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951.
Jianye Ge Benjamin Crysup Dixie Peters Romy Franco Muyi Liu Xuewen Wang Meng Huang Bruce Budowle 《Electrophoresis》2023,44(13-14):1080-1087
Y chromosome Short Tandem Repeat (STR) haplotypes have been used in assisting forensic investigations primarily for identification and male lineage determination. The current SWGDAM interpretation guidelines for Y-STR typing provide helpful guidance on those purposes but do not address the issue of kinship analysis with Y-STR haplotypes. Because of the high mutation rate of Y-STRs, there are complex missing person cases in which inconsistent Y-STR haplotypes between true paternal lineage relatives will arise and cases with two or more male references in the same lineage and yet differ in their haplotypes. Therefore, more useful methods are needed for interpreting the Y-STR haplotype data. Computational methods and interpretation guidelines have been developed specifically addressing this issue, either using a mismatch-based counting method or a pedigree likelihood ratio method. In this study, a software program, MPKin-YSTR, was developed by implementing those more sophisticated methods. This software should be able to improve the interpretation of complex cases with Y-STR haplotype evidence. Thus, more biological evidence will be interpreted, which in turn will result in more investigation leads to help solve crimes. 相似文献
952.
Dr. Jiawei Zhang Dr. Daisuke Ishikawa Dr. Michael M. Koza Prof. Dr. Eiji Nishibori Dr. Lirong Song Dr. Alfred Q. R. Baron Prof. Dr. Bo B. Iversen 《Angewandte Chemie (International ed. in English)》2023,62(13):e202218458
Loosely bonded (“rattling”) atoms with s2 lone pair electrons are usually associated with strong anharmonicity and unexpectedly low thermal conductivity, yet their detailed correlation remains largely unknown. Here we resolve this correlation in thermoelectric InTe by combining chemical bonding analysis, inelastic X-ray and neutron scattering, and first principles phonon calculations. We successfully probe soft low-lying transverse phonons dominated by large In1+ z-axis motions, and their giant anharmonicity. We show that the highly anharmonic phonons arise from the dynamic lone pair expression with unstable occupied antibonding states induced by the covalency between delocalized In1+ 5s2 lone pair electrons and Te 5p states. This work pinpoints the microscopic origin of strong anharmonicity driven by rattling atoms with stereochemical lone pair activity, important for designing efficient materials for thermoelectric energy conversion. 相似文献
953.
Dr. Keke Guo Weijun Li Yuhong He Xiaopeng Feng Jinmei Song Wanting Pan Wei Qu Prof. Bai Yang Prof. Haotong Wei 《Angewandte Chemie (International ed. in English)》2023,62(23):e202303445
The low-dimensional halide perovskites have attracted increasing attention due to their improved moisture stability, reduced defects, and suppressed ions migration in many optoelectronic devices such as solar cells, light-emitting diodes, X-ray detectors, and so on. However, they are still limited by their large band gap and short charge carriers’ diffusion length. Here, we demonstrate that the introduction of metal ions into organic interlayers of two-dimensional (2D) perovskite by cross-linking the copper paddle-wheel cluster-based lead bromide ([Cu(O2C−(CH2)3−NH3)2]PbBr4) perovskite single crystals with coordination bonds can not only significantly reduce the perovskite band gap to 0.96 eV to boost the X-ray induced charge carriers, but can also selectively improve the charge carriers’ transport along the out-of-plane direction and blocking the ions motion paths. The [Cu(O2C−(CH2)3−NH3)2]PbBr4 single-crystal device can reach a record charges/ions collection ratio of 1.69×1018±4.7 % μGyair−1 s, and exhibit a large sensitivity of 1.14×105±7% μC Gyair−1 cm−2 with the lowest detectable dose rate of 56 nGyair s−1 under 120 keV X-rays irradiation. In addition, [Cu(O2C−(CH2)3−NH3)2]PbBr4 single-crystal detector exposed to the air without any encapsulation shows excellent X-ray imaging capability with long-term operational stability without any attenuation of 120 days. 相似文献
954.
