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121.
Density functional theory within the local density approximation is used to investigate the effect of the oxygen vacancy on the LaGaO_3/SrTiO_3(001) heterojunction. It is found that the energy favorable configuration is the oxygen vacancy located at the 3~(rd) layer of the STO substrate, and the antiferrodistortive distortion is induced by the oxygen vacancy introduced on the SrTiO_3 side. Compared with the heterojunction without introducing oxygen vacancy, the heterojunction with introducing the oxygen vacancy does not change the origin of the two-dimensional electron gas(2DEG), that is, the 2DEG still originates from the d_(xy) electrons, which are split from the t~(2g) states of Ti atom at interface; however the oxygen vacancy is not beneficial to the confinement of the 2DEG. The extra electrons caused by the oxygen vacancy dominantly occupy the 3d_(x~2-y~2) orbitals of the Ti atom nearest to the oxygen vacancy, thus the density of carrier is enhanced by one order of magnitude due to the introduction of oxygen vacancy compared with the density of the ideal structure heterojunction. 相似文献
122.
采用基于密度泛函理论的第一性原理计算方法,系统地研究了La_(1-x)Sr_xMnO_3层中Sr的掺杂方式和掺杂量对4La_(1-x)Sr_xMnO_3/3LaAlO_3/4SrTiO_3(LSMO/LAO/STO)异质结构原子和电子结构的影响.结果表明:对于相同的Sr掺杂量,掺杂方式的差异对体系电子结构的影响微弱,不会导致体系发生金属-绝缘体转变;掺杂量的不同对体系电子结构有着显著的影响,当Sr的掺杂量较少时,LAO/STO界面处存在着准二维电子气,当Sr的掺杂量高于1/3时,LAO/STO界面处准二维电子气消失.我们相信,Sr的引入以及通过Sr掺杂量的改变可以对LSMO覆盖层极化进行调控,这也是导致体系LAO/STO界面处金属-绝缘体转变的可能原因,进一步为极化灾变机制导致的界面处电子重构提供了证据. 相似文献
123.
IHEP, China is constructing a 100 MeV/100 kW electron Linac for NSC KIPT, Ukraine. This linac will be used as the driver of a neutron source based on a subcritical assembly. In 2012, the injector part of the accelerator was pre-installed as a testing facility in the experimental hall ≠2 of IHEP. The injector beam and key hardware testing results met the design goal. Recently, the injector testing facility was disassembled and all of the components for the whole accelerator have been shipped to Ukraine from China by the ocean shipping. The installation of the whole machine in KIPT will be started in June, 2013. The construction progress, the design and testing results of the injector beam and key hardware are presented. 相似文献
124.
通过在强磁场条件下,利用环形刀口石墨阴极(刀口尺寸38~39mm)开展电子束轰击收集极内表面铜箔和垂直轰击金属靶片实验,对无箔二极管中电子束的空间密度分布进行了初步研究,并对其产生原因进行了分析。研究结果表明,电子束径向分布在37.2~40.2mm,存在密度较高区域(38.8~39.4mm)和密度最大值点(39.2mm),且均偏向于阴极外侧。无箔二极管环形阴极爆炸发射产生电子束的径向密度分布可用偏态分布近似。 相似文献
125.
126.
Nanocrystalline cobalt ferrites with nominal composition CoCrxFe2−xO4 ranging from x=0.0 to 0.5 with step increment of 0.25 were prepared by sol–gel auto combustion and chemical co-precipitation techniques. A comparative study of structural, electrical and magnetic properties of these ferrites has been measured using different characterization techniques. Structural and micro-structural studies were measured using X-ray diffraction, Fourier transform infra-red spectroscopy (FTIR), scanning electron microscopy and atomic force microscopy. Crystallite sizes of the series are within the range of 12–29±2 nm. Lattice parameters decrease by increasing Cr3+ concentration. FTIR confirms the presence of two lattice absorption bands. DC electrical resistivity increases to a value of ∼1010 Ω-cm with increase in Cr3+ concentration, but the most significant increase is in samples prepared by sol–gel combustion. Dielectric properties have been measured as a function of frequency at room temperature. Dielectric loss decreases to 0.1037 and 0.0108 at 5 MHz for chemical co-precipitation and sol–gel combustion, respectively. Impedance measurements further helped in analyzing the electrical properties and to separate the grain and grain boundary resistance effects using a complex impedance analysis. Magnetic parameters were studied using a vibrating sample magnetometer in the applied field of 10 kOe. The saturation magnetization decreased from 63 to 10.8 emu/gm with increase in Cr3+ concentration. 相似文献
127.
