogenic unit was made up from a naphthyl ring attached to the alkyloxylated azobenzene via the ester (COO–) bond. The chiral moiety attached to the 6-position of the naphthyl ring possesses a terminal carboxylic group COO– which linked up the mesogenic unit and the spacer. The thermal and optical properties for the ultimate compounds at different temperature were studied explicitly with the aids of differential scanning calorimetry and polarising optical microscopy. All dimers exhibit unambiguously the monotropic nematic and smectic A phases. The homeotropic alignment of the molecules within the anisotropic region was further confirmed through the application of homogeneously treated cell.  相似文献   
140.
Thermal decomposition of plasma-polymerized hexamethyl-cyclotrisilazane (PP-HMCTSN) thin films was studied by using various techniques. Pyrolysis-gas chromatography investigation of thermal decomposition products and IR examination of the polymer films showed that methylsilyl groups present in the monomer were highly susceptible to form disilymethylene and disilyethylene cross-linkages under plasma conditions. A three-stage mechanism of the thermal decomposition found by thermogravimetry proved a great complexity of the thermal reactions which occur during this process and, in turn, provided strong evidence for a very complex structure of plasma polymer. Electron microscopy investigation revealed a marked effect of the thermal decomposition process on the film microstructure. The trend observed in the morphological changes was consistent with kinetics of this process. The high temperature thermal treatment reduced the organic content of polymer film, correspondingly increasing its inorganic character. Films produced with this process were of unusually interesting properties, displaying strong adhesion to metal substrates and high resistance to corrosive agents.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号