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11.
Shigeru Arimoto 《Journal of mathematical chemistry》2007,41(3):231-269
The present article is the first part of a series devoted to extending the Repeat Space Theory (RST) to apply to carbon nanotubes
and related molecular networks. Four key problems are formulated whose affirmative solutions imply the formation of the initial
investigative bridge between the research field of nanotubes and that of the additivity and other network problems studied
and solved by using the RST. All of these four problems are solved affirmatively by using tools from the RST. The Piecewise
Monotone Lemmas (PMLs) are cornerstones of the proof of the Fukui conjecture concerning the additivity problems of hydrocarbons.
The solution of the fourth problem gives a generalized analytical formula of the pi-electron energy band curves of nanotube
(a, b), with two new complex parameters c and d. These two parameters bring forth a broad class of analytic curves to which the PMLs and associated theoretical devices apply.
Based on the above affirmative solutions of the problems, a central theorem in the RST, called the asymptotic linearity theorem
(ALT) has been applied to nanotubes and monocyclic polyenes. Analytical formulae derived in this application of the ALT illuminate
in a new global context (i) the conductivity of nanotubes and (ii) the aromaticity of monocyclic polyenes; moreover an analytical
formula obtained by using the ALT provides a fresh insight into Hückel’s (4n+2) rule. The present article forms a foundation of the forthcoming articles in this series.
The present series of articles is closely associated with the series of articles entitled ‘Proof of the Fukui conjecture via
resolution of singularities and related methods’ published in the JOMC. 相似文献
12.
Shigeru?ArimotoEmail author Mark?Spivakovsky Keith?F.?Taylor Paul?G.?Mezey 《Journal of mathematical chemistry》2005,37(2):171-189
The present article is a direct continuation of the first part of this series. We reduce a proof of the Fukui conjecture (concerning the additivity problem of the zero-point vibrational energies of hydrocarbons) to that of a proposition related to the theory of algebraic curves, so that we can focus on the key mechanism of the additivity phenomena. Namely, by establishing what is called the Basic Piecewise Monotone Theorem (BPMT), we reduce a proof of the Fukui conjecture to that of a proposition, called the Local Analyticity Proposition, Version 1 (LAP1), which admits a proof via resolution of singularities. By LAP1, the essential part of the mechanism of the asymptotic linearity phenomena is extracted and is elucidated by using tools from the mathematical theory of algebraic curves, whose language is of vital importance in analyzing the crux of the additivity mechanism.
Dedicated to the memory of Prof. Kenichi Fukui (1918–1998). 相似文献
13.
Beatriz Pascual-Escudero 《Journal of Pure and Applied Algebra》2019,223(6):2598-2614
Let X be an algebraic variety defined over a field of characteristic zero, and let be a point in the closed subset of maximum multiplicity of X. We provide a criterion, given in terms of arcs, to determine whether ξ is isolated in . More precisely, we use invariants of arcs derived from the Nash multiplicity sequence to characterize when ξ is an isolated point in . 相似文献
14.
In this paper, we prove controllability results for a two-dimensional semilinear heat equation with mixed boundary conditions. It is well-known that mixed boundary conditions can present a singular behaviour of the solution. First, we will prove global Carleman estimates then we will use these inequalities to obtain controllability results. 相似文献
15.
We present here a fine singularity analysis of solutions to the Laplace equation in special polygonal domains in the plane. We assume piecewise constant Neumann data on one component of the boundary. Our motivation is to study the so‐called Berg effect, which is explained in the introduction. Copyright © 2014 John Wiley & Sons, Ltd. 相似文献
16.
The phenomenon of a topological monodromy in integrable Hamiltonian and nonholonomic systems is discussed. An efficient method for computing and visualizing the monodromy is developed. The comparative analysis of the topological monodromy is given for the rolling ellipsoid of revolution problem in two cases, namely, on a smooth and on a rough plane. The first of these systems is Hamiltonian, the second is nonholonomic. We show that, from the viewpoint of monodromy, there is no difference between the two systems, and thus disprove the conjecture by Cushman and Duistermaat stating that the topological monodromy gives a topological obstruction for Hamiltonization of the rolling ellipsoid of revolution on a rough plane. 相似文献
17.
This paper deals with secondary bifurcations near a double eigenvalue of a nonlinear equation with two parameters. Utilizing symmetries (or more generally, equivariances ) and introducing two new parameters, we give some extended systems so that the double singular points, secondary bifurcation points and initial secondary branches respectively become their regular solutions. The methods in this paper not only give more general conditions of secondary bifurcation but also avoid the adjacent singularities of existing extended systems for computing the simple bifurcation points on non-trivial solution branches A numerical example is presented, showing the effectiveness of our methods. 相似文献
18.
The Index of Cusp Operators on Manifolds with Corners 总被引:3,自引:0,他引:3
We recall a Fredholm criterion for fully elliptic cusp(pseudo)differential operators on a compact manifold with corners ofarbitrary codimension, acting on suitable Sobolev spaces. Then we give aformula for the index in terms of regularized `trace' functionalssimilar to the residue trace of Wodzicki and Guillemin. 相似文献
19.
Affine-Invariant Distances, Envelopes and Symmetry Sets 总被引:3,自引:0,他引:3
Affine invariant symmetry sets of planar curves are introduced and studied in this paper. Two different approaches are investigated. The first one is based on affine invariant distances, and defines the symmetry set as the closure of the locus of points on (at least) two affine normals and affine-equidistant from the corresponding points on the curve. The second approach is based on affine bitangent conics. In this case the symmetry set is defined as the closure of the locus of centers of conics with (at least) 3-point contact with the curve at two or more distinct points on the curve. This is equivalent to conic and curve having, at those points, the same affine tangent, or the same Euclidean tangent and curvature. Although the two analogous definitions for the classical Euclidean symmetry set are equivalent, this is not the case for the affine group. We present a number of properties of both affine symmetry sets, showing their similarities with and differences from the Euclidean case. We conclude the paper with a discussion of possible extensions to higher dimensions and other transformation groups, as well as to invariant Voronoi diagrams. 相似文献
20.
Acceleration waves propagating in isotropic solids at finite temperatures are studied by applying the method of singular surfaces to a new continuum model derived statistical-mechanically from a three-dimensional lattice model. The continuum model explicitly takes into account the microscopic thermal vibrations of the constituent atoms as one of the field variables. The propagation speeds and the ratios of mechanical and thermal amplitudes for both longitudinal and transverse waves are consistently determined. The differential equations that govern the time variation of the amplitudes of the waves are also derived. The analytical results, which are valid over a wide temperature range that includes the melting point, are evaluated numerically for several materials, and their physical implications are discussed. One of the findings to be emphasized is that of the singularities of the characteristic quantities at the melting point.Received: 13 March 2003, Accepted: 20 June 2003PACS:
62.30. + d, 65.40.-bM. Sugiyama: Correspondence to
Dedicated to Prof. Ingo Müller on the occasion of his 65th birthday. 相似文献