Recent theoretical work has not led to a consensus regarding the nature of the low-energy E1 strength in the 40,44,48Ca isotopes, for which high-resolution (γ,γ′) data exist. Here we revisit this problem using the first-order quasiparticle random-phase approximation (QRPA) and different interactions. First we examine all even Ca isotopes with N=14–40. All isotopes are predicted to undergo dipole transitions at low energy, of large and comparable isoscalar strength but of varying E1 strength. Provided a moderate and uniform energetic shift is introduced to the results, QRPA with the Gogny D1S interaction is able to account for the (γ,γ′) data, because, up to N=28, it yields a rather pure isoscalar oscillation. A neutron-skin oscillation is anticipated for N?30. This contradicts existing predictions that 44,48Ca develop a neutron-skin mode. Which theoretical result is correct cannot be resolved conclusively using the available data. We propose that alpha-scattering, possibly followed by an electroexcitation experiment, could resolve the situation and thereby help to improve the different models aspiring to describe reliably the low-energy dipole strength of nuclei. 相似文献
128.
The spatially controlled field assisted etching method for sharpening metallic tips, in a field ion microscope (FIM), is used to study the evolution of the field emission when the tip apex radius is decreased below 1 nm. Unlike the conventional image formation in a field emission microscope (FEM), we demonstrate that at this scale the field emission is rather confined to atomic sites. A single atom apex fabricated at the end of such tips exhibits an outstanding brightness compared to other atomic tips. The measurements have been repeated for two double atom tips, with different atom-atom separations, and images of atomic field emission localization have also been obtained. We have found that the field emission intensity alternates between adjacent atoms when the applied voltage is gradually increased beyond a threshold value. 相似文献
129.
Lars Müller-Meskamp Rainer Waser Melanie Homberger Ulli Englert 《Surface science》2009,603(4):716-8968
The self-assembly of ω-ferrocenylalkanethiols (FcCnSH) with different alkyl-spacer lengths on Au(1 1 1) substrates has been studied by scanning tunneling microscopy (STM). Upon deposition at room temperature FcCnSH molecules tend to form multilayers, while by thermal treatment monolayer formation, a rearrangement of the molecules and the formation of ordered domains is achieved. The surface structure of the resulting full coverage self-assembled monolayers is resolved with molecular resolution by STM. The ordered monolayer structure of ω-ferrocenylpropanethiol is discussed in comparison with its bulk crystal structure, derived from single crystal X-ray analysis. Based on these results a monolayer structure of ω-ferrocenylalkanethiols with longer alkyl chains closely related to the bulk crystal structure of the shorter alkyl-spacer derivates is suggested. Our results provide detailed insight into the self-assembly of FcCnSH on gold substrates. 相似文献
130.
Low-energy cluster beam deposition was used to deposit mass-selected Aun clusters (n = 4, 6, 13 and 20) on amorphous carbon (a-C) substrates. The resulting samples were stored at room temperature under ambient conditions for time periods up to 32 months to analyze the coarsening behaviour of the clusters. Cluster-size distributions were measured in regular time intervals by transmission electron microscopy (TEM). The TEM experiments show a significant increase of the average cluster size with time analogous to classical surface Ostwald ripening (OR). The coarsening of Au clusters can be well described by steady-state diffusion-limited kinetics. The derived surface mass-transport diffusion coefficients at room temperature range between 1.1 and 3.8·10−25 m2 s−1 for our samples. A detailed analysis of values suggests that, the rate of the surface OR for mass-selected Aun clusters increases with the cluster size in the sequence: Au4 ≈ Au6 < Au13 < Au20 for the investigated range of Au clusters. Given that the initial, on-surface cluster-size distributions are nominally monodisperse, classical OR with cluster coarsening based only on the Gibbs-Thomson effect cannot explain the observed coarsening. The activation of the coarsening process is rationalized by initial variations of the cluster sizes due to the deposition process itself and/or the interaction of the clusters with the substrate. Moreover, the presence of initial deposited Au clusters as different isomers with slightly different chemical potential on the substrate, may also initiate the coarsening by surface OR. Furthermore, we find that the coarsening is most pronounced for the paucidispersed sample with Aum (10 ? m ? 20) clusters. A possible explanation of this behaviour is the presence of an initial distribution of different cluster sizes directly after deposition. 相似文献