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31.
This article describes the technique of fast atom bombardment mass spectrometry (FAB MS) and its applications to the analysis of organometallic and coordination complexes. Sections on ion generation and matrices are followed by a Periodic Group-based review of FAB MS results obtained from Transition Metal and Main Group compounds, organometallic cluster carbonyls and their derivatives, and salts of poly-oxo-anions. The literature has been surveyed from 1981 to approximately mid-1986. 相似文献
32.
外汇储备规模与多元变量弹性系数的实证研究 总被引:5,自引:0,他引:5
中国外汇储备近几年的迅速增长引发了关于中国外汇储备规模是否适度的广泛讨论。本文从需求的角度,运用计量经济学的多元线性回归的方法,建立中国外汇储备与平均进口倾向、进口和国际收支三变量的双对数模型,通过计算并通过相关检验得到外汇储备与相关变量的弹性系数。为预测和制定相关政策提供依据。 相似文献
33.
通过求解BogoliubovedeGennes(BdG)方程,利用推广的BlonderTinkhamKlapwijk(BTK)理论,计算铁磁绝缘层铁磁d波超导结中的微分电导、平均电流和散粒噪声功率.研究表明,系统的微分电导和散粒噪声与平均电流的比值都随中间铁磁层厚度作周期性振荡,振荡的幅度随绝缘层势垒增高而变大,随铁磁层中磁交换劈裂的增强而变小.
关键词:
微分电导 散粒噪声 磁交换劈裂 相似文献
34.
35.
A compact high-resolution optical heterodyne interferometer combining a two-frequency light module and a minute optical system
is described. The light module, which generates two independent frequencies of light, is fabricated by proton exchange method
on LiNbO3 substrate. We report an experiment evaluating measurement accuracy using a micro-displacement measurement system which incorporates
this interferometer. Results of the experiment with a standard thickness sample show high thermal stability with maximum measurement
error of 1.8 nm at a temperature from 19°C to 33°C. The system was used to measure the hysteresis of a piezoelectric element
for displacements of several nm, thereby making it possible to analyze the system quantitatively in practice. 相似文献
36.
提出了核双电荷交换反应的双重子共振态的反应机制,成功地解释了长期以来一直困惑着人们的共振区反应的角分布的实验结果.说明了共振区核双电荷交换反应是寻找双重子共振态的一个可能的途径. 相似文献
37.
Yan Shun MA Qing Hua MENG Hong Yu SHI Yuan De LONG Tian Bao HUANG 《中国化学快报》2006,17(6):807-808
Dencichine (β-N-oxalyl-L-α, β-diaminopropionic acid, L-ODAP), a nonprotein amino acid, is a haemostatic agent present in important Chinese medicinal herbs such as Panax notoginseng, as well as other Panax species1. It was first isolated from the seeds … 相似文献
38.
Experiments employing photoreflectance spectroscopy have uncovered band bending due to electrically active defects at the Si(1 1 1)–SiO2 interface after sub-keV Ar+ ion bombardment. The band bending of about 0.5 eV resembles that for Si(1 0 0)–SiO2, and both interfaces exhibit two kinetic regimes for the evolution of band bending upon annealing due to defects healing. The healing takes place about an order of magnitude more quickly at the (1 1 1) interface, however, probably because of less fully saturated bonding and higher compressive stress. 相似文献
39.
Peter D. Verhaert Maria C. Prieto Conaway Tonya M. Pekar Ken Miller 《International journal of mass spectrometry》2007,260(2-3):177
Direct tissue imaging was performed on dissected insect tissue using a MALDI ion trap to visualize endogenous neuropeptides. Coupling tissue imaging to tandem MSn allows for the identification of previously known species and the ability to identify new ones by de novo sequencing, as searchable databases for insects are sparse. Direct tissue imaging is an attractive technique for the study of neuropeptides as minimal sample preparation is required prior to mass spectrometry. We successfully identified neuropeptides present in the corpora cardiaca and allata of Acheta domesticus (the house cricket). Diagnostic fragments at low m/z were used to distinguish between lipids and neuropeptides. The distribution of peptides appears to be more differentially localized than that of phospholipids, which seem to be more evenly distributed within the tissue. 相似文献
40.
A. S. Peregudov L. N. Usatova E. I. Smyslova E. I. Fedin D. N. Kravtsov 《Russian Chemical Bulletin》1995,44(8):1513-1519
It has been shown by the19F NMR method that the relative polarities of nitrogenelement bonds in 2-(4-fluorophenyl)benzimidazole and its PhHg and PPh3Au derivatives increase in the order N-H19F NMR. It has been found that these reactions occur by a bimolecular associative mechanism and that the N-H bond is substantially less reactive than the N-Hg and N-Au bonds, which have identical reactivities within the limits of sensitivity of the method used.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1574–1580, August, 1995.This work was carried out with financial support from the Russian Foundation for Basic Research (Project No. 93-03-5528). 相似文献