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91.
应用超球会标表示氦原子和氢负离子的薛定谔方程,将二电子原子在三维空间中的运动转化为单电子原子在六维空间中受广义库仑力作用的运动,我们给出了六维空间广义角动量算符的本征值与本征函数,并以此本征函数微基构造超球波函数,得到超球径微分方程,以广义Laguerre 多项式表示超球径波函数,运用密度矩阵和线性变分法得到非正交基下超球径波函数满足的久期方程,最后求得能量和波函数,计算结果与精确的计算符合良好。 相似文献
92.
Different structures have been found for poly(α-tetrathiophene) [poly(α-4TF)] electrosynthesized on Pt by anodic oxidation of 1.0 mM monomer solutions in media such as 45:35:20 (v/v/v) acetonitrile/THF/DMF, 45:35:20 (v/v/v) acetonitrile/ethanol/DMF and 72:28 (v/v) acetonitrile/DMF containing 0.1 M LiClO4; as well as 72:28 (v/v) acetonitrile/DMF with 0.1 M NaClO3, under dynamic and static conditions at 25 °C. In all cases the polymer was generated by chronoamperometry at 1.000 V vs. Ag∣AgCl, corresponding to the first oxidation peak detected by cyclic voltammetry. Uniform, adherent, insoluble and black polymer films were obtained under these conditions. The resulting structures have been elucidated by combining the information of their IR spectrum, nox-value and doping level of the counterion. The degree of crosslinking of every polymer has been quantified and related to the molecular flow of monomer on the Pt electrode. A monomer concentration flow between 4 × 10−6 and 5 × 10−6 mmol cm−2 s−1 was determined as the limiting value below which the polymer grows with crosslinking. This value corresponds to the electropolymerization rate of α-4TF by Pt area unit at 25 °C. 相似文献
93.
Ginting Suka IrwanShin-ichi Kuroda Hitoshi Kubota Takashi Kondo 《European Polymer Journal》2002,38(6):1145-1150
The effect of monomer concentration on photografting of methacrylic acid (MAA) onto linear low-density polyethylene (PE) film (thickness=30 μm) was investigated at 60 °C in water solvent together with the location of MAA-grafted chains. Xanthone was used as a photoinitiator which was coated on the film sample earlier. The higher percentage of grafting and graft efficiency were afforded for the system with the higher monomer concentration. The resultant MAA-grafted films were subjected to measurements of pH-responsive character and ability to adsorb cupric ion in order to understand the characteristics of function introduced. The grafted samples exhibited the pH-responsive character, where they shrank and swelled in acidic and alkaline media, respectively. The pH-responsive character of the grafted films was higher for the samples prepared in the system with a higher monomer concentration. Moreover, the grafted samples exhibited the ability to adsorb cupric ion, and the ability was reduced when the sample was prepared in the system with a higher monomer concentration. The different extents of the pH-responsive character and ability to adsorb cupric ion of the resulting grafted PE films were discussed in terms of location of grafted chains in the film substrate, which was determined by a scanning electron microscope and an attenuated total reflection infrared spectroscopy. 相似文献
94.
甲醇—乙醇—水—盐体系的等压气液平衡 总被引:4,自引:1,他引:4
木文采用CPⅡ型沸点仪测定了在93.33kPa下甲醇-乙醇-水-盐(NaCl,NaBr,Nal,LiCl,CaCl_2)体系的气液平衡数据。实验证明,当三元混合溶剂的相对组成固定时,体系的沸点与加入的盐量呈线性关系,用热力学理论导出了该线性方程,用Gibbs相律探讨了该线性关系的起因。 相似文献
95.
《Journal of separation science》2003,26(17):1541-1546
A novel approach is proposed for the simultaneous optimization of mobile phase pH and gradient steepness in RP‐HPLC using artificial neural networks. By presetting the initial and final concentration of the organic solvent, a limited number of experiments with different gradient time and pH value of mobile phase are arranged in the two‐dimensional space of mobile phase parameters. The retention behavior of each solute is modeled using an individual artificial neural network. An “early stopping” strategy is adopted to ensure the predicting capability of neural networks. The trained neural networks can be used to predict the retention time of solutes under arbitrary mobile phase conditions in the optimization region. Finally, the optimal separation conditions can be found according to a global resolution function. The effectiveness of this method is validated by optimization of separation conditions for amino acids derivatised by a new fluorescent reagent. 相似文献
96.
C. Gonalves Joaquim C.G. Esteves da Silva M.F. Alpendurada 《Analytica chimica acta》2006,560(1-2):164-171
An extensive monitoring programme of pesticides was carried out in soil samples from an intensive horticulture area in north of Portugal, putting into practice the needs for increased control of soil quality as far as organic pollution is concerned. The area under investigation was additionally defined as vulnerable to nitrates due to local soil and aquifer characteristics, which might be extended to pesticides contamination. Five sampling sites were selected and soils analysed at three depths in eight sampling campaigns, for the period of 2 years. A stepwise multivariate statistical approach was selected to uncover most relevant patterns inside a complex environmental data matrix. Cluster analysis was applied both to group pesticides and samples, giving a primary and unsupervised overlook of privileged relationships. Clusters of persistent pesticides and selected herbicides were identified, whereas sample classes were also formed and disposed geographically. Thirty eight percent of analysed soils samples fell into one class characterized by low contamination (class 1 in cluster analysis), which is entirely representative of the sampling site no. 1. Afterwards, linear discriminant analysis was applied to identify those pesticides, which had a higher impact in the definition of classes. Finally, factor analysis using a five component model was implemented in order to bring to light the constitution and data variance explained by each of the five main principal components, as well as, their relation to pest management practices. A factor was identified (PC1 – 22% variance) composed of chlorinated pesticides, which was representative of one of the investigated sites indicating its high contamination status. Qualitative main findings and class average concentration values were obtained through this multivariate statistical approach. 相似文献
97.
采用乙酸乙酯为环型和线型聚苯乙烯的非良溶剂, 确定了Mark-Houwink方程分别为[η]_r=1.91×10~(-2)·M~(0.607)和[η]_l=4.06×10~(-2)·M~(0.572)。研究了环型和线型聚苯乙烯的激基缔合物的荧光效应。通过稀溶液中环型和线型高分子线团在柔顺性上存在着差异, 解释了二者之间在荧光效应方面的差异, 并根据实验结果,确定了(I_E/I_M)c→0~M关系式分别为(I_E/I_M)r,c→0=1.91+3.40×10~(-6)M和(I_E/I_M)l,c→0=2.15+3.05×10~(-6)M。 相似文献
98.
Bohumír Grüner Jaroslav Ba?kovský Bohumil Štíbr 《Journal of organometallic chemistry》2005,690(11):2850-2852
The compounds with a single and double -CH2C6H4CH2- spacer, [CpFeC3B8H10-NH-CH2C6H4CH2-NH-C3B8H10FeCp] and [CpFeC3B8H10-N-(CH2C6H4CH2)2-N-C3B8H10FeCp], represent the first example of designed shaping by extremely stable cyclopentadienyl-ferratricarbollide (CpFeTCB) cages into rigid molecular constructions approaching linear arrangement. 相似文献
99.
最小一乘稳健多元分析校正 总被引:1,自引:3,他引:1
本文论述最小一乘求解的多元分析校正算法,探讨了最小一乘较常规最小二乘法及其他隐健算法的优点。用计算机数值模拟及实际多组分光谱体系对方法进行了检验,展示了最小一乘法在分析化学计量学中实际应用的可行性。 相似文献
100.