全文获取类型
收费全文 | 1038篇 |
免费 | 76篇 |
国内免费 | 60篇 |
专业分类
化学 | 672篇 |
晶体学 | 57篇 |
力学 | 8篇 |
综合类 | 2篇 |
数学 | 1篇 |
物理学 | 434篇 |
出版年
2023年 | 7篇 |
2022年 | 8篇 |
2021年 | 15篇 |
2020年 | 24篇 |
2019年 | 27篇 |
2018年 | 21篇 |
2017年 | 24篇 |
2016年 | 31篇 |
2015年 | 41篇 |
2014年 | 46篇 |
2013年 | 112篇 |
2012年 | 39篇 |
2011年 | 75篇 |
2010年 | 43篇 |
2009年 | 76篇 |
2008年 | 76篇 |
2007年 | 83篇 |
2006年 | 77篇 |
2005年 | 50篇 |
2004年 | 60篇 |
2003年 | 57篇 |
2002年 | 38篇 |
2001年 | 37篇 |
2000年 | 19篇 |
1999年 | 13篇 |
1998年 | 6篇 |
1997年 | 18篇 |
1996年 | 11篇 |
1995年 | 12篇 |
1994年 | 10篇 |
1993年 | 4篇 |
1992年 | 4篇 |
1991年 | 3篇 |
1990年 | 3篇 |
1987年 | 1篇 |
1985年 | 1篇 |
1982年 | 1篇 |
1981年 | 1篇 |
排序方式: 共有1174条查询结果,搜索用时 203 毫秒
111.
Direct- and pulse-current (DC and PC) chromium electroplating on Cr-Mo steel were performed in a sulfate-catalyzed chromic acid solution at 50 °C using a rotating cylinder electrode (RCE). The electroplating cathodic current densities were at 30, 40, 50 and 60 A dm−2, respectively. The relationship between electroplating current efficiency and the rotating speed of the RCE was studied. The cross-sectional microstructure of Cr-deposit was examined by transmission electron microscope (TEM). Results showed that DC-plating exhibited higher current efficiency than the PC-plating under the same conditions of electroplating current density and the rotating speed. We found the critical rotating speed of RCE used in the chromium electroplating, above this rotating speed the chromium deposition is prohibited. At the same plating current density, the critical rotating speed for DC-plating was higher than that for PC-plating. The higher plating current density is, the larger difference in critical rotating speeds appears between DC- and PC-electroplating. Equiaxed grains, in a nanoscale size with lower dislocation density, nucleate on the cathodic surface in both DC- and PC-electroplating. Adjacent to the equiaxed grains, textured grains were found in other portion of chromium deposit. Fine columnar grains were observed in the DC-electroplated deposit. On the other hand, very long slender grains with high degree of preferred orientation were detected in PC-electroplated deposit. 相似文献
112.
J.-F. Colomer L. Henrard Ph. Lambin G. Van Tendeloo 《The European Physical Journal B - Condensed Matter and Complex Systems》2002,27(1):111-118
The atomic structure of single-wall carbon nanotube bundles produced by three different techniques (laser ablation, electric
arc discharge and catalytic chemical vapor deposition (CCVD)) has been characterized by electron diffraction and microscopy.
Information on the helicity and the lattice packing has been obtained. Concerning the helicity, small bundles produced by
CCVD exhibit only one or two tube helicities within a single bundle. The diffraction patterns of laser-ablation produced bundles
also present well-defined but more diversified chiralities within a single bundle. By contrast the data acquired on bundles
formed by arc discharge show a more diffuse pattern, characteristic of a random chirality dispersion within a single bundle.
Concerning the lattice packing, informations are obtained via a detailed study of the equatorial line of the diffraction pattern for bundles produced by the three techniques. This electron
diffraction study is completed by high-resolution electron microscopy.
Received 8 August 2001 and Received in final form 14 March 2002 相似文献
113.
