全文获取类型
收费全文 | 38319篇 |
免费 | 4770篇 |
国内免费 | 2790篇 |
专业分类
化学 | 12648篇 |
晶体学 | 163篇 |
力学 | 5736篇 |
综合类 | 554篇 |
数学 | 11286篇 |
物理学 | 15492篇 |
出版年
2024年 | 80篇 |
2023年 | 390篇 |
2022年 | 1038篇 |
2021年 | 1005篇 |
2020年 | 1237篇 |
2019年 | 1075篇 |
2018年 | 1038篇 |
2017年 | 1370篇 |
2016年 | 1604篇 |
2015年 | 1259篇 |
2014年 | 1917篇 |
2013年 | 2854篇 |
2012年 | 2249篇 |
2011年 | 2440篇 |
2010年 | 2080篇 |
2009年 | 2359篇 |
2008年 | 2218篇 |
2007年 | 2295篇 |
2006年 | 1983篇 |
2005年 | 1707篇 |
2004年 | 1609篇 |
2003年 | 1389篇 |
2002年 | 1322篇 |
2001年 | 1031篇 |
2000年 | 1042篇 |
1999年 | 954篇 |
1998年 | 864篇 |
1997年 | 714篇 |
1996年 | 583篇 |
1995年 | 578篇 |
1994年 | 493篇 |
1993年 | 400篇 |
1992年 | 382篇 |
1991年 | 297篇 |
1990年 | 283篇 |
1989年 | 226篇 |
1988年 | 217篇 |
1987年 | 198篇 |
1986年 | 161篇 |
1985年 | 170篇 |
1984年 | 181篇 |
1983年 | 92篇 |
1982年 | 122篇 |
1981年 | 79篇 |
1980年 | 50篇 |
1979年 | 54篇 |
1978年 | 41篇 |
1977年 | 35篇 |
1976年 | 23篇 |
1973年 | 25篇 |
排序方式: 共有10000条查询结果,搜索用时 0 毫秒
11.
Mass distributions of fragments in the low-energy fission of nuclei from 187Ir to 213At have been analysed. This analysis has shown that shell effects in symmetric-mode fragment mass yields from the fission of pre-actinide nuclei could be described if one assumes the existence of two strongly deformed neutron shells in the arising fragments with neutron numbers N1 ≈ 52 and N2 ≈ 68. A new method has been proposed for quantitatively describing the mass distributions of the symmetric fission mode for pre-actinides with A ≈ 180–220. 相似文献
12.
In [5] Phillips proved that one can obtain the additive group of any nonstandard model *? of the ring ? of integers by using a linear mod 1 function h : F ?, where F is the α-dimensional vector space over ? when α is the cardinality of *?. In this connection it arises the question whether there are linear mod 1 functions which are neither addition nor quasi-linear. We prove that this is the case. 相似文献
13.
在工农业产品评定级别中,专家组的水平是至关重要的。文中给出一个挑选专家组成员的数学模型,可以检验专家对参评产品的决策水平,为评价所评结论的可信度提供参考依据。 相似文献
14.
This research extends previous work with dynamic models to manage groundwater quality by using the consumptive nitrate use rate instead of the nitrate application rate. The analysis indicates that misspecification results in overestimation of economic benefits, and supra-optimum nitrogen fertilizer application rates and groundwater nitrate stocks at a steady state. 相似文献
15.
Semi-empirical molecular orbital calculations were carried out for the compounds (C2H5)3As, (C2H5)3Ga and RAsH2 (R = C2H5, i-C3H7, i-C4H9, and t-C4H9) by using the CNDO/2-U program, and their capability of β-elimination reaction is compared on the basis of the torsion energy to the transition state, electrostatic interactions and orbital overlapping between the central atom and the β-hydrogen, and bond order of the metal-carbon, and carbon-hydrogen bond. In the comparison of (C2H5)3As with (C2H5)3Ga, we found that the β-elimination of (C2H5)3As could hardly be expected to take place in the thermal decomposition. The capability of β-elimination would be smaller in C2H5AsH2 than that in (C2H5)3As. Moreover when the ethyl group is replaced by a t-butyl group in RAsH2, the β-elimination reaction appears to become more difficult and a large possibility for a radical process is suggested. 相似文献
16.
17.
The hydrocarbon discovery prediction problem is important to firms having to make decisions about the deployment of scarce exploration resources. Traditional methods for estimating the discovery rate rely on the completion of time consuming simulation experiments. A rapid approximation that does not require the completion of simulation exists and has been shown to have some promise as a prediction tool. This paper investigates the accuracy of the approximation method under a wide variety of distributional and drilling efficiency assumptions. The results indicate that the approximation produces predictions close to those of simulation under most of the tested conditions. This suggests that resource exploration firms could conveniently use the method for a wide variety of planning purposes without incurring the same costs in time and personnel required for simulation. 相似文献
18.
This contribution discusses the phenomena of retrograde condensation of one or two liquids. It w1 be shown that both phenomena can be well understood. Also the relation of retrograde condensation of one liquid phase with the condensation behavior of natural gas will be discussed. Similarly that of two liquid phases with multiple phase behavior occurring in low temperature reservoir fluids will be pointed out. 相似文献
19.
Hiroshi Ito Masaki Okazaki Dolores C. Miller 《Journal of polymer science. Part A, Polymer chemistry》2004,42(6):1478-1505
Radical copolymerizations of electron‐deficient 2‐trifluoromethylacrylic (TFMA) monomers, such as 2‐trifluoromethylacrylic acid and t‐butyl 2‐trifluoromethylacrylate (TBTFMA), with electron‐rich norbornene derivatives and vinyl ethers with 2,2′‐azobisisobutyronitrile as the initiator were investigated in detail through the analysis of the kinetics in situ with 1H NMR and through the determination of the monomer reactivity ratios. The norbornene derivatives used in this study included bicyclo[2.2.1]hept‐2‐ene (norbornene) and 5‐(2‐trifluoromethyl‐1,1,1‐trifluoro‐2‐hydroxylpropyl)‐2‐norbornene. The vinyl ether monomers were ethyl vinyl ether, t‐butyl vinyl ether, and 3,4‐dihydro‐2‐H‐pyran. Vinylene carbonate was found to copolymerize with TBTFMA. Although none of the monomers underwent radical homopolymerization under normal conditions, they copolymerized readily, producing a copolymer containing 60–70 mol % TFMA. The copolymerization of the TFMA monomer with norbornenes and vinyl ethers deviated from the terminal model and could be described by the penultimate model. The copolymers of TFMA reported in this article were evaluated as chemical amplification resist polymers for the emerging field of 157‐nm lithography. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 1478–1505, 2004 相似文献
20.
In this paper, we discuss the local and global existence ofweak solutions for some hyperbolicparabolic systems modellingchemotaxis. 相似文献