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151.
152.
The effect of Al substitution for Fe on crystal structure, magnetostriction and spontaneous magnetostriction, anisotropy and spin reorientation of a series of polycrystalline Tb0.3Dy0.7(Fe1-xAlx)1.95 alloys (x = 0, 0.05, 0.1, 0.15, 0.20, 0.25, 0.30, 0.35) at room temperature and 77 K was investigated systematically. It was found that the primary phase of Tb0.3Dy0.7(Fe1-xAlx)1.95 is the MgCu2-type cubic Laves phase structure when x < 0.4 and the lattice constant a of Tb0.3Dy0.7(Fe1-xAlx)1.95 increases approximately and monotonically with the increase of x. The substitution of Al leads to the fact that the magnetostriction ( inceases slightly in a low magnetic field (H ≤ 40 kA/m), but decreases sharply and is easily close to saturation in a high applied field as x increases, showing that a small amount of Al substitution is beneficial to a decrease in the magnetocrystalline anisotropy. It was also found that the spontaneous magnetostriction (ζ)111 decreases greatly with x increasing. The analysis of the M(o)ssbauer spectra indicated that the easy magnetization direction in the {110} plane deviates slightly from the main axis of symmetry with the changes of composition and temperature, namely spin reorientation. A small amount of non-magnetic phase exists for x = 0.15 in Tb0.3Dy0.7(Fe1-xAlx)1.95 alloys and the alloys become paramagnetic for x > 0.15 at room temperture, but at 77 K the alloys still remain magnetic phase even for x = 0.2. At room temperature and 77 K, the hyperfine field decreases and the isomer shifts increase with Al concentration increasing. 相似文献
153.
154.
m‐Methoxy Substituents in a Tetraphenylethylene‐Based Hole‐Transport Material for Efficient Perovskite Solar Cells
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Dr. Fei Wu Jianlin Liu Gang Wang Prof. Qunliang Song Dr. Linna Zhu 《Chemistry (Weinheim an der Bergstrasse, Germany)》2016,22(46):16636-16641
Three tetrapheynlethylene derivatives (N,N‐di(4‐methoxyphenyl)aminophenyl‐substituted tetraphenylethylene; TPE‐4DPA) with different methoxy positions (pp‐, pm‐, and po‐) have been synthesized and characterized. The methoxy groups can control the oxidation potential of the materials, and the electronic properties of the derivatives were affected by the position of the methoxy substituents. These compounds were synthesized in a facile and cost‐effective way, and were applied as hole‐transport materials in perovskite solar cells. The corresponding cell performances were compared with respect to their structure modifications, and it was found that the derivative with m‐OMe substituents showed the highest power conversion efficiency (PCE) of 15.4 %, with a Jsc value of 20.04 mA cm?2, a Voc value of 1.07 V, and a fill factor (FF) value of 0.72, which is higher than the p‐OMe and o‐OMe substituents. Moreover, the PCE of pm‐TPE‐4DPA is comparable with that of the state‐of‐the‐art 2,2′,7,7′‐tetrakis(N,N′‐di‐p‐methoxyphenylamine)‐9,9′‐spirobifluorene under identical conditions. 相似文献
155.
Alain Messager 《Journal of statistical physics》2002,106(3-4):785-810
The Falicov–Kimball (FK) model(1) involves two types of interacting particles: first the itinerant spinless electrons are quantum particles, secondly the static ions are classical particles. It is striking to see that, despite the simplicity of its hamiltonian, the phase diagram of the FK model is highly sophisticated, moreover it remains in great part conjectural. An antiferromagnetic phase transition was proven for the FK model on a square lattice in the seminal paper of T. Kennedy and E. Lieb.(2) This result was extended by Lebowitz and Macris(3) to small magnetic field. Then the same result was obtained by using a new method.(4) The main results of this paper concerns the two dimensional FK model on a square lattice, for which we apply the general results contained in ref. 5. First there exists an effective hamiltonian which is a long range many body Ising model, and which governs the behaviour of the ions. Secondly we compute explicitly the truncated effective hamiltonian up to the fourth order w.r.t. a small parameter (the inverse of the on site energy). Finally we use the classical Pirogov–Sinai theory, to get the hierarchy of the phase diagrams up to the fourth order. More precisely, we show that, when the chemical potential varies, the FK model exhibits, at low temperature, a sequence of phase transitions: first between phases of period two, then of period three, then of period four, and finally of period five. In each case the completeness of the phase diagram is proved. This paper supports the conjecture that the phase diagram of the FK model contains periodic phases outside of a Cantor set. 相似文献
156.
Ph. Boullay G. TrolliardD. Mercurio J.M. Perez-MatoL. Elcoro 《Journal of solid state chemistry》2002,164(2):252-260
A generalized structural model of Aurivillius-type compounds is presented using a 4D superspace group analysis where Aurivillius structures are considered as cation-deficient perovskites with the general formula AB1−xO3. Being essentially composition independent, the model is valid for any Aurivillius-type compounds where x is the only composition-dependent parameter. The atomic domains representing the atoms in superspace are described by means of crenel functions. For any composition, the conventional space groups can be easily derived from a unique superspace group. This work is supported by a TEM investigation where the continuously variable character of the diffraction diagram indicates that the various stacking sequences can be interpreted in terms of a structural modulation over a common average structure. 相似文献
157.
158.
Pedro MaroteBernard Durand Jean-Pierre Deloume 《Journal of solid state chemistry》2002,163(1):202-209
Zirconia powders are prepared by reaction of a zirconium precursor with an alkali metal nitrate. The major part of the reactions takes place before the melting points and then the reactions go slowly to completion at 450°C in the molten salts. The roles of the precursor and the alkali metal ion are discussed considering the reaction between two precursors, octahydrated zirconium oxychloride and zirconium tetrachloride, and two nitrates, LiNO3 and NaNO3, and some resulting physico-chemical differences. The obtained zirconia powders contain very small amounts of alkali metal ions which act as stabilizing agent. Their effect on the balance tetragonal-monoclinic ZrO2 depends upon the homogeneity of their distribution which is related to their ability to diffuse inside the bulk of particles and their polarizing power when located mainly on the surface. 相似文献
159.
Alain Messager 《Journal of statistical physics》2002,106(3-4):723-783
We study a large class F
of models of the quantum statistical mechanics dealing with two types of particles. First the spinless electrons are quantum particles obeying to the Fermi statistics, they can hop. Secondly the ions which cannot move, are classical particles. The Falicov–Kimball (FK) model(1) is a well known model belonging to F, for which the existence of an antiferomagnetic phase transition was proven in the seminal paper of Kennedy and Lieb.(2) This result was extended by Lebowitz and Macris.(3) A new approach to this problem based on quantum selection of the ground states was proposed in ref. 4. In this paper we extend this approach to show that, under the strong insulating condition, any hamiltonian of the class F admits, at every temperature, an effective hamiltonian, which governs the behaviour of the ions interacting through forces mediated by the electrons. The effective hamiltonians are long range many body Ising hamiltonians, which can be computed by a cluster expansion expressed in term of the quantum fluctuations. Our main result is that we can apply the powerfull results of the classical statistical mechanics to our quantum models. In particular we can use the classical Pirogov–Sinai theory to establish a hierarchy of phase diagrams, we can also study of the behaviour of the quantum inter- faces,(29) and so on... 相似文献
160.
Joel L. Lebowitz 《Journal of statistical physics》1977,16(6):463-476
We derive a new inequality for ferromagnetic Ising spin systems and then use it to obtain information about the number of phases which can coexist in such systems. We show in particular that for even interactions only two phases (up and down magnetization) can coexist below the critical temperature at zero magnetic field (h=0) whenever the energy is a continuous function of the temperature. We also prove that the derivatives with respect toh ath=0 of the odd correlation functions (triplet,...) diverge like the susceptibility in the vicinity of the critical temperature (at least for pair interactions). Our results also apply to higher order Ising spins (not just spin 1/2).Research supported in part by NSF Grant #MPS 75-20638 and USAFOR Grant #73-2430D.John Simon Guggenheim Fellow. 相似文献