Adriana Boschetti‐de‐Fierro Daniel Fierro Julio Albuerne Sérgio S. Funari Volker Abetz 《Journal of Polymer Science.Polymer Physics》2007,45(23):3197-3206
The bulk morphology of poly(1,4‐butadiene)–block–polystyrene–block–poly (ethylene oxide) (PB‐b‐PS‐b‐PEO) and polyethylene–block–polystyrene–block–poly (ethylene oxide) (PE‐b‐PS‐b‐PEO) triblock terpolymers is analyzed under a thermal protocol. This allows the investigation of the morphology during the occurrence of thermal transitions, such as crystallization and melting, which is a neat way of studying the competition between microphase separation and crystallization for the morphology formation. Only one of the studied systems presented a morphological transition upon melting of the PEO and the PE blocks, attributed to the crystallization of the PE block in finite interconnected domains. All the other systems presented no morphological transitions during the thermal scan. The results prove that the crystallization only disrupt the microphases generated in the molten state under very specific circumstances for these block copolymers. © 2007 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 3197–3206, 2007 相似文献
114.
J.D. Song W.J. Choi J.I. Lee J.Y. Lee 《Physica E: Low-dimensional Systems and Nanostructures》2006,32(1-2):115
We report structural and optical properties of In0.5Ga0.5As/GaAs quantum dots (QDs) in a 100 Å-thick In0.1Ga0.9As well grown by repeated depositions of InAs/GaAs short-period superlattices with atomic force microscope, transmission electron microscope (TEM) and photoluminescence (PL) measurement. The QDs in an InGaAs well grown at 510 °C were studied as a function of n repeated deposition of 1 monolayer thick InAs and 1 monolayer thick GaAs for n=5–10. The heights, widths and densities of dots are in the range of 6–22.0 nm, 40–85 nm, and 1.6–1.1×1010/cm2, respectively, as n changes from 5 to 10 with strong alignment along [1 −1 0] direction. Flat and pan-cake-like shape of the QDs in a well is found in TEM images. The bottoms of the QDs are located lower than the center of the InGaAs well. This reveals that there was intermixing—interdiffusion—of group III materials between the InGaAs QD and the InGaAs well during growth. All reported dots show strong 300 K-PL spectrum, and 1.276 μm (FWHM: 32.3 meV) of 300 K-PL peak was obtained in case of 7 periods of the QDs in a well, which is useful for the application to optical communications. 相似文献
115.
本文报道用X-射线衍射(XRD),TEM和FTIR光谱考察了在不同的制备条件下BSA-SDS-Ag的SDS-Ag聚合物纳米微粒的结构,形貌以及表面性质,随制备条件的不同,微粒的表面形貌有很大的差异。体系在微也液状态下,用甲醛作还原剂,可把银离子还原为单质,进而聚集成包裹型的团状微粒,微粒粒径32-60nm;微粒表面结构复杂,表明Ag^+先后与蛋白质中的某些氨基酸残基产生化学键合,再还原为Ag粒,进而聚合成网状结构的聚合物。 相似文献
116.
Carotenoids are essential pigments in natural photosynthesis. They absorb in the blue–green region of the solar spectrum and transfer the absorbed energy to (bacterio-)chlorophylls, and so expand the wavelength range of light that is able to drive photosynthesis. This process is an example of singlet–singlet energy transfer and so carotenoids serve to enhance the overall efficiency of photosynthetic light reactions. Carotenoids also act to protect photosynthetic organisms from the harmful effects of excess exposure to light. In this case, triplet–triplet energy transfer from (bacterio-)chlorophyll to carotenoid plays a key role in this photoprotective reaction. In the light-harvesting pigment–protein complexes from purple photosynthetic bacteria and chlorophytes, carotenoids have an additional role, namely the structural stabilization of those complexes. In this article we review what is currently known about how carotenoids discharge these functions. The molecular architecture of photosynthetic systems will be outlined to provide a basis from which to describe the photochemistry of carotenoids, which underlies most of their important functions in photosynthesis. Then, the possibility to utilize the functions of carotenoids in artificial photosynthetic light-harvesting systems will be discussed. Some examples of the model systems are introduced. 相似文献
117.
