Heat of adsorption and density distribution in slit pores with defective walls: GCMC simulation studies and comparison with experimental data

The adsorption behavior (capacity, density distribution and packing density) and the isosteric heat versus loading in a slit pore whose walls contain defective graphene layers are investigated in this paper. The defective wall is characterized by the extent and size of the defect. Simulation results obtained with the Grand Canonical Monte Carlo method reveal complex patterns of isosteric heat, and this complex behavior is a result of the interplay between three factors: (i) the surface heterogeneity (solid-fluid interaction, sites with varying degree of affinity), (ii) fluid-fluid interaction and (iii) the overlapping of potentials exerted by the two defective walls. We illustrate this with argon adsorption in pores of various sizes, and results obtained from the simulation agree qualitatively with the experimental data at 77 K on Saran microporous S600H and micro-mesoporous S84 charcoals of Beebe et al. [R.A. Beebe, B. Millard, J. Cynarski, J. Am. Chem. Soc. 75 (1953) 839]. The S600H was found to contain pores predominantly in the neighborhood of 7 Å with 30% of defect and a defective size of 2.84 Å. This is consistent with the argument made by Beebe et al. that this sample is a microporous solid and most pores can accommodate only one layer. The other sample, S84, has larger pores than S600H, and it is found that it has a wider pore size distribution and the pore width is centered at about 12 Å.     

Modeling and characterization of fiber Bragg grating for maximum reflectivity

This paper presents the modeling and characterization of an optical fiber grating for maximum reflectivity. Grating length and change in refractive index are the critical parameters in contributing to the performance of fiber Bragg grating. The wavelength chosen for analysis is from the third window to minimize the attenuation. The reflection spectra, bandwidth and side lobes strength were analyzed with different lengths and change in refractive index. The simulations are based on solving coupled mode equations by transfer matrix method that describes the interaction of guided modes.     

基于Matlab/Simulink的电压型超导储能功率调节控制仿真

本文首先对电压型超导储能（Voltage-Superconducting-Magnet-Energy-Storage,简称VSMES）功率调节系统（Power-Conditioning-System,简称PCS）的原理进行介绍,并运用Matlab/Simulink仿真分析软件,针对三相电压型超导储能功率调节系统的控制过...     

基于GUI的阿贝-波特滤波实验的计算机仿真

介绍了阿贝-波特空间滤波的实验原理,在Matlab环境下建立了带有图形用户界面（GUI）的计算机仿真平台.不仅可以准确地完成针对不同输入图像、不同滤波要求的滤波过程,还可以通过调整滤波器参数观察滤波效果的差异,形象地展现光学空间滤波过程的物理本质,提高教学效果.     

LabVIEW与Matlab在信息光学教学中的应用

计算机仿真技术已经被广泛应用到教学和科研中.将LabVIEW和Matlab引入信息光学课程教学中,通过设计相关的程序,可使复杂的物理理论以形象直观的实验仿真表现出来.经过实践证明,该措施可提高学生的学习兴趣和教学质量.     

高温超导磁悬浮列车视景仿真系统

文中介绍研究开发的高温超导磁悬浮车的视景仿真系统.首先研究了视景仿真的体系结构,接着用3DMAX构建了视景仿真的三维场景,然后根据高温超导磁悬浮车的运行特性建立仿真所用的simulin模型,最后用过Visual C++编制用户界面.演示结果表明,该系统能较好地展示了世界上首辆载人高温超导磁悬浮车及其在轨道上的运行情况和...     

Determination of depth-of-focus in lensless in-line digital particle holography

Lensless in-line digital particle holography (DPH) can be thought of as a special case of photography, and its depth of focus (DoF) characteristics combine those of both photography and holography. The effect of important parameters such as the pixel size and the number of pixels in a charge-coupled device (CCD), the object's distance, the wavelength of the laser, and the particle diameter on the DoF of a reconstruction image in lensless in-line DPH was investigated using simulation holograms. The DoF is directly proportional to the object distance and the particle size. As the wavelength of the laser increases, the DoF decreases. The DoF is inversely proportional to the pixel size and to the number of pixels in a CCD. Instead of expressing nonspecific proportional relationships for DoF, the DoF prediction equations for typical CCD cameras were obtained using DoF data from many simulation holograms and efficient data-fitting software. Finally, the DoF prediction equations were verified using real holograms from a calibration target for several cases. Good agreement between measured and predicted values was confirmed.     

Super S_(25)与New S_(25)光电阴极的光谱响应特性的数值模拟

根据多碱光电阴极的光谱响应理论表达式 ,对荷兰DEP公司和日本Hamamatsu公司美国分公司开发的两种SuperS2 5阴极的光谱响应曲线进行了理论模拟 ,得到了这些阴极的有关特性参量 ,并通过对模拟结果的分析以及与美国夜视实验室研制的NewS2 5光电阴极特性的比较 ,揭示了两种SuperS2 5光电阴极内在机理和可能采用的工艺处理方法 ,对多碱光电阴极的理论研究和实际操作具有指导意义     

Standing waves, clustering, and phase waves in 1D simulations of kinetic relaxation oscillations in NO+NH3 on Pt(1 0 0) coupled by diffusion

The Lombardo–Imbihl–Fink (LFI) ODE model of the NO+NH₃ reaction on a Pt(1 0 0) surface shows stable relaxation oscillations with very sharp transitions for temperatures T between 404 and 433 K. Here we study numerically the effect of linear diffusive coupling of these oscillators in one spatial dimension. Depending on the parameters and initial conditions we find a rich variety of spatio-temporal patterns which we group into four main regimes: bulk oscillations (BOs), standing waves (SW), phase clusters (PC), and phase waves (PW). Two key ingredients for SW and PC are identified, namely the relaxation type of the ODE oscillations and a nonlocal (and nonglobal) coupling due to relatively fast diffusion of the kinetically slaved variables NH₃ and H. In particular, the latter replaces the global coupling through the gas phase used to obtain SW and PC in models of related surface reactions. The PW exist only under the assumption of (relatively) slow diffusion of NH₃ and H.     

Classical Molecular Dynamics Model for Coupled Two‐Component Plasmas – Ionization Balance and Time Considerations

The dynamic properties of ion‐electron two‐component plasmas (TCP) are studied by using classical molecular dynamics (MD) simulations. There is a variety of time dependent and structural results that MD is able to provide in complement to other methods, e.g., useful micro‐field sequences can be generated. The method deals with some specific difficulties: the mass ratio between ions and electrons enforces very small time‐steps appropriate to follow electrons motion while, ions must move significantly in order to build, self consistently, their spatial structure. This results in expensive simulations. Electron trajectories are trapped and de‐trapped with multiple electron collisions around ions resulting in the occurrence of quasi metastable bound electron states. An analysis of micro‐fields at neutral in a hydrogen plasma reveals the need to consider a complete hierarchy of time scales extended typically over 7 order of magnitude, i.e., from a time‐step: ～10^‐19s, to a time required to obtain statistical averages, ～10^‐11s. In order to extend the MD capabilities in representing real coupled plasmas a classical ionization/recombination process has been implemented allowing to follow the evolution of plasmas involving several ion stages and model the ionization balance. Here again TCP simulations deal with extended time‐scale providing information about relaxation of non equilibrium plasma states (© 2011 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)