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71.
72.
Chemically shortened multi-walled carbon nanotubes used as anode materials for lithium-ion batteries
An easy chemically cutting process, modified Hummers' method, was proposed to treat multi-walled carbon nanotubes, successfully cutting pristine long, entangled carbon nanotubes into hydrosoluble pieces, mostly less than 200 nm. This short, chemically oxidized carbon nanotube was then applied as an anode material for lithium-ion batteries. The as-prepared material possessed higher reversible capacity and coulombic efficiency. The intrinsic factors were explored by X-ray photoelectron spectroscopy and cyclic voltammetry. 相似文献
73.
Masahiro FujiwaraNaoya Tajima Tatsuro ImakuboMasafumi Tamura Reizo Kato 《Journal of solid state chemistry》2002,168(2):396-407
This article reports preparation, structure, and conducting property of several cation radical salts of organic donors tetramethyltetrathiafulvalene (TMTTF), ethylenedithiotetrathiafulvalene (EDT-TTF), bis(ethylenedithio)tetrathiafulvalene (ET), bis(ethylenedithio)tetraselenafulvalene (BETS) and hexamethylenetetraselenafulvalene (HMTSF) with two novel planar Te-based dianions, TeI42− and Te2I62−. (ET)5Te2I6 1 and (BETS)5Te2I6 2 are isostructural. In these Te2I62− salts, intermolecular short I···I contacts form a supramolecular corrugated anion sheet. Donor arrangement is similar to the θ-type. With lowering temperature, the resistivity of 1 shows a gradual increase followed by a sharp upturn at 110 K. 2 is metallic down to 120 K and shows a gradual increase of the resistivity followed by a clear transition to an insulating state around 60 K. Crystal structure of (ET)4TeI4 3 is based on the “herring bone” arrangement of ET molecules similar to the α-type. 3 shows a semiconductive behavior around room temperature followed by a transition to an insulating state at 210 K. (EDT-TTF)4TeI4 4, a semiconductor, exhibits a unique two-dimensional arrangement of dimerized EDT-TTF molecules. 相似文献
74.
Multi-layered thin films, which consisted of metallic silver, GeSe3 glass, and silver oxyhalide superionic conductor glass were prepared. Photo- and electrochemical reaction of metallic silver with the chalcogenide glass layer was studied by optical absorbance and cyclic-voltammetry. Photo-doping of silver through the superionic glass layer was observed using evaporated AgI---Ag2MoO4 film and it was partly undoped by electrochemical treatment. However, no photo-doping was observed for the cell consisting of a AgI---AgPO3 dip-coated layer. The doped silver was dissolved into the GeSe3 layer during the photo-doping process. However, it formed another intermediate compound layer (probably silver selenide) during the electrodoping process. 相似文献
75.
76.
Nanocomposite electrodes of recently identified polyanion cathode materials comprising Li
x
M2(MoO4)3 {0 ≤ x < 3} [M = Co, Ni] and nanosized carbon having ~10 nm particle size were found to show remarkable improvement in their discharge
capacity compared to the one prepared with acetylene black. The addition of nanosized carbon as a conductive additive offered
improved initial discharge capacity of 121 mAh/g between 3.5–2.0 V vs Li/Li. The cause for such an increase could be firmly
attributed to the filling up of the grain–grain contact area of the active material, facilitating the intimate grain–grain
contacts in the composite structure leading to enhanced capacity delivery. As for the nanocomposite Li
x
Co2(MoO4)3, it was found that at least 55% of its first discharge capacity was retained at the end of 20th cycle compared to its analogous
counterpart, Li
x
Ni2(MoO4)3.
Paper presented at the Third International Conference on Ionic Devices (ICID 2006), Chennai, Tamilnadu, India, Dec. 7–9, 2006. 相似文献
77.
Tin oxalate as a precursor of tin dioxide and electrode materials for lithium-ion batteries 总被引:2,自引:0,他引:2
R. Alcántara Fernández F. Madrigal P. Lavela C. Pérez-Vicente J. Tirado 《Journal of Solid State Electrochemistry》2001,6(1):55-62
Tin(II) oxalate was studied as a novel precursor for active electrode materials in lithium-ion batteries. The discharge of
lithium cells using tin oxalate electrodes takes place by three irreversible steps: tin reduction, forming a lithium oxalate
matrix; solvent decomposition to form a passivating layer; and oxalate reduction in a two-electron process. These are followed
by reversible alloying of tin with lithium, leading to a maximum discharge of 11 F/mol. Cycling of the cells showed reversible
capacities higher than 600 mAh/g during the first five cycles and ca. 200 mAh/g after 50 cycles. Tin oxalate was converted
to tin dioxide by thermal decomposition at 450 °C and also by a chemical method by dissolving tin oxalate powder in 33% v/v
hydrogen peroxide at room temperature. The ultrafine nature of the tin dioxide powders obtained by this procedure allow their
use as electrodes in lithium cells. The best capacity retention during the first five cycles was achieved for a sample heat
treated to 250 °C to eliminate surface water.
Electronic Publication 相似文献
78.
由一道证明题引申出一个命题,对该命题给出了证明;通过几个实例说明应用该命题可以简便地求解某些接地导体的感应电荷. 相似文献
79.
To improve the cycling performance of graphite anode materials, we propose a functional electrolyte additive, trimethoxymethylsilane (TMSi), which contains a silyl ether functional group as part of its molecular structure. First principal calculation studies, in addition to ex situ analyses, demonstrated that electrochemical reduction of ethylene carbonate (EC) gives an anionic reduced EC product. Subsequent chemical reaction with TMSi then generates solid-electrolyte interphase (SEI) layers of Si–O and Si–C functionalized carbonate on the surface of the graphite anode, which prolongs and stabilizes the cycling performance of the cells. As a result, the cell cycled with TMSi-controlled electrolyte exhibits a cycling retention of 89.5%, whereas the cell cycled with standard electrolyte suffers from poor cycling retention (84.3%) after 100 cycles. 相似文献
80.
The creep life of aluminum conductor composite core (ACCC) utilized in high voltage electric transmission was investigated using an experimental method based on the equivalence relationship. First, the time-temperature-stress equivalence relationship was developed using the time-temperature and the time-stress equivalence relationships. Then, tensile creep experiments were conducted under different temperatures and different stress levels to obtain the strain-time curves of the ACCC. Finally, the creep strain master curve was obtained using the experimental data based on the time-temperature-stress equivalence relationship, allowing prediction of ACCC creep life. The results will play an important role in evaluation of the long-term characteristics of the ACCC for engineering applications. 相似文献