《Comptes Rendus Chimie》2015,18(9):914-928
A quick and simple procedure for the synthesis of nanosized complexes of the drug moxifloxacin (MOX) is described. MOX nanoparticles were synthesized via charge-transfer (CT) interactions with the organic acceptors picric acid (PA), chloranilic acid (CLA) and chloranil (CHL). The structure and morphology of these nanoparticles were fully characterized using physicochemical techniques, such as UV–visible, IR, 1H NMR and 13C NMR spectroscopies, XRD, SEM, TEM, and elemental and thermal analyses. Notably, it has been found that the complexation of MOX with an organic acceptor leads to well-organized nanoparticles with a main diameter in the range of 10–20 nm. Interestingly, the direct carbonization of the complex containing the PA acceptor leads to nanoporous carbon material with uniform morphology. This method is an efficient way to remove and utilize discarded MOX antibiotic in other products. 相似文献
118.
《Comptes Rendus Chimie》2015,18(12):1335-1343
Zinc oxide has attracted wide research interest due to its unique properties. Its band gap width, high refractive index, high electrical conductivity, and high optical transmission in the visible, etc., have made it suitable for a variety of applications, such as gas sensors, varistors, optoelectronic devices, etc. The first part of the paper presents three methods for the synthesis of zinc oxide nanoparticles: sol–gel, polyol, and hydrothermal methods. Then, we report on the characteristics of the powders in terms of structure, composition and morphology as well as of in-vitro testing on cell cultures. The influence of the nanoparticles on cell viability was evaluated by the lactate dehydrogenase method. It turns out that all ZnO powders tested present high cytotoxicity. Also, it is found that the synthesis method significantly influences cell viability, the lowest one being obtained for nanopowders synthesized by the sol–gel method. 相似文献
119.
Analysis of corrosion scales formed on steel at high temperatures in hydrocarbons containing model naphthenic acids and sulfur compounds
下载免费PDF全文
![点击此处可从《Surface and interface analysis : SIA》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Corrosive naphthenic acids and sulfur compounds in crude oils present a major challenge for refineries from a corrosion perspective. Although it is accepted that some sulfur compounds may form protective FeS scales on the metal surface and deter corrosion, attempting to correlate the characteristics of FeS scale with its protective properties has not been successful. Given the complex chemical compositions of real crudes, model sulfur compound and model naphthenic acids were used to mimic the corrosion by crude fractions in the present study. The iron sulfide scale formed by the model sulfur/acid compounds was challenged by naphthenic acids under high‐velocity conditions to examine its protectiveness against corrosion. Moreover, the scale was analyzed with transmission electron microscope/energy dispersive X‐ray spectroscopy technique, and a layer of iron oxide formed on the 5Cr steel was found when naphthenic acids were present in the solution. The iron oxide layer appeared to be important for maintaining protection against naphthenic acid corrosion, and further analysis revealed that it was composed of magnetite. Copyright © 2015 John Wiley & Sons, Ltd. 相似文献
120.
Mechanical polishing,surface roughness,near‐surface deformation,and electrochemical corrosion of Alloy 690TT
下载免费PDF全文
![点击此处可从《Surface and interface analysis : SIA》网站下载免费的PDF全文](/ch/ext_images/free.gif)
The effects of mechanical grinding/polishing, surface roughness, and near‐surface deformation on the electrochemical corrosion behavior of thermally treated (TT) Alloy 690 were studied in a sodium chloride solution. The X‐ray photoelectron spectroscopy and transmission electron microscopy analyses revealed that mechanical grinding/polishing can change the ratio of the elements at the surface of the as‐received Alloy 690TT specimen by removing its Cr‐rich outer layer and causing deformation at the near‐surface microstructure, something which has a direct impact on the rate of the oxygen reduction reaction (ORR), the pitting potential (Epit), and the corrosion potential (Ecorr) of Alloy 690TT. It was observed that the ratio of Cr in the surface is a significant factor that controls the rate of the ORR and the corrosion parameters such as Ecorr. Higher amounts of Cr at the surface accelerate the ORR. The near‐surface deformation shifts the Epit values towards less positive potentials. It was also found that due to the different near‐surface chemical composition of the as‐received Alloy 690TT specimen compared with the ground and the polished specimens, the surface roughness parameters do not have a regular correlation with the rate of the ORR and the values of the Ecorr and the Epit. Only the passive current density increases when the surface roughness is increased. Copyright © 2015 John Wiley & Sons, Ltd. 相似文献