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951.
Photochemical kinetics for holographic grating formation in phenanthrenequinone doped poly (methyl methacrylate) photopolymer
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The photochemical kinetics of phenanthrenequinone (PQ) doped poly
(methyl methacrylate) photopolymer in holographic recording was
studied theoretically and experimentally. The diffusion of PQ
molecules during holographic recording was negligible because of its
small diffusion coefficient at room temperature. A photochemical
reaction kinetics model of PQ/PMMA was established. The analytical
expressions for the temporal variations of transmittance and
diffraction efficiency were derived. By fitting the experimental
curves, some parameters related with the polymer components were
obtained by the proposed model, which can be used to analyze the
photochemical process and will be helpful to the optimization of
material preparation. 相似文献
952.
P. M. Kochergin I. A. Mazur G. K. Rogul'chenko E. V. Aleksandrova B. E. Mandrichenko 《Chemistry of Heterocyclic Compounds》2000,36(12):1437-1440
We have synthesized imidazo[1,2-a]pyrimidine derivatives by reaction of 2-aminopyrimidines with methyl aryl ketones and halogens (bromine, iodine). Using bromine leads to formation of 6-bromo- and 3,6-dibromo-substituted 2-arylimidazo[1,2-a]pyrimidines. 相似文献
953.
Xin‐Ping Hui Heng‐Shan Dong Peng‐Fei Xu Zi‐Yi Zhang Qin Wang Yan‐Ni Gong 《中国化学会会志》2000,47(5):1115-1119
The condensation of 4‐amino‐5‐mercapto‐3‐(2‐phenylquinolin‐4‐yl)/3‐(1‐p‐chlorophenyl‐5‐methyl‐1,2,3‐triazol‐4‐yl)‐1,2,4‐triazoles 1a‐b with chloroacetaldehyde 2a‐b , ω‐bromo‐ω‐(1H‐1,2,4‐triazol‐1‐yl)acetophenone 3a‐b , chloranil 4a‐b , 2‐bromocyclohexanone 5a‐b , 2,4′‐dibromoacetophenone 6a‐b and 2‐bromo‐6′‐methoxy‐2′‐acetonaphthone 7a‐b are described. The structures of the compounds synthesized were confirmed by elemental analyses, IR, 1H NMR and mass spectra. The antibacterial activities were also evaluated. 相似文献
954.
A series of novel N-[(α)-(isoflavone-7-O-)acetyl] amino acid methyl esters were prepared from the efficient and regioselective alkylation of isoflavones with chloroacetyl amino acid derivatives under mild condition. 相似文献
955.
956.
957.
在0~100℃温度范围内,由原子转移自由基聚合方法,采用助催化和非助催化体系,引发甲基丙烯酸甲酯聚合,利用13CNMR测定聚甲基丙烯酸甲酯的等规度.发现原子转移自由基聚合仍以间同立构为主,随着聚合温度的升高间同立构等规度降低,与通常自由基聚合对有规立构控制特征相似.助催化剂异丙醇铝和活性端羰基配位,对聚合物的立构规整性有一定的影响. 相似文献
958.
用活性炭吸附环境空气中的丙烯酸乙酯和甲基丙烯酸甲酯,经二硫化碳妥吸后用气相色谱法测定在填充2.5%DNP+2.5%Bentone34/ChromosorbW HP DMCS的玻璃色谱柱上,丙烯酸乙酯与甲基丙烯酸甲酯及干扰物之间能较好地分离。方法的回收率:丙烯酸乙酯为86.4%-103.0%,甲基丙烯酸甲酯为86.3%-101.2%,变异系数:丙烯酸乙酯为4.1%-4.4%,甲基丙烯酸甲酯为4.4% 相似文献
959.
Balakrishna Kolli Someshwarnath Pandey Sarada P. Mishra Tapan Kanai Mukesh P. Joshi Raj S. Mohan Tham Singh Dhami Lalit Mohan Kukreja Asit Baran Samui 《Journal of polymer science. Part A, Polymer chemistry》2013,51(20):4317-4324
Main chain polymers containing azo and bisbenzylidene moiety were synthesized by polycondensation method. The successful polymerization reaction was characterized by UV–vis absorption, FT‐IR and NMR spectroscopy. The resulting polymers were soluble in polar solvents like dimethyl formamide (DMF) and showed good thermal stability up to 250 °C. These polymers were blended with poly methyl methacrylate (PMMA) and corona poled for characterizing second harmonic generation (SHG) property. Temperature stability study of SHG intensity of poled polymer showed that it is stable up to 80 °C. To improve temperature stability further the crosslinking of polymer under UV light is proposed. © 2013 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2013, 51, 4317–4324 相似文献
960.
《Journal of Coordination Chemistry》2012,65(20):3620-3626
A new tri-functional ligand iBu2NCOCH2SOCH2CONiBu2 was prepared and characterized. The coordination chemistry of this ligand with uranyl nitrate was studied with IR, 1H NMR, electrospray mass–spectrometry, thermogravimetry, and elemental analysis. The structure of [UO2(NO3)2(iBu2NCOCH2SOCH2CONiBu2)] was determined by single-crystal X-ray diffraction. The uranium(VI) ion is surrounded by eight oxygens in a hexagonal bipyramidal geometry. Four oxygens from two nitrates and two oxygens from the ligand form a planar hexagon. The ligand is a bidentate chelate, bonding through sulfoxo and one of the carbamoyl groups to uranyl nitrate. 相似文献