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61.
Based on electro-optic switch effect in crystal, a novel laser ranging method is proposed. CW-laser emitted by laser transmitter propagates forward to the measured target, after being reflected by the target, and then goes back to the transmitter. Close to the transmitter, a special mono-block LiNbO3 crystal is added into the round-trip light beams. High-voltage pulses with the sharp enough changes in rising edges are loaded on the crystal. Based on electro-optic effect, double refraction and internal double reflection effect in crystal, the crystal cuts off the round-trip light beams, and reflects a light pulse cut out by the crystal to a detector aside from the original beam path. The pulse width T is the period that laser propagates forward and back between the crystal and the target. The feasibility of the new idea is proved by our experiments and a brand-new way for the laser ranging is provided. 相似文献
62.
Zbigniew Kisiel Lech Pszczó?kowski Steven B. Charnley 《Journal of Molecular Spectroscopy》2007,241(2):220-229
The rotational spectrum of pyruvic acid has been investigated for the first time in the millimeter-wave region, at 160-314 GHz, and also in supersonic expansion, at 10-17.4 GHz. The analysis of the broadband spectra recorded in this work was carried out with the newly developed AABS software package for Assignment and Analysis of Broadband Spectra, and precise spectroscopic constants are reported for the ground state, the first excited state of the low-frequency skeletal torsional mode ν24, and the first excited state of the methyl torsional mode ν23. Limited results have also been obtained for several higher excited states. The dataset for the ground state currently exceeds 1500 lines and for both the A and E internal rotor sublevels spans the complete range of values of Ka at the mid values of J for the measured transitions. The results were analysed with three freely available computer programs employing different strategies for dealing with internal rotation and a comparative discussion of their merits is made. 相似文献
63.
64.
To obtain the key subelements that may influence the scaling of gas-gas injector combustor performance, the combustion performance subelements in a liquid propellant rocket engine combustor are initially analysed based on the results of a previous study on the scaling of a gas-gas combustion flowfield. Analysis indicates that inner wall friction loss and heat-flux loss are two key issues in gaining the scaling criterion of the combustion performance. The similarity conditions of the inner wall friction loss and heat-flux loss in a gas-gas combustion chamber are obtained by theoretical analyses. Then the theoretical scaling criterion was obtained for the combustion performance, but it proved to be impractical. The criterion conditions, the wall friction and the heat flux are further analysed in detail to obtain the specific engineering scaling criterion of the combustion performance. The results indicate that when the inner flowfields in the combustors are similar, the combustor wall shear stress will have similar distributions qualitatively and will be directly proportional to pc0.8 dt-0.2 quantitatively. In addition, the combustion peformance will remain unchanged. Furthermore, multi-element injector chambers with different geometric sizes and at different pressures are numerically simulated and the wall shear stress and combustion efficiencies are solved and compared with each other. A multi-element injector chamber is designed and hot-fire tested at several chamber pressures and the combustion performances are measured in a total of nine hot-fire tests. The numerical and experimental results verified the similarities among combustor wall shear stress and combustion performances at different chamber pressures and geometries, with the criterion applied. 相似文献
65.
The gas-phase Raman spectra of 1,3-butadiene and its 2,3-d2, 1,1,4,4-d4, and d6 isotopologues have been recorded with high sensitivity and resolution of 0.7 cm−1. Hot band series of fundamentals and combinations involving the ν13 torsional vibration of the s-trans rotamer have been observed for each of the isotopologues. Modes studied were ν10 (CH wag), ν12 (CH2 twist), ν10 + ν12, ν15 (CH2 wag) + ν16 (CH2 twist), and ν23 (CH2 rock) + ν24 (CCC deformation). The spacings of the quantum states of the torsional contribution were found to decrease with additional excitation of this mode (ν13) in the upper vibrational states except for the ν23 + ν24 combination state. 相似文献
66.
The rotational spectra of nine isotopomers of dimethyl diselenide, CH3SeSeCH3, have been measured with a molecular-beam Fourier transform microwave spectrometer. The spectra were complex due to the presence of many isotopomers in natural abundance and the splitting caused by the interactions with two methyl internal rotors. The spectra were assigned and fit to experimental precision to an effective rotational Hamiltonian for molecules with two periodic internal motions. The spectra of the symmetric isotopomers are consistent with a C2 equilibrium structure. The rotational constants were used to determine the rs structure of the C-Se-Se-C frame with the results r(SeSe)=2.306(3) Å, r(SeC)=1.954(6) Å, ?(CSeSe)=99.8(2)°, ?(CSeSeC)=85.2(1)°. A barrier to internal rotation of the methyl groups of 395 ± 2 cm−1 was derived from the internal rotation splittings. 相似文献
67.
High-resolution Fourier transform spectra of CH3OH have been investigated in the infrared region from 930 to 1450 cm−1 in order to map the torsion-rotation energy manifolds associated with the ν7 in-plane CH3 rock, the ν11 out-of-plane CH3 rock, and the ν6 OH bend. Upper-state term values have been determined from the assigned spectral subbands, and have been fitted to power-series expansions to obtain substate origins and effective B-values for the three modes. The substate origins have been grouped into related families according to systematic trends observed in the torsion-vibration energy map, but there are substantial differences from the traditional torsional patterns. There appears to be significant torsion-mediated spectral mixing, and a variety of “forbidden” torsional combination subbands with |Δυt|>1 have been observed, where υt denotes the torsional quantum number (equivalent to υ12). For example, coupling of the (υ6,υt)=(1,0) OH bend to nearby torsionally excited (υ7,υt)=(1,1) CH3-rock and (υ8,υt)=(1,1) CO-stretch states introduces (υ6,υt)=(1,0)←(0,1) subbands into the spectrum and makes the ν7+ν12−ν12 torsional hot band stronger than the ν7 fundamental. The results suggest a picture of strong coupling among the OH-bending, CH3-rocking, and CO-stretching modes that significantly modifies the traditional energy structure and raises interesting and provocative questions about the torsion-vibration identity of a number of the observed states. 相似文献
68.
Numerical simulation of two-dimensional granular shearing flows and the friction force of a moving slab on the granular media 下载免费PDF全文
This paper studies some interesting features of two-dimensional granular shearing flow by using molecular dynamic approach for a specific granular system.The obtained results show that the probability distribution function of velocities of particles is Gaussian at the central part,but diverts from Gaussian distribution nearby the wall.The macroscopic stress along the vertical direction has large fluctuation around a constant value,the non-zero average velocity occurs mainly near the moving wall,which forms a shearing zone.In the shearing movement,the volume of the granular material behaves in a random manner.The equivalent friction coefficient between moving slab and granular material correlates with the moving speed at low velocity,and approaches constant as the velocity is large enough. 相似文献
69.
70.
运用化学Langevin方程 ,数值研究了内噪声对单个和单向耦合自催化三分子模型动力学行为的影响 .研究发现 ,对于单个振子体系 ,内噪声可以诱导持续振荡 ,而且随着系统尺度的增大 ,信噪比经过一个极大值 ,从而证明了内噪声随机共振和最佳尺度效应的存在 ;对于单向耦合系统 ,信噪比还随耦合强度的变化而经过极大值 .此外 ,边界条件对耦合体系的内噪声随机共振行为有很大影响 ,非零流条件下 ,耦合可以增强内噪声随机共振 ,而零流条件下 ,耦合会抑制随机共振 ;当耦合强度适宜时 ,每个振子发生随机共振时的尺度几乎相同 ,表明最佳体系尺度和耦合强度有助于体系达到最佳的化学反应状态 . 相似文献