Zhi Yong Wei~ 《中国化学快报》2008,19(3):363-366
Copolymerizations of L-lactide (L-LA) and ε-caprolactone (ε-CL) were conducted in bulk using magnesium octoate as a catalyst. The reactivity ratios of L-LA and ε-CL were determined to be rL=23 and rc=0.22, respectively. The sequence analyses of the copolymers were performed on ^13C NMR. An increase in the reaction temperature enhances the role of transesterification and the extent of randomness. 相似文献
955.
甲基丙烯酸缩水甘油酯与甲基丙烯酸甲酯的共聚合及竞聚率测定 总被引:1,自引:0,他引:1
以N,N-二甲基甲酰胺(DMF)为溶剂,实施了甲基丙烯酸缩水甘油酯(GMA)与甲基丙烯酸甲酯(MMA)的溶液共聚合,测定了共聚物P(GMA-co-MMA)的红外光谱(FT-IR),对其化学结构进行了表征,并采用差示扫描量热法(DSC)测定了共聚物的玻璃化转变温度(Tg).改变两单体投料比进行共聚合,采用化学分析法测定低转化率下(<7%)共聚物组成,重点研究了两单体的竞聚率.结果表明:GMA与MMA的共聚合易于进行,P(GMA-co-MMA)的玻璃化转变温度(Tg)介于均聚物PGMA(72℃)与PMMA(106℃)之间,当n(GMA)/n(MMA)=4/6时,共聚物的Tg为9l℃.采用FR和KT 2种作图法及YBR计算法对单体的竞聚率进行了计算和比较,结果表明:KT和YBR法较为准确,以DMF为溶剂时,GMA与MMA的竞聚率分别为2.14与0.69. 相似文献
956.
Godin JP Breuillé D Obled C Papet I Schierbeek H Hopfgartner G Fay LB 《Journal of mass spectrometry : JMS》2008,43(10):1334-1343
On-line gas chromatography-combustion-isotope ratio mass spectrometry (GC-C-IRMS) is commonly used to measure isotopic ratios at natural abundance as well as for tracer studies in nutritional and medical research. However, high-precision (13)C isotopic enrichment can also be measured by liquid chromatography-isotope ratio mass spectrometry (LC-IRMS). Indeed, LC-IRMS can be used, as shown by the new method reported here, to obtain a baseline separation and to measure (13)C isotopic enrichment of underivatised amino acids (Asp, Thr-Ser, Glu, Pro, Gly, Ala, Cys and Val). In case of Val, at natural abundance, the SD(delta(13)C) reported with this method was found to be below 1 per thousand . Another key feature of the new LC-IRMS method reported in this paper is the comparison of the LC-IRMS approach with the conventional GC-C-IRMS determination. To perform this comparative study, isotopic enrichments were measured from underivatised Val and its N(O, S)-ethoxycarbonyl ethyl ester derivative. Between 0.0 and 1.0 molar percent excess (MPE) (delta(13)C= -12.3 to 150.8 per thousand), the calculated root-mean-square (rms) of SD was 0.38 and 0.46 per thousand and the calculated rms of accuracy was 0.023 and 0.005 MPE, respectively, for GC-C-IRMS and LC-IRMS. Both systems measured accurately low isotopic enrichments (0.002 atom percent excess (APE)) with an SD (APE) of 0.0004. To correlate the relative (delta(13)C) and absolute (atom%, APE and MPE) isotopic enrichment of Val measured by the GC-C-IRMS and LC-IRMS devices, mathematical equations showing the slope and intercept of the curves were established and validated with experimental data between 0.0 to 2.3 MPE. Finally, both GC-C-IRMS and LC-IRMS instruments were also used to assess isotopic enrichment of protein-bound (13)C-Val in tibial epiphysis in a tracer study performed in rats. Isotopic enrichments measured by LC-IRMS and GC-C-IRMS were not statistically different (p>0.05). The results of this work indicate that the LC-IRMS was successful for high-precision (13)C isotopic measurements in tracer studies giving (13)C isotopic enrichment similar to the GC-C-IRMS but without the step of GC derivatisation. Therefore, for clinical studies requiring high-precision isotopic measurement, the LC-IRMS is the method of choice to measure the isotopic ratio. 相似文献
957.
