全文获取类型
收费全文 | 557篇 |
免费 | 26篇 |
国内免费 | 44篇 |
专业分类
化学 | 190篇 |
晶体学 | 2篇 |
力学 | 35篇 |
数学 | 127篇 |
物理学 | 273篇 |
出版年
2024年 | 1篇 |
2023年 | 26篇 |
2022年 | 11篇 |
2021年 | 10篇 |
2020年 | 16篇 |
2019年 | 16篇 |
2018年 | 12篇 |
2017年 | 13篇 |
2016年 | 15篇 |
2015年 | 18篇 |
2014年 | 35篇 |
2013年 | 42篇 |
2012年 | 29篇 |
2011年 | 42篇 |
2010年 | 42篇 |
2009年 | 45篇 |
2008年 | 43篇 |
2007年 | 46篇 |
2006年 | 29篇 |
2005年 | 18篇 |
2004年 | 16篇 |
2003年 | 13篇 |
2002年 | 9篇 |
2001年 | 9篇 |
2000年 | 4篇 |
1999年 | 13篇 |
1998年 | 6篇 |
1997年 | 11篇 |
1996年 | 6篇 |
1995年 | 1篇 |
1994年 | 3篇 |
1993年 | 4篇 |
1992年 | 4篇 |
1991年 | 3篇 |
1989年 | 1篇 |
1988年 | 2篇 |
1987年 | 3篇 |
1986年 | 1篇 |
1984年 | 3篇 |
1983年 | 2篇 |
1982年 | 1篇 |
1980年 | 1篇 |
1977年 | 1篇 |
1976年 | 1篇 |
排序方式: 共有627条查询结果,搜索用时 0 毫秒
21.
We report a simple fabricating approach to control the mode couplings in long-period fiber gratings (LPFGs) through side exposing fiber to long-pulse-10.6-μm laser from a cheap, internally modulated CO2 tube. By tuning focused-spot size on fibers, not only circularly symmetric mode coupling but also asymmetric mode couplings can be effectively achieved. Simulation of mode profiles in grating cross-section with Finite Element Method (FEM), and LPFG-cladding etching experiment with hydrofluoric acid (HF), support our explanation that asymmetric mode coupling in LPFGs depends on local refractive-index (RI) change within an azimuthally thin cladding layer, resulted from large-spot method induced deep melt flow on fiber surface during CO2 laser irradiation. 相似文献
22.
基于长光程技术的痕量海水营养盐自动分析仪的设计与测试 总被引:1,自引:0,他引:1
海水中可溶性的营养盐浓度是海洋监测的常规项目之一;大洋水体中的营养盐含量很低,使用传统的分光光度计难于定量测量。文章基于液芯波导长光程技术,设计了高灵敏度的痕量海水营养盐光谱分析仪。分析仪以1.02 nm的光谱分辨率实现350~900 nm光谱范围的水样吸光度连续光谱测量,并由嵌入式PC104微机自动实现了水样采集、吸光度测量和数据分析的功能。针对亚硝酸盐的测试实验结果表明,仪器检出限达到nmol·L-1的量级,比传统分光光度计的检测限提高了三个量级,且显色反应时间可缩短到3 min,能适用于大洋水体中营养盐的现场痕量分析。 相似文献
23.
Li-Yang Shao Albane Laronche Predrag Mikulic Jacques Albert 《Optics Communications》2010,283(13):2690-2694
We demonstrate a new type of fiber optic bend sensor with a hybrid structure made up of a long period grating (LPG) and a tilted fiber Bragg grating (TFBG). The sensing mechanism is based on the spectrum of power transfers between the core and cladding modes from a TFBG located downstream from a LPG. We show that the curvature of a beam can be determined by the reflected power difference between the core mode and the recoupled cladding modes. We further provide design rules for the LPG and TFBG to optimize and linearize the sensor response. In addition, the temperature cross-sensitivities of this configuration are also investigated for two different types of fiber. 相似文献
24.
提出了一种改进型边缘滤波波长解调技术,解决干涉型或谐振型光纤传感器输出的干涉谱波长的快速解调问题。该波长解调技术基于啁啾光栅和长周期光栅的光谱特点,以啁啾光栅作为矩形滤波器,提取传感器输出干涉谱的一个干涉峰;以长周期作为边缘滤波器,将干涉峰的波长信息转化为光强信息进行检测。该波长解调技术波长解调范围为传感器输出干涉谱的一个自由光谱范围(FSR),解调速度快,克服了当前波长解调技术中存在的测量范围与测量速度难以同时提高的问题,同时还具有系统成本低 ,体积小,能够灵活多路扩展的特点。详细介绍了解调系统的工作原理以及系统结构,并将其实际应用于一种干涉型光纤电流传感器输出干涉谱的波长解调中。通过实验证明电流传感器工作在工频及脉冲电流(脉冲宽度25 μs)情况下,该解调系统对传感器输出干涉谱具有准确、快速的解调效果。该研究对推进干涉或谐振型光纤传感器的实际工程化水平的提高具有重要意义。 相似文献
25.
