高亮度白光LED用外延片的新进展

文章首先介绍了发光二极管（LED）的内量子效率、外量子效率的基本概念和提高量子效率的基本方法，接着对LED外延的结构和方法做了简要介绍．文章的第三和第四部分则着重介绍了提高内、外量子效率的外延方法，这些方法包括外延结构的优化，侧向外延生长，SiC和GaN衬底的生长，AIInGaN四元系有源区生长，非极性面、半极性面的外延，表面粗化结构生长，图形化二次外延结构．图形化蓝宝石衬底上的外延，提高载流子注入效率的结构和组分设计．文章的第五部分则介绍了基于可靠性和成本考虑的其他新型外延结构，第六部分介绍了提高LED可靠性的外延方法．最后得出结论：采用非极性面的GaN衬底，生长优化的LED结构，并结合光子晶体技术，可望取得突破性进展．     

微型投影机光学引擎的研究

设计了一种针对个人用户使用的微型投影机光学引擎,系统为单片式数字光线处理器结构,采用红绿蓝三色大功率高亮度发光二极管作为光源,使用X棱镜作为合色元件,从而实现38.1～50.8 cm的彩色投影显示.对设计结果进行理论分析后可知,设计结果满足投影显示对颜色的要求,光学引擎的理论效率为16.1%.同时利用Light Tools仿真软件对系统进行建模分析,300万条光线追迹仿真的结果表明,光学引擎的效率为14.6%,与理论分析结果基本符合,屏幕上光通量为22.8 lm,其美国国家标准协会规定的九点照度均匀性达到91.55%和-93.36%,满足设计要求.     

利用LED的投影系统光源设计

设计了利用多颗LED(Light Emitting Diode,发光二极管)阵列组成的扩展面光源.经过合理的聚光设计使之符合某些投影设备对亮度要求不是很高,但结构紧凑、性能稳定、使用寿命长的要求.结合数学建模和软件模拟的方式设计了一种小巧的反光杯,利用反光杯把LED近180°的发散光束汇聚到60°左右;然后再用一一对应的透镜阵列汇聚为平行光;最后采用柯勒照明方式把较大的面光源阵列汇集到LCD投影屏幕上,从而达到了较高亮度且具有很高均匀性的目的.     

An investigation into EMI-induced noise in nanometer multi-quantum well InGaN LEDs

This study investigates the low-frequency noise induced by electromagnetic radiation interference (EMI) in a nanometer multi-quantum well InGaN LED (NMQLED). Theoretical models of the noise spectra and the EMI are constructed. In general, a good agreement is identified between the experimental and theoretical results. Both sets of results reveal that the magnitude of the EMI-induced noise is related to the pulse height, the output load, the parasitic capacitance, the interference frequency and the interference amplitude. It is shown that the harmonic noise increases with an increasing interference amplitude and frequency. The techniques presented in this study provide a systematic approach for obtaining the interference noise and signal-to-noise ratio (SNR) in LEDs and similar wavelength-based semiconductor devices.     

Application of diffusion‐edited NMR spectroscopy for selective suppression of water signal in the determination of monomer composition in alginates

Alginate is a linear copolymer of 1‐4 linked β‐D ‐mannuronic acid (M) and 1‐4 linked α‐L ‐guluronic acid (G). The physical properties of these polysaccharides such as gel properties and viscosity are largely correlated to the monomer composition (M/G ratio), the sequence of the polymer and the molecular weight. Determination of the M/G ratio is therefore important and NMR spectroscopy is among the most common methods used to accurately obtain this ratio. Instead of using time consuming, possibly sample altering, acid hydrolysis to reduce the viscosity of the alginate sample prior to analysis, samples of low concentrations can be used. However, this results in a water peak in the NMR spectrum that is several orders of magnitude larger than the alginate signals and water suppression is required. In this article, a diffusion‐edited NMR experiment that suppresses the water peak while retaining the signals of interest has been used to enable correct M/G ratio determination. This approach exploits the difference in translational diffusion between the larger alginate molecules and the smaller water molecules. Using this method, the monomer composition of 20 different alginate powders was determined. The diffusion parameters were optimized to allow measurement for samples covering a large range of M/G ratios and viscosities. Thus, such method should be useful for analyzing large numbers of unknown alginate samples using, for example, automation procedures. Copyright © 2011 John Wiley & Sons, Ltd.     

