全文获取类型
收费全文 | 38395篇 |
免费 | 3736篇 |
国内免费 | 6379篇 |
专业分类
化学 | 30195篇 |
晶体学 | 1346篇 |
力学 | 850篇 |
综合类 | 257篇 |
数学 | 5879篇 |
物理学 | 9983篇 |
出版年
2024年 | 74篇 |
2023年 | 395篇 |
2022年 | 985篇 |
2021年 | 928篇 |
2020年 | 1174篇 |
2019年 | 1244篇 |
2018年 | 1071篇 |
2017年 | 1346篇 |
2016年 | 1364篇 |
2015年 | 1249篇 |
2014年 | 1726篇 |
2013年 | 3173篇 |
2012年 | 2167篇 |
2011年 | 2685篇 |
2010年 | 2276篇 |
2009年 | 2684篇 |
2008年 | 2734篇 |
2007年 | 2649篇 |
2006年 | 2435篇 |
2005年 | 2180篇 |
2004年 | 1954篇 |
2003年 | 1598篇 |
2002年 | 1409篇 |
2001年 | 1202篇 |
2000年 | 1110篇 |
1999年 | 977篇 |
1998年 | 794篇 |
1997年 | 680篇 |
1996年 | 637篇 |
1995年 | 625篇 |
1994年 | 575篇 |
1993年 | 475篇 |
1992年 | 360篇 |
1991年 | 260篇 |
1990年 | 173篇 |
1989年 | 173篇 |
1988年 | 141篇 |
1987年 | 93篇 |
1986年 | 90篇 |
1985年 | 91篇 |
1984年 | 78篇 |
1983年 | 41篇 |
1982年 | 63篇 |
1981年 | 80篇 |
1980年 | 70篇 |
1979年 | 57篇 |
1978年 | 42篇 |
1977年 | 34篇 |
1976年 | 22篇 |
1973年 | 19篇 |
排序方式: 共有10000条查询结果,搜索用时 0 毫秒
141.
Ummadisetty Subramanyam Swaminathan Sivaram 《Journal of polymer science. Part A, Polymer chemistry》2007,45(2):191-210
Homopolymerization of octadecene‐1 at different reaction conditions has been studied. Significant chain running can be seen at higher polymerization temperatures. Interestingly, insertion of octadecene‐1 into a sterically hindered nickel‐cation/carbon (secondary) bond is observed. The microstructure of the polymer was established using NMR spectroscopy. The effects of chain running on polymer melting, crystallization behavior, and dynamic mechanical thermal properties were studied using DSC and DMTA. The extent of chain running (i.e., 2,ω‐, 1,ω‐enchainments) decreases with an increase in the carbon number of α‐olefins. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 191–210, 2007 相似文献
142.
The results of the electronic structures and conduction properties of four novel donor-acceptor polymers based on polysilole, obtained on the basis of ab initio Hartree-Fock crystal orbital method using their optimized geometries, are reported. The repeat unit of these polymers consists of bicyclopentadisilole unit bridged by an electron-accepting group Y(Y=CCH2 in PSICH, CO in PSICF, CCF2 and CC(CN)2 in PSICN). All the polymers on the basis of their geometries and π-bond order values are found to have benzenoid-type electronic structures. Comparison of the important electronic properties such as ionization potential, electron affinity and band-gap of these polymers indicates PSICN to be the best candidate for intrinsic conductivity and reductive (n-) doping while PSICH is predicted to be the best candidate for oxidative (p-) doping. All these polymers are estimated to have band-gap values ranging between 1 and 2 eV. The low band-gap values of these polymers are rationalised on the basis of the patterns of their frontier orbitals. 相似文献
143.
XIE Fu-Ding Xiao-Shan LIU Feng 《理论物理通讯》2004,42(11)
Based on the rank analysis method, algorithmization idea, and symbolic computation, in this paper we have presented a method to construct the conservation laws for nonlinear evolution equations. The polynomial conservation laws for K (n 2, n) equations and mnK(m, n) equations are found by using of this approach and some new results have been obtained. 相似文献
144.
Li Taihua An Zhu Luo Zhengming Center for Radiation Physics Institute of Nuclear Science Technology Sichuan Union University Chengdu 《原子与分子物理学报》1997,(1)
MEASUREMENTSOFFeANDCuK-ShelIONIZATIONCROSSSECTIONSBYSLOWELECTRONIMPACTLiTaihuaAnZhuLuoZhengmingCenterforRadiationPhysics,Ins... 相似文献
145.
