首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   12682篇
  免费   2642篇
  国内免费   1298篇
化学   3068篇
晶体学   171篇
力学   1451篇
综合类   153篇
数学   2141篇
物理学   9638篇
  2024年   19篇
  2023年   141篇
  2022年   268篇
  2021年   321篇
  2020年   386篇
  2019年   315篇
  2018年   314篇
  2017年   420篇
  2016年   496篇
  2015年   453篇
  2014年   709篇
  2013年   919篇
  2012年   799篇
  2011年   884篇
  2010年   845篇
  2009年   867篇
  2008年   873篇
  2007年   810篇
  2006年   808篇
  2005年   734篇
  2004年   766篇
  2003年   628篇
  2002年   566篇
  2001年   454篇
  2000年   439篇
  1999年   368篇
  1998年   329篇
  1997年   275篇
  1996年   235篇
  1995年   167篇
  1994年   154篇
  1993年   118篇
  1992年   94篇
  1991年   89篇
  1990年   83篇
  1989年   88篇
  1988年   62篇
  1987年   48篇
  1986年   62篇
  1985年   40篇
  1984年   27篇
  1983年   14篇
  1982年   24篇
  1981年   21篇
  1980年   20篇
  1979年   14篇
  1978年   15篇
  1977年   9篇
  1976年   7篇
  1973年   6篇
排序方式: 共有10000条查询结果,搜索用时 234 毫秒
961.
The performance analysis of three-dimensional (3-D) braided composites is made difficult by their complex and interlacing structure, and is still under development. To get complete first-hand data on the material parameters of these composites, co-braided optical fiber sensors (OFS) can be used to measure the internal strain. This information is helpful for subsequent stiffness predictions and failure analysis. This paper introduces a method of incorporating OFS into braided composites, and establishes a constitutive theoretical model for the hybrid material. Experiments are conducted to measure the internal strain of specimens under tension, and the results are compared to theoretical predictions.  相似文献   
962.
We study theoretically the thermoelectric power in the presence of a large magnetic field (TPM) in heavily doped III–V, II–VI, PbTe/PbSnTe, strained layer and HgTe/CdTe quantum dot superlattices (QDSLs) with graded structures on the basis of newly formulated electron energy spectra and compare the same with that of the constituent materials. It has been found, taking heavily doped GaAs/Ga1−xAlxAs, CdS/CdTe, PbTe/PbSnTe, InAs/GaSb and HgTe/CdTe QDSLs as examples, that the TPM increases with increasing inverse electron concentration and film thickness, respectively, in different oscillatory manners and the nature of oscillations is totally band structure dependent. We have also suggested the experimental methods of determining the Einstein relation for the diffusivity–mobility ratio, the Debye screening length and the electronic contribution to the elastic constants for materials having arbitrary dispersion laws.  相似文献   
963.
EAST���򳡵�Դ���ϵͳ�������ʵ��   总被引:2,自引:0,他引:2  
利用组态软件编程设计监控界面,监控节点通过与现场总线控制器及高压监控节点的通信,实现对极向场电源状态的实时、可靠监控,并经ODBC接口将状态数据发送至数据库节点备份。简述了电源监控系统的构成,及通过不同的通信协议实现实时数据传输和处理的过程。  相似文献   
964.
The rotational spectrum of pyruvic acid has been investigated for the first time in the millimeter-wave region, at 160-314 GHz, and also in supersonic expansion, at 10-17.4 GHz. The analysis of the broadband spectra recorded in this work was carried out with the newly developed AABS software package for Assignment and Analysis of Broadband Spectra, and precise spectroscopic constants are reported for the ground state, the first excited state of the low-frequency skeletal torsional mode ν24, and the first excited state of the methyl torsional mode ν23. Limited results have also been obtained for several higher excited states. The dataset for the ground state currently exceeds 1500 lines and for both the A and E internal rotor sublevels spans the complete range of values of Ka at the mid values of J for the measured transitions. The results were analysed with three freely available computer programs employing different strategies for dealing with internal rotation and a comparative discussion of their merits is made.  相似文献   
965.
Solution‐processable polymers consisting of perylene diimide (PDI) acceptor moieties alternating with dithienothiophene (DTT), N‐dodecyl‐dithienopyrrole (DTP), or oligomers of these donor groups have been synthesized. We have, in addition to varying the donor, varied the N,N′ substituents of the PDIs. The thermal, optical, electrochemical, and charge‐transport properties of the polymers have been investigated. The polymers show broad absorption extending from 300 to 1000 nm with optical band gaps as low as 1.2 eV; the band gap decreases with increasing the conjugation length of donor block, or by replacement of DTT by DTP. The electron affinities of the polymers, estimated from electrochemical data, range from ?3.87 to ?4.01 eV and are slightly affected by the specific choice of donor moiety, while the estimated ionization potentials (?5.31 to ?5.92 eV) are more sensitive to the choice of donor. Bottom‐gate top‐contact organic field‐effect transistors based on the polymers generally exhibit n‐channel behavior with electron mobilities as high as 1.7 × 10–2 cm2/V/s and on/off ratios as high as 106; one PDI‐DTP polymer is an ambipolar transport material with electron mobility of 4 × 10–4 cm2/V/s and hole mobility of 4 × 10–5 cm2/V/s in air. There is considerable variation in the charge transport properties of the polymers with the chemical structures. © 2013 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2013  相似文献   
966.
Poly{4,8‐bis(4‐decylphenylethynyl)benzo[1,2‐b:4,5‐b′]dithiophene} ( P1 ) homopolymer and poly{4,8‐bis(4‐decylphenylethynyl)benzo[1,2‐b:4,5‐b′]dithiophene ‐alt‐thiophene} ( P2 ) alternating copolymer have been synthesized by Stille coupling polymerization. The field‐effect mobilities of both polymers were measured on both untreated and silane‐treated OFET devices. Various silanes were selected to allow an incremental increase in the hydrophobicity of the silicon dioxide dielectric. A direct correlation was observed between the hydrophobicity of the silicon dioxide dielectric surface and the enhancement of the field‐effect mobilities. The highest mobilities for both polymers were measured on the OFET devices treated with heptadecafluoro‐1,1,2,2‐tetrahydro‐decyl‐1‐trimethoxysilane (FS) which generated the most hydrophobic surface. © 2011 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2011  相似文献   
967.
Inkjet‐printed high speed polymeric complementary circuits are fabricated using an n‐type ([poly{[N,N′‐bis(2‐octyldodecyl)‐naphthalene‐1,4,5,8‐bis(dicarboximide)‐