光子晶体几何结构设计对LED出光效率影响的研究

利用禁带理论、等效介质理论分析了增透机理,研究了一种参数设计方法.采用FDTD方法计算了表面覆盖ITO层的六角排列圆形光子晶体出光效率.计算该结构参数的光子晶体的LED出光效率,结果表明加入ITO层的光子晶体能提高GaN基蓝光LED出光效率2倍,该参数设计思路也为光子晶体设计提供了参考依据.     

Crystallization kinetics of SrBi<Subscript>2</Subscript>B<Subscript>2</Subscript>O<Subscript>7</Subscript> glasses by non-isothermal methods

In the photomicrocalorimetric module designed by Johansson and Wadsö for a commercial Thermometric TAM heat conduction batch microcalorimeter, the incident light from an external xenon lamp was divided by a beam splitter and directed to the two vessels of the differential system by light guides ideally to give zero heat flow. In practice this proved difficult and so to improve the balance between the vessels in terms of the incident light heat output as well as potentially to give more versatility regarding the choice of wavelengths, the xenon lamp-based system was replaced in the first stage by a pair of cold white LEDs embedded directly in the test and reference vessels. The LEDs had independent electrical circuits to achieve the balance by manual adjustment. As a second stage, the test vessel was equipped with PTFE tubing for changing the liquid phase in it while it was in the middle thermal equilibrium position. This improved the reproducibility of the results.     

Structure–property studies and orientation effects of polythiophenes containing mesogenic side chains

Liquid crystalline materials display unique properties, which can be exploited in organic light emitting diodes. Polythiophene model compounds containing phenyl groups linked with azomethine, ester, and alkoxy groups [thiophene‐3‐alkyloxy benzoyloxy aniline series (N series) and thiophene‐3‐alkoxy phenoxy amino benzoate series (R Series)] were synthesized. Molecular orbital calculations were performed and the predicted band gaps compared to understand the effects of spacer length and linkage. The experimental photoabsorption characteristics are compared with the theoretically predicted band gap. Photoabsorption and emission studies on N series and R series polymers as the function of polarizer angle suggest that polymers of both series emit polarized light in all base color ranges. The electroemission characteristics of the above‐synthesized polymers were also recorded as the function of polarizer angle. The results show that the compounds also emit polarized electroemission, and the EL polarization ratio decreases with the increase of alkoxy chain length for N and R polymers. © 2008 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 46: 1463–1477, 2008     

Bipolar copolymers comprised mesogen‐jacketed polymer containing oxadiazole units and PVK as host materials for electroluminescent devices

Nonconjugated bipolar transport polymers have been developed as host materials for electroluminescent devices by incorporating both electron‐transporting and hole‐transporting functionalities into copolymers. The random copolymer PCt‐nvk3‐7 containing mesogen‐jacketed segment of P‐Ct have been synthesized and characterized. The effect of mesogen‐jacketed segment content of these bipolar copolymers on device performance has been investigated. The results of polymer light‐emitting diodes (PLEDs) show that the jacketed content of copolymers has a significant effect on device performance: lowering charge transport and facilitating the hole‐electron recombination leads to much higher current efficiency. Applying these high triplet random copolymers as host, the maximum current efficiency of 0.70 cd/A and the maximum brightness of 1872.8 cd/m² was achieved for PCt‐nvk3‐7 with an orange‐emitting complex dopant. The results suggest that the bipolar copolymers PCt‐nvks can be good host polymers for electrophosphorescent devices. © 2008 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 46: 7861–7867, 2008     

Blue-excited luminescence of Eu-doped strontium boroaluminate glasses

We report on a blue-excited luminescence phenomenon in Eu²⁺-doped strontium boroaluminate glasses in this paper. The emission wavelengths strongly depend on the B₂O₃ content in the glasses, changing hue from green to yellow. The excitation spectra exhibit a peculiar blue excitation window that the excitation at UV band is strongly depressed and at blue band is enhanced correspondingly. The low emission quantum efficiency in the glasses can be significantly improved by forming a strontium boroaluminate glass-ceramics, accompanying with the window disappearance.