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101.
Tavorite‐structured oxyphosphates, fluorophosphates, oxysulfates, and fluorosulfates are evaluated for use as cathode materials in lithium ion batteries and activation energies for lithium diffusion through LiVO(PO4), LiV(PO4)F, and LiFe(SO4)F are calculated. 相似文献
102.
We have investigated the effects of screened Coulomb (Yukawa) potentials on the bound 1,3D states and the doubly excited 1,3 De resonance states of helium atom using highly correlated exponential basis functions. The Density of resonance states are calculated using stabilization method. Highly correlated exponential basis functions are used to consider the correlation effect between the charged particles. A total of 18 resonances (nine each for 1 De and 3 De states) below the n = 2 He + threshold has been calculated. For each spin states, this includes four members in the 2pnp series, three members in the 2snd series, and two members in 2pnf series. The resonance energies and widths for various screening parameters ranging from infinity to a small value for these 1,3 De resonance states are reported along with the bound‐excited 1s3d 1,3 D state energies. Overall behavior of the spectral profile of 1s3d 1D state of helium atom due to electron‐electron and electron‐nucleus screening are also presented. Accurate resonance energies and widths are also reported for He in vacuum. © 2009 Wiley Periodicals, Inc. Int J Quantum Chem, 2010 相似文献
103.
Atomistic simulation of site preference, Curie temperature, and lattice vibration of Nd2Co7 - xFex 下载免费PDF全文
The effects of Fe substitution for Co on the structural stability and the site preference of intermetallics Nd 2 Co 7-x Fe x with a hexagonal Ce 2 Ni 7-type structure are studied by using a series of interatomic pair potentials.In Nd 2 Co 7-x Fe x,Fe atoms are substituted for Co atoms with a strong preference for the 6h sites and the order of site preference is 6h,4e,4f,2a,and 12k.Calculated lattice parameters are found to be consistent with the reported results in the literature.The variation behaviour of the Curie temperature of Nd 2 Co 7-x Fe x is explained qualitatively by the exchange interaction model.The properties related to lattice vibration,such as phonon density of states and Debye temperature,are first evaluated for the Nd 2 Co 7-x Fe x compounds. 相似文献
104.
Lina Guo Jiulin Du 《Physica A》2011,390(2):183-188
The generalized Gibbs free energy and enthalpy are derived in the framework of nonextensive thermodynamics by using the concept of the physical temperature and the physical pressure. Some relations of the thermodynamical potentials are changed due to the difference between the physical temperature and the inverse of Lagrange multiplier. We derive the thermodynamical relation between the heat capacities at a constant volume and at a constant pressure using the generalized thermodynamical potential. We find that it has a different form from the traditional one in Gibbs thermodynamics. But, the expressions of the heat capacities in this framework using the generalized thermodynamical potentials are still the same as the traditional one. 相似文献
105.
本文研究下面的非周期离散非线性Schrödinger 方程:
-Δun + vnun - ωun = gn(un),n ∈ Z,
其中V = {vn}n∈Z 和gn 都是非周期的,当|n| → +∞ 时,vn → +∞,并且时间频率ω ∈ R 可以满足下面的任何一种情形:(1)ω 属于算子-Δ + V 的一个有限谱间隔;(2)ω < inf σ(-Δ + V);(3)ω ∈ σ(-Δ+ V),其中σ(-Δ+ V)表示-Δ+ V的谱. 本文将用一些局部条件(在无穷远或零处)来代替一些全局条件. 利用变化的喷泉定理,当非线性项在无穷远处是超线性时,本文得到这个方程的无穷多个非平凡孤立子,并且,也得到指数衰减的孤立子的存在性. 相似文献
106.
This paper is concerned with the construction of globally smooth solutions near a given global Maxwellian to the Cauchy problem of the Vlasov-Poisson-Boltzmann system for non-cutof hard potentials in three space dimensions without the neutral condition imposed on the initial perturbation.Our analysis is based on the time-weighted energy method and some delicate estimates. 相似文献
107.
We consider discrete one-dimensional Schrödinger operators with aperiodic potentials generated by primitive substitutions. Using the three-block version of Gordon's criterion, we establish purely singular continuous spectrum with probability one provided that the potentials have index greater than three. It is also shown that one cannot use this criterion to prove uniform results. 相似文献
108.
109.
《偏微分方程通讯》2013,38(1-2):133-155
Abstract For regularized hard potentials cross sections, the solution of the spatially homogeneous Boltzmann equation without angular cutoff lies in Schwartz's space 𝒮(? N ) for all (strictly positive) time. The proof is presented in full detail for the two-dimensional case, and for a moderate singularity of the cross section. Then we present those parts of the proof for the general case, where the dimension, or the strength of the singularity play an essential role. 相似文献
110.
Raji Heyrovska 《Electroanalysis》2010,22(9):903-907
Aqueous standard potentials, referred to that of the SHE as zero, were recently shown to vary linearly with gaseous ionization potentials, with the absolute potential of SHE as the intercept. This enabled arriving at the absolute redox potentials of elements. Here, the distances between the oxidized and reduced forms in aqueous solutions have been evaluated. From the linear dependence of these distances on the covalent radii of atoms, the radii of the redox components have been obtained. The latter also vary linearly with the aqueous ionic radii estimated earlier from ion‐water distances, and indicate the presence of aqueous molecular anions. 相似文献