A Zeeman slower based on magnetic dipoles

A transverse Zeeman slower composed of an array of compact discrete neodymium magnets is considered. A simple and precise model of such a slower based on magnetic dipoles is developed. The theory of a general Zeeman slower is modified to include spatial nonuniformity of the slowing laser beam intensity due to its convergence and absorption by slowed atoms. The slower needs no high currents or water cooling and the spatial distribution of its magnetic field can be adjusted. In addition the slower provides a possibility to cool the slowed atoms transversally along the whole length of the slower. Such a slower would be ideal for transportable optical atomic clocks and their future applications in space physics.     

Mind the gap

In this summary of the application of Dyson-Schwinger equations to the theory and phenomenology of hadrons, some deductions following from a nonperturbative, symmetry-preserving truncation are highlighted, notable amongst which are results for pseudoscalar mesons. We also describe inferences from the gap equation relating to the radius of convergence of a chiral expansion, applications to heavy-light and heavy-heavy mesons, and quantitative estimates of the contribution of quark orbital angular momentum in pseudoscalar mesons; and recapitulate upon studies of nucleon electromagnetic form factors.     

Feasibility of narrow-line cooling in optical dipole traps

We have investigated the influence of narrow-line laser cooling on the loading of Ca atoms into optical dipole traps. To describe the narrow-line cooling of alkaline-earth atoms in combination with optical dipole trapping, we have developed a model that takes into account the light shifts of the cooling transition in three dimensions. The model is compared with two experimental realizations of optical dipole traps for calcium at the wavelengths 514 nm and 10.6 μm.     

Di-electrons from η -meson Dalitz decay in proton-proton collisions

The reaction is discussed within a covariant effective meson-nucleon theory. The model is adjusted to data of the subreaction . Our focus is on di-electrons from Dalitz decays of η -mesons, , and the role of the corresponding transition form factor . Numerical results are presented for the intermediate-energy kinematics of HADES experiments.     

In‐situ neutron reflectometry probing competitive swelling and de‐swelling of thin polystyrene films

The competitive penetration of toluene with respect to oxygen, nitrogen and carbon dioxide into a thin and initially dry film of deuterated polystyrene (dPS) is compared to the reverse process of de‐swelling. In‐situ neutron reflectometry is used to follow the swelling and de‐swelling kinetics, allowing the determination of the total dPS thickness, roughness and solvent penetration. Swelling cannot be described in terms of case II diffusion due to the small film thickness and undersaturation results in a small swelling rate of 0.03 nm s^–1. De‐swelling is slower by more than two orders in magnitude, thereby underlining the difficulty to remove once incorporated solvent molecules. (© 2007 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)

     

Synthesis of Zn‐doped talc in hydrothermal atmosphere

Zn‐doped talc were synthesized under hydrothermal conditions at constant reaction time and pressure of 160 hours and 2 kbar respectively, at three different temperatures (300, 500 and 650 °C) with pH‐values of 5 and 7. The starting materials and run products were characterized by X‐ray powder diffraction (XRPD), scanning electron microscopy with annexed energy‐dispersive spectrometry (SEM‐EDS), differential scanning calorimetry thermogravimetric analysis (DSC‐TG) and Fourier transform infrared (FT‐IR). The results showed that the temperature, pH‐value of the reaction mixture and amount of zinc in the starting mixture affected the growth of the Zn‐doped talc. When synthesized at low temperature talc presents low crystallinity, flawed morphology but higher content in zinc in its lattice. A thermal treatment at, or above 500 °C allowed a significant flaw reduction in talc morphology, a higher crystallinity and a lower content in dopant. When large amounts of Zn were present in the starting mixtures, Zn‐doped talc grew small in size and poorly shaped. The effect of Zn doping on some chemical/physical characteristics of the synthesized talc was also discussed.     

Instanton interpolating current for σ-tetraquark

We perform a QCD sum rule analysis for the light scalar meson σ   (f₀(600)$f_0(600)$) with a tetraquark current related to the instanton picture for QCD vacuum. We demonstrate that instanton current, including equal weights of scalar and pseudoscalar diquark–antidiquarks, leads to a strong cancelation between the contributions of high dimension operators in the operator product expansion (OPE). Furthermore, in the case of this current direct instanton contributions do not spoil the sum rules. Our calculation, obtained from the OPE up to dimension 10 operators, gives the mass of σ-meson around 780 MeV.     

Off-shell photon light-cone wave functions with odd chirality

Based on a more reasonable simulation method for dealing with the Λ-parameter characterizing the pole form for the form factor (the Fourier transform of the instanton zero mode), and a unified way for regularizing the integrals appearing in the expressions of the light-cone photon wave functions, the transverse photon wave function (u, P ²) at the leading twist with the on-shell or off-shell momentum have been re-examined in the effective low-energy theory derived from the instanton vacuum, and the twist-two parts of the other two photon wave functions, h ^{(s), twisttwo} _{γ ||} (u, P ²) and h ^{(t), twisttwo} _{γ ||} (u, P ²), with odd chirality are calculated based on the Wandzura-Wilczek-like relations as well. A brief discussion of the dependence of the coupling f _γ ^⊥(P ²) and the light-cone photon wave functions with respect to P² and the end-point behavior of the photon wave functions are given.     

Unraveling the carbene chemistry of oxymethylene ethers: Experimental investigation and kinetic modeling of the high-temperature pyrolysis of OME-2

Oxymethylene ethers (OMEs) form an interesting family of synthetic compounds to replace fossil fuels. This alternative liquid energy carrier can contribute to a circular carbon economy when produced via carbon capture and utilization technology using renewable electricity. Despite the potential to reduce greenhouse gas and particulate matter emissions and their ideal ignition characteristics, little is known about the thermal decomposition behavior of OMEs. In this work, new insights are obtained in the pyrolysis chemistry of oxymethylene ether-2 (OME-2) and the role of carbenes by performing experiments at high temperatures (> 850 K) in a tubular quartz reactor. The used continuous bench-scale pyrolysis unit has a dedicated on-line analysis section including comprehensive two-dimensional gas chromatography (GC $\times$ GC) coupled with flame ionization detection (FID) and mass spectroscopy (MS) to identify and quantify the full product spectrum over the complete temperature range. The reactor temperature was varied between 850 and 1150 K at a fixed pressure of 0.15 MPa and residence times of 400 to 850 ms. The major products are dimethoxymethane, formaldehyde, methyl formate, methane, CO₂, CO and H₂. Minor intermediate compounds comprise dimethyl ether, formic anhydride, formic acid, methoxymethyl formate and methoxymethanol. The yields of compounds with carbon-carbon bonds are low since no such bonds originally occur in OME-2. Precursors of aromatic compounds and soot particles are absent in the reactor effluent. The experimental results are simulated with a new first principles-based kinetic model for pyrolysis and combustion of OME-2. This model can predict the experimental trends of major products on average within the experimental uncertainty margin of ± 10% relative for major product species. A reaction pathway and sensitivity analysis are presented to highlight the importance of the carbenes for initiation of the radical chemistry under pyrolysis conditions.