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951.
Dan Ben-Yaakov David Andelman Rudi Podgornik Daniel Harries 《Current Opinion in Colloid & Interface Science》2011,16(6):542-550
In aqueous solutions, dissolved ions interact strongly with the surrounding water and surfaces, thereby modifying solution properties in an ion-specific manner. These ion-hydration interactions can be accounted for theoretically on a mean-field level by including phenomenological terms in the free energy that correspond to the most dominant ion-specific interactions. Minimizing this free energy leads to modified Poisson-Boltzmann equations with appropriate boundary conditions. Here, we review how this strategy has been used to predict some of the ways ion-specific effects can modify the forces acting within and between charged interfaces immersed in salt solutions. 相似文献
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The water exchange matrix is an efficient tool to study the water exchange among the sub-areas in large-scale bays. The application
of the random walk method to calculate the water exchange matrix is studied. Compared with the advection-diffusion model,
the random walk model is more flexible to calculate the water exchange matrix. The forecast matrix suggested by Thompson et
al. is used to evaluate the water exchange characteristics among the sub-areas fast. According to the theoretic analysis,
it is found that the precision of the predicted results is mainly affected by three factors, namely, the particle number,
the generated time of the forecast matrix, and the number of the sub-areas. The impact of the above factors is analyzed based
on the results of a series of numerical tests. The results show that the precision of the forecast matrix increases with the
increase of the generated time of the forecast matrix and the number of the particles. If there are enough particles in each
sub-area, the precision of the forecast matrix will increase with the number of the sub-areas. Moreover, if the particles
in each sub-area are not enough, the excessive number of the sub-areas can result in the decrease of the precision of the
forecast matrix. 相似文献
955.
《Operations Research Letters》2019,47(5):344-347
We consider exchange markets with single-unit endowments and demands where there is a bound on the size of the exchange cycles. The computational problem we study is that of computing a Pareto optimal and individually rational allocation. We present polynomial-time algorithms to compute a Pareto optimal and individually rational allocation when preferences are strict, the exchange bound is two, or when Pareto optimality is replaced with weak Pareto optimality. 相似文献
956.
白丽霞 《数学的实践与认识》2021,(7):246-250
对热传导问题的微分方程采用无单元Galerkin法进行数值求解.首先,将微分方程用Galerkin加权残量法转化为等效的积分形式.然后,先将时间变量看作参数,对空间变量进行离散化,得到方程的半离散形式,接着,对时间采用向后Euler—Galerkin格式进行离散,得到方程的全离散形式最后,编制MATLAB程序,上机计算.列举了两个热传导算例,通过计算说明EFG法适用于热传导问题,且其计算速度快,精确度高、前后处理也十分方便,是一种具有潜力的温度场数值计算的新方法. 相似文献
957.
Abstract The water exchange reaction of [Pd(dien)H2O]2+ (dien = diethylenetriamine) was studied as function of temperature (268-308 K) and pressure 0.1-197 MPa) using 17O NMR techniques. The rate and activation parameters are: kcx = 5100 s?1 at 298 K; ΔH# =38 kJ mol?1; ΔS# = -47 JK?1 mol?1; ΔV# = -2.8 cm3 mol?1 at 296 K. The results are discussed in reference to solvent exchange data for other Pt(II) and Pd(II) complexes, and are interpreted in terms of an associatively activated substitution process. 相似文献
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Shuchi Gupta Olga Zhovtiuk Aleksandar Vaneski Yan‐Cheng Lin Wu‐Ching Chou Stephen V. Kershaw Andrey L. Rogach 《Particle & Particle Systems Characterization》2013,30(4):346-354
The energy gap between valence and conduction levels in colloidal semiconductor quantum dots can be tuned via the nanoparticle diameter when this is comparable to or less than the Bohr radius. In materials such as cadmium mercury telluride, which readily forms a single phase ternary alloy, this quantum confinement tuning can also be augmented by compositional tuning, which brings a further degree of freedom in the bandgap engineering. Here it is shown that compositional control of 2.3 nm diameter CdxHg(1?x)Te nanocrystals by exchange of Hg2+ in place of Cd2+ ions can be used to tune their optical properties across a technologically useful range, from 500 nm to almost 1200 nm. Data on composition‐dependent changes in the optical properties are provided, including bandgap, extinction coefficient, emission energy and spectral shape, Stokes shift, quantum efficiency, and radiative lifetimes as the exchange process occurs, which are highly relevant for those seeking to use these technologically important QD materials. 相似文献
960.