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71.
72.
Wenping Deng Gang Xu Lei Wan Anwen Liu Bo Gao Junhe Du Shuiming Hu Yang Chen 《Acta Physico》2008,24(8):1329-1334
Apparatus integrating a Fourier transform-infrared (FT-IR) spectrometer and a mid-infrared difference frequency generation (DFG) laser spectrometer was built for the study of the matrix isolation spectrum in solid molecular hydrogen. A 3-cm-long molecular hydrogen crystal was grown in a liquid-helium Dewar, and its infrared absorption spectrum in the 1-5 μm region was recorded to test the system. The W0(0) (ν=0←0, J=6←0) line around 2410 cm−1 of solid hydrogen was investigated with the DFG laser spectroscopy. High-resolution matrix isolation spectrum of CO2 co-deposited with hydrogen on a BaF2 cold plate at liquid-helium temperature was studied. 相似文献
73.
Michael C. W. Chan Dr. 《化学:亚洲杂志》2008,3(1):18-27
The notion of weak attractive ligand–polymer interactions is introduced, and its potential application, importance, and conceptual links with “cooperative” ligand–substrate interactions are discussed. Synthetic models of weak attractive ligand–polymer interactions are described, in which intramolecular weak C? H???F? C interactions (the existence of which remains contentious) have been detected by NMR spectroscopy and neutron and X‐ray diffraction experiments. These C? H???F? C interactions carry important implications for the design of catalysts for olefin polymerization, because they provide support for the practical feasibility of ortho‐F???Hβ ligand–polymer contacts proposed for living Group 4 fluorinated phenoxyimine catalysts. The notion of weak attractive noncovalent interactions between an “active” ligand and the growing polymer chain is a novel concept in polyolefin catalysis. 相似文献
74.
75.
We propose a perturbation theory that allows solving the equations of motion for the displacement vector in the body of the Earth in the framework of the linear theory of elasticity. We show that tectonic processes are primarily determined by tidal actions. We analyze the tidal effects in the Earth–Moon–Sun system. 相似文献
76.
Sharmistha Dutta Choudhury 《Journal of luminescence》2007,124(1):33-38
Laser flash photolysis of phenazine (PZ) solution reveals the existence of a stable species with a long lifetime at 380 nm in addition to the usual triplet PZ at 440 nm. The former is suggested to be due to formation of triplet PZ excimer. The triplet excimer also undergoes photoinduced electron transfer with some aromatic amines. The formation of PZ dimer anion radical and amine cation radicals are confirmed by external magnetic field effect studies. Measurement of B1/2, which estimates hyperfine present in the system, also supports this assignment. 相似文献
77.
闪光灯泵浦的Nd:KGd(WO4)2激光器 总被引:1,自引:0,他引:1
报道了用闪光灯泵浦的掺钕的钨酸钆镓(Nd3+:KGd(WO4)2激光器.在重复频率1Hz,脉宽120μs的灯泵下,测量了不同透过率下激光输出能量,获得最大输出能量384mJ,斜率效率1.0%,外推阈值0.54J.在调Q运行时,Nd:KGW晶体的斜率效率为0.16%,最大输出能量46mJ. 相似文献
78.
Pure gas sorption and transport properties of polyesters based on bisphenol-A and both pure isophthalic and pure terephthalic acid chloride were obtained for He, N2, O2, CH4, and CO2 at 35°C. The polymers were synthesized in our laboratory and amorphous films were prepared with a specialized solvent casting procedure. The polymer containing m-phenylene groups shows higher permselectivity for most of the gas pairs. The ideal selectivity of O2/N2 was increased by 33% when p-phenylene units were replaced by m-phenylene ones. On the other hand, the polyester containing only p-phenylene groups, shows higher permeability to all the gases studied. The polymer based on pure terephthalic acid chloride has a 75% higher oxygen permeability and a 1.1-fold higher carbon dioxide permeability than the isophthalic acid derivative. The polyester containing meta-phenylene units has lower Tg, higher permselectivity, lower permeability, lower fractional free volume (FFV), and lower d-spacing. The values of FFV, and lower d-spacing. The values of FFV and d-spacing were only slightly different between the two isomers. Moreover, for the sub-Tgγ transition the maximum in tan δ occured at essentially the same temperature (?55°C). The polymer with a higher concentration of p-phenylene units shows somewhat larger area under the γ-peak, indicating slightly more sub-Tg motion. The Distribution of FFV is considered to be the determining factor for the differences in transport properties observed. © 1993 John Wiley & Sons, Inc. 相似文献
79.
80.
M. Stenger S. Baumhoff J.-Y. Prieur J. Joffrin J.-P. Contour 《The European Physical Journal B - Condensed Matter and Complex Systems》1998,2(2):177-182
We present measurements of the attenuation and phase velocity of surface acoustic waves in thin YBa2Cu3O films as a function of temperature, in magnetic fields up to 3.6 T applied parallel to the c-axis of the films. We have observed anomalies in both, the attenuation and the phase velocity in the vicinity of the superconducting
critical temperature which do not depend on the magnetic field. Possible origins of these anomalies, observed, to our knowledge,
for the first time in YBa2Cu3O thin films, are discussed and compared to bulk acoustic wave experiments. We present a kind of feedback technique for surface
acoustic waves which improves the sensitivity of this type of measurement. The actual sensitivity limits are mentioned.
Received: 7 August 1997 / Revised: 7 November 1997 / Accepted: 17 November 1997 相似文献