C. Ruyer-Quil P. Manneville 《The European Physical Journal B - Condensed Matter and Complex Systems》1998,6(2):277-292
A new model of film flow down an inclined plane is derived by a method combining results of the classical long wavelength
expansion to a weighted-residuals technique. It can be expressed as a set of three coupled evolution equations for three slowly
varying fields, the thickness h, the flow-rate q, and a new variable that measures the departure of the wall shear from the shear predicted by a parabolic velocity profile. Results of a preliminary
study are in good agreement with theoretical asymptotic properties close to the instability threshold, laboratory experiments
beyond threshold and numerical simulations of the full Navier-Stokes equations.
Received: 16 April 1998 / Revised: 29 June 1998 / Accepted: 2 July 1998 相似文献
146.
Katalin E. Kövér Dušan Uhr?&#x;n Victor J. Hruby 《Journal of magnetic resonance (San Diego, Calif. : 1997)》1998,130(2):162-168
A pulsed field gradient version of the sensitivity-enhanced 2D TOCSY experiment is proposed which yields high-quality spectra with improved sensitivity and a minimum of two scans pert1increment. For rapid acquisition of 1D TOCSY spectra, the 1D DPFGSE–TOCSY experiment was modified to include phase-encoded multiple-selective excitation followed by a simple spectral editing. Combination of these two building blocks is used in a sensitivity-enhanced 2D analog of the 3D TOCSY–TOCSY experiment which provides an efficient tool for resolving severely overlapped signals of oligomers in short experimental time. 相似文献
147.
Let (X,0) be the germ of a normal space of dimension n+1 and let f be the germ at 0 of a holomorphic function on X. Assume both X and f have an isolated singularity at 0. Denote by J the image of the restriction map , where F is the Milnor fibre of f at 0. We prove that the canonical Hermitian form on , given by poles of order at in the meromorphic extension of , passes to the quotient by J and is non-degenerate on . We show that any non-zero element in J produces a “mass concentration” at the singularity which is related to a simple pole concentrated at for (in a non-na?ve sense). We conclude with an application to the asymptotic expansion of oscillatory integrals , for , when .
Received: 28 May 2001 / Published online: 26 April 2002 相似文献
148.
Smooth Solutions to Optimal Investment Models with Stochastic Volatilities and Portfolio Constraints
Pham 《Applied Mathematics and Optimization》2002,46(1):55-78
Abstract. This paper deals with an extension of Merton's optimal investment problem to a multidimensional model with stochastic volatility
and portfolio constraints. The classical dynamic programming approach leads to a characterization of the value function as
a viscosity solution of the highly nonlinear associated Bellman equation. A logarithmic transformation expresses the value
function in terms of the solution to a semilinear parabolic equation with quadratic growth on the derivative term. Using a
stochastic control representation and some approximations, we prove the existence of a smooth solution to this semilinear
equation. An optimal portfolio is shown to exist, and is expressed in terms of the classical solution to this semilinear equation.
This reduction is useful for studying numerical schemes for both the value function and the optimal portfolio. We illustrate
our results with several examples of stochastic volatility models popular in the financial literature. 相似文献
149.
Sergio Albeverio Volodymyr Koshmanenko Mykola Pratsiovytyi Grygoriy Torbin 《Positivity》2006,10(1):39-49
We introduce the conflict interaction with two positions between a couple of image probability measures and consider the associated
dynamical system. We prove the existence of invariant limiting measures and find the criteria for these measures to be a pure
point, absolutely continuous, or singular cotinuous as well as to have any topological type and arbitary Hausdorff dimension. 相似文献
150.
氟氧化物陶瓷的多谱线上转换发光 总被引:1,自引:0,他引:1
以氧化硅、氟化铅为基质制备了Er3 :Yb3 共掺杂氟氧化物陶瓷 ,X 射线分析表明陶瓷中存在着 β PbF2 晶相 ,沉积在其中的稀土离子由于具有很低的无辐射跃迁几率而显示出良好的上转换性能。Er3 ,Yb3 离子之间存在的多种能量传递通道 ,导致稀土离子十分丰富的上转换谱线的出现。 相似文献