Surface properties of silica gel samples modified by selected proteins

The adsorption of a polar (water) and a non-polar (n-octane) liquid on silica gels, modified by adsorption of proteins, has been studied by thermal analysis. Silica gels with physically adsorbed BSA and ovalbumin layers were used. Thermodesorption energies were determined from Q-TG and Q-DTG curves recorded under quasi-equilibrium conditions. Significant differences in liquid desorption were observed from the surfaces due to heterogeneous changes (energetic and geometrical) as a result of modification. These results are compared with those obtained for the samples heated at 160°C for 1 h.     

Nonnormality and stochastic differential equations

A highly nonnormal Jacobian may give rise to large transients. This behaviour has been shown to have implications for (a) the relevance of linearising a nonlinear system and (b) the timestep restrictions required to keep a numerical method stable. Here, we show that nonnormality also manifests itself for stochastic differential equations. We give an example of a family of systems that is stable without noise, but can be made exponentially unstable in mean-square by a noise perturbation that shrinks to zero as the nonnormality increases. We then show via finite-time convergence theory that an Euler approximation shares the same property, giving a discrete analogue of the result. In memory of Germund Dahlquist (1925–2005).AMS subject classification (2000) 65C30, 34F05     

Transfer processes in fractal media

An irreversible process in fractal media involves coupling relation between the space and the time. The present note displays how the fractional derivation has to be introduced to describe this effect. As a result the law of the chemical diffusion to a fractal is given.     

Charge orderings in the atomic limit of the extended Hubbard model

The extended Hubbard model in the atomic limit (AL-EHM) on a square lattice with periodic boundary conditions is studied with use of the Monte Carlo (MC) method. Within the grand canonical ensemble the phase and order-order boundaries for charge orderings are obtained. The phase diagrams include three types of charge ordered phases and the nonordered phase. The system exhibits very rich structure and shows unusual multicritical behavior. In the limiting case of t_ij=0, the EHM is equivalent to the pseudospin model with single-ion anisotropy , exchange interaction W in an effective magnetic field . This classical spin model is analyzed using the MC method for the canonical ensemble. The phase diagram is compared with the known results for the Blume-Capel model.     

Fractality feature in incompressible three-dimensional magnetohydrodynamic turbulence

Direct Numerical Simulation (DNS) of decaying isotropic 3D magnetohydrodynamic (MHD) turbulence based on the 10243-modes in a periodic box is used to study the statistical properties of turbulence. In this paper, the presence of intermittency in MHD turbulence is investigated through the analysis of the Probability Distribution Function (PDF) for Elsässer fields and total energy fluctuations. We observe that the PDFs of the Elsässer fields fluctuations display a strong non-Gaussian behavior at small scale, which can be ascribed to multifractality feature, while the PDFs of the total energy fluctuations have the same shape over all observed scales and are monofractal. The PDFs have stretched exponential tail and satisfy the function P(|δX|) ～ exp(?A|δX| ^μ ). Numerically, we extract the exponent μ and find that it is constant for monofractal behavior as the length scale varies. To check the notion of self-similarity in the respective fluctuation, we apply the compensated structure functions.