Microemulsion-mediated synthesis of cadmium zinc sulfide nanocrystals with composition-modulated optical properties

Cadmium zinc sulfide nanocrystals were synthesized by a microemulsion-mediated process, which involving two steps: the preparation of CdS (or ZnS) seeds and the succedent hydrothermal growth of ZnS (or CdS) component. The XRD results show that the cadmium zinc sulfide nanocrystals with CdS seeds present a hexagonally homogeneous alloyed structure, while the ones with ZnS seeds mainly take on the characteristic of hexagonal CdS nanocrystals. The intrinsic factors influencing the crystal structures were discussed. The UV-vis and photoluminescence (PL) spectra indicate that the optical properties of the obtained nanocrystals with CdS seeds can be continuously modulated by tuning their compositions, although their sizes and size distributions are not under a strict control. The composition-modulated strategy, along with the hydrothermal microemulsion process, will be an effective route to achieve semiconductor nanocrystals with tunable optical properties under more manageable conditions.     

Hard disk magnetic domain nano-spatial resolution imaging by using a near-field scanning microwave microscope with an AFM probe tip

A near-field scanning microwave microscope (NSMM) incorporating an atomic force microscope (AFM) probe tip was used for the direct imaging of magnetic domains of a hard disk under an external magnetic field. We directly imaged the magnetic domain changes by measuring the change of reflection coefficient S₁₁ of the NSMM at an operating frequency near 4.4 GHz. Comparison was made to the magnetic force microscope (MFM) image. Using the AFM probe tip coupled to the tuning fork distance control system enabled nano-spatial resolution. The NSMM incorporating an AFM tip offers a reliable means for quantitative measurement of magnetic domains with nano-scale resolution and high sensitivity.     

Distinguishing between dark matter and pulsar origins of the ATIC electron spectrum with atmospheric Cherenkov telescopes

Recent results from the Advanced Thin Ionization Calorimeter (ATIC) balloon experiment have identified the presence of a spectral feature between approximately 300 and 800 GeV in the cosmic ray electron spectrum. This spectral feature appears to imply the existence of a local (1 kpc) source of high energy electrons. Emission from a local pulsar and dark matter annihilations have each been put forth as possible origins of this signal. In this Letter, we consider the sensitivity of ground based atmospheric Cherenkov telescopes to electrons and show that observatories such as HESS and VERITAS should be able to resolve this feature with sufficient precision to discriminate between the dark matter and pulsar hypotheses with considerably greater than 5σ significance, even for conservative assumptions regarding their performance. In addition, this feature provides an opportunity to perform an absolute calibration of the energy scale of ground based, gamma ray telescopes.     

Fast image method for impulse response calculations of box-shaped rooms

The image method has been used for calculating the impulse response of box-shaped rooms for over 25 years. While this method is functional, it can be inefficient because many of the commonly used mathematical operations are either redundant or unnecessary. This paper addresses these two inefficiencies by proposing both the use of look-up tables to prevent redundant calculations, and the use of a sorting method to allow the prevention of unnecessary calculations. Either technique, by itself, results in a large reduction in computation time. The greatest time reductions, however, can be achieved when both techniques are used together.     

Isomerization and fluorescence characteristics of sterically hindered azobenzene derivatives

We report synthesis and isomerization behaviors of sterically hindered azobenzene derivatives (1 and 2) with decyloxy and hydroxy groups, respectively, and their fluorescence enhancement under UV light irradiation characterized by means of absorption and fluorescence spectroscopy measurements. Upon irradiation of as-prepared solution (1) with UV light (∼200 mJ/cm²) a cis-rich photostationary state was reached. Obviously different from 2 showing very fast thermal cis-to-trans isomerization within 2 min, slow cis-to-trans thermal back isomerization of 1 with a long alkyl chain at ambient temperature was observed on the time scale of weeks. In contrast to no striking changes in absorption and fluorescence spectra of compound 2, the azobenzene 1 showed green fluorescence upon prolonged irradiation with UV light (about 3-8 J/cm² exposure doses), although both the initial trans-rich and cis-rich states of azobenzene molecules were not fluorescent in solution. The stability of fluorescence efficiency caused by drying and redissolving processes was examined.     

Fabrication of Step-and-Flash Imprint Lithography (S-FIL) templates using XeF<Subscript>2</Subscript> enhanced focused ion-beam etching

The fabrication of Step-and-Flash Imprint Lithography (S-FIL) templates with line widths of 50 nm is described in this work. The structures have been patterned using a Ga⁺ focused ion beam (FIB) in a quartz template. FIB milling is generally accompanied with re-deposition effects, which represent a hindrance to densely patterned nanostructures required in most NIL applications. To reduce these re-deposition effects, in this research, xenon difluoride (XeF₂) enhanced FIB etching was applied that also increases the material removal rates in comparison to pure kinetic ion sputtering. To optimise the process when using XeF₂ gas the following ion scanning parameters have been examined: ion dose, beam current, dwell time and beam overlap (step size). It has been found that the assisting gases at very low doses do not bring significant etching enhancements whilst the sputtering rates have increased at high doses. Using the XeF₂ gas-assisted etching, FIB structuring has been used to fabricate <100 nm structures onto quartz S-FIL templates. The presence of XeF₂ considerably enhances the etching rate of quartz without any significant negative effects on the spatial resolution of the FIB lithographic process and reduces the template processing time.     

A scheme to produce a dense positronium plasma for an antihydrogen experiment

A 6 MeV industrial electron linac with 0.2 mA average current will be installed in December 2007 in CEA-Saclay. Equipped with a tungsten target and moderator, it is aimed at producing rates of order 10⁸ s⁻¹ slow positrons. This setup is part of a project to demonstrate the feasibility of an experiment to produce the ion for a free fall measurement of . The energy is below the neutron activation threshold. Its small size and cost could be of interest for a university laboratory or industry, and could be envisaged as a replacement source for the antihydrogen experiments at CERN.     

Local convergence of the method of pseudolinear equations for quasilinear elliptic boundary-value problems

A variant of the method of pseudolinear equations, an iterative method of solving quasilinear partial differential equations, is described for quasilinear elliptic boundary-value problems of the type -[p₁(u_x)]_x - [p₂(u_y)]_y = f on a bounded simply connected two-dimensional domain D. A theorem on local convergence in C^{2, λ}(D) of this variant, which has constant coefficients, is proved. Three other method of solving quasilinear elliptic boundary-value problems, namely. Newton's method, the Ka?anov method and a variant of the method of successive approximations that has constant coefficients, are briefly discussed. Results of a series of numerical experiments in a finite-difference setting of solving quasilinear Dirichlet problems of the above-mentioned type by the method of pseudolinear equations and these three methods are given. These results show that Newton's method converges for stronger nonlinearities than do the other methods, which, in order thereafter, are the Ka?anov method, the method of pseudolinear equations and, last, the method of successive approximations, which converges only for relatively weak nonlinearities. From fastest to slowest, the methods are: the method of successive approximations, the method of pseudolinear equations, Newton's method, the Ka?anov method.     

Monte Carlo calculations of angular momentum projected many-body matrix elements in the Pairing Plus Quadrupole Model

We extend the recently presented formalism for Monte Carlo calculations of the partition function, for both even and odd particle number systems (Phys. Rev. C 59, 2500 (1999)), to the calculation of many-body matrix elements of the type <ψ| e ^{- βℋ}|ψ> where |ψ> is a many-body state with a definite angular momentum, parity, neutron and proton numbers. For large β such matrix elements are dominated by the lowest eigenstate of the many-body Hamiltonian ℋ, corresponding with a given angular momentum parity and particle number. Emphasis is placed on odd-mass nuclei. Negligible sign fluctuations in the Monte Carlo calculation are found provided the neutron and proton chemical potentials are properly adjusted. The formalism is applied to the J ^π = 0⁺ state in ¹⁶⁶ Er and to the J ^π = 9/2^-, 13/2⁺, 5/2^- states in ¹⁶⁵ Er using the pairing-plus-quadrupole model. Received: 28 April 2000 / Accepted: 20 September 2000     

Numerical modelling of the radiation efficiency of asymmetrical structures

The radiation efficiency of a structural element is required by some models in order to predict its sound insulation. A common assumption is that the radiation on both sides of the element is the same. This is not true for asymmetrical structural elements like lightweight floors consisting of a beam-supported flat board. The radiation efficiency is larger on the beam side, because the beams act as exciters and increase the pressure level in the room. These different radiation efficiencies are calculated here for a two-dimensional cross-section by using finite elements and boundary elements. The obtained preliminary results illustrate that considering a single radiation efficiency can be a source of errors and that further investigation is required in order to improve predictions.