二氧化碳(CO2)是植物光合作用的原材料,也是一种温室气体,其过量地排放会影响动植物的生态环境。在碳达峰、碳中和的背景下,研制高灵敏度的CO2检测装置具有重要意义。为了监测大气环境中CO2含量的变化,设计了一种长光程共振式CO2气体光声传感器,并以此搭建了光声检测装置。以中心波长为2 004 nm的分布式反馈激光器(DFB)作为激发光源,激光射入由漫反射材料制成的球型吸收腔,在腔内多次反射以增加气体的吸收路径。吸收腔外部被两个高热传导率的铝制半球包裹,降低由池体吸收光能后产生的热噪声。吸收腔上耦合一根声学管,当其工作在一阶纵向共振模态时,光声信号被放大,在管子末端达到极大值。为了进一步增大光声信号,通过饱和加湿样品的方式来加快CO2气体的弛豫速率,加湿后的样品产生的光声信号是干燥样品的2.1倍左右。使用一系列浓度的湿润CO2样品标定光声检测装置,结果表明,光声信号与浓度之间呈现良好的线性关系。在此基础上,通过对标准气体的检测实验,验证了装置的准确性与稳定性... 相似文献
26.
《Physics letters. A》2020,384(34):126864
We address the investigation of non trivial properties of the energy current in boundary driven XXZ quantum spin models. In specific, we focus on the occurrence of the one-way street phenomenon in asymmetrical chains, a phenomenon stronger than rectification, which establishes the existence of a unique way for the energy current in the absence of external magnetic field, that is, the magnitude and direction of the energy flow does not change as we invert the baths at the boundaries. For general target polarizations at the boundaries, we show that such a phenomenon holds in the presence of long range interactions, ingredient which increases the flow and the rectification in chains of classical oscillators, and so, of interest in the study of manipulation and control of the energy flow. 相似文献
27.
Jakob Jonsson 《Journal of Combinatorial Theory, Series A》2008,115(8):1504-1526
Building on work by Bouc and by Shareshian and Wachs, we provide a toolbox of long exact sequences for the reduced simplicial homology of the matching complex Mn, which is the simplicial complex of matchings in the complete graph Kn. Combining these sequences in different ways, we prove several results about the 3-torsion part of the homology of Mn. First, we demonstrate that there is nonvanishing 3-torsion in whenever , where . By results due to Bouc and to Shareshian and Wachs, is a nontrivial elementary 3-group for almost all n and the bottom nonvanishing homology group of Mn for all n≠2. Second, we prove that is a nontrivial 3-group whenever . Third, for each k?0, we show that there is a polynomial fk(r) of degree 3k such that the dimension of , viewed as a vector space over Z3, is at most fk(r) for all r?k+2. 相似文献
28.
The aim of this work is to describe a method whereby low levels of long chain branching, LCB, can be quantified on a relative basis for whole, unfractionated, and essentially linear ethylene/α-olefin copolymers. The method is based on a well established, relatively fast and robust experiment, namely the measurement of the linear viscoelastic properties by a single, isothermal, small amplitude oscillatory shear experiment. The analysis of the data is predicated on the use of the so-called van Gurp-Palmen plots (the phase angle, δ (=tan−1(G″/G′)), plotted against the absolute value of the dynamic complex modulus, |G∗| = (G′2+G″2)1/2). From this plot, the value of δ at |G∗| = 10 kPa is recorded, and it is demonstrated that the amount of LCB inversely correlates with such value of the phase angle, δ. Depending on the desired frequency range, the experiment duration varies between 15 and 60 min rendering this technique well suited for high throughput parallel testing. Its applicability is critically examined with a wide variety of commercial ethylene/α-olefin copolymers. Moreover, we have improved on the long chain branching index (LCBI) proposed by Shroff and Mavridis [Shroff RN, Mavridis H. Long-chain-branching index for essentially linear polyethylenes. Macromolecules 1999;32:8454-64] by basing it on data of truly linear polyethylenes (hydrogenated anionically synthesized polybutadienes) instead of apparently linear commercial polyethylenes. 相似文献
29.
30.
首先用溶胶-凝胶法制备符合SrAl2O4:Eu^2 ,Dy^3 化学组成的溶胶,然后通过机械研磨、水热反应和微波加热反应三种不同的组装方法和微波还原扩散法使其进入主体ZSM-5沸石的孔道中。主客体材料的荧光光谱出现显著蓝移,余辉光谱出现400nm和517nm两个发射峰,两个余辉峰的相对发射强度随组装方法和组装浓度的改变而具有可调性,呈现有规律的变化。分析其原因是由于发光材料进入沸石的纳米级孔洞引起的。 相似文献