958.
Pengcheng Li Prof. Hao Zhang Prof. Jun Lu Prof. Ge Li 《Angewandte Chemie (International ed. in English)》2023,62(10):e202216312
Electrolyte engineering is crucial for the commercialization of lithium metal batteries. Here, lithium metal is stabilized in the highly reactive sulfolane-based electrolyte under low concentration (0.25 M) for the first time. Inorganic-polymer hybrid solid electrolyte interphase (SEI) with high ionic conductivity, low bonding with lithium and high flexibility enables dense chunky lithium deposition and high plating/stripping efficiency. Low concentration electrolyte (LCE) also enables excellent cycling stability of LiNi0.5Co0.2Mn0.3O2 (NCM523)/Li cells at 1 C (90.7 % retention after 500 cycles) and 0.3 C (83.3 % retention after 1000 cycles). With a low N/P ratio (≈2), the capacity retention for NCM523/Li cells can achieve 94.3 % after 100 cycles at 0.3 C. Exploring the LCE is of paramount significance because it provides more possibilities of the lithium salt selections, especially reviving some lithium salts that are excluded before due to their low solubility. More importantly, LCE has the significant advantage of commercialization due to its cost-effectiveness. 相似文献
959.
Dr. Xuelin Yao Dr. Heng Zhang Fanmiao Kong Dr. Antoine Hinaut Dr. Rémy Pawlak Prof. Dr. Masanari Okuno Dr. Robert Graf Dr. Peter N. Horton Prof. Dr. Simon J. Coles Prof. Dr. Ernst Meyer Prof. Dr. Lapo Bogani Prof. Dr. Mischa Bonn Prof. Dr. Hai I. Wang Prof. Dr. Klaus Müllen Prof. Dr. Akimitsu Narita 《Angewandte Chemie (International ed. in English)》2023,62(46):e202312610
Structurally defined graphene nanoribbons (GNRs) have emerged as promising candidates for nanoelectronic devices. Low band gap (<1 eV) GNRs are particularly important when considering the Schottky barrier in device performance. Here, we demonstrate the first solution synthesis of 8-AGNRs through a carefully designed arylated polynaphthalene precursor. The efficiency of the oxidative cyclodehydrogenation of the tailor-made polymer precursor into 8-AGNRs was validated by FT-IR, Raman, and UV/Vis-near-infrared (NIR) absorption spectroscopy, and further supported by the synthesis of naphtho[1,2,3,4-ghi]perylene derivatives ( 1 and 2 ) as subunits of 8-AGNR , with a width of 0.86 nm as suggested by the X-ray single crystal analysis. Low-temperature scanning tunneling microscopy (STM) and solid-state NMR analyses provided further structural support for 8-AGNR . The resulting 8-AGNR exhibited a remarkable NIR absorption extending up to ∼2400 nm, corresponding to an optical band gap as low as ∼0.52 eV. Moreover, optical-pump TeraHertz-probe spectroscopy revealed charge-carrier mobility in the dc limit of ∼270 cm2 V−1 s−1 for the 8-AGNR . 相似文献
960.
A concept demonstration has been made to simultaneously enhance both O2 and CO2 gas permeance and O2/N2 and CO2/CH4 selectivity via intelligently decoupling the effects of elongational and shear rates on dense-selective layer and optimizing spinning conditions in dual-layer hollow fiber fabrication. The dual-layer polyethersulfone hollow fiber membranes developed in this work exhibit an O2/N2 selectivity of 6.96 and an O2 permeance of 4.79 GPU which corresponds to an ultrathin dense-selective layer of 918 Å at room temperature. These hollow fibers also show an impressive CO2/CH4 selectivity of 49.8 in the mixed gas system considering the intrinsic value of only 32 for polyethersulfone dense films. To our best knowledge, this is the first time to achieve such a high CO2/CH4 selectivity without incorporating any material modification. The above gas separation performance demonstrates that the optimization of dual-layer spinning conditions with balanced elongational and shear rates is an effective approach to produce superior hollow fiber membranes for oxygen enrichment and natural gas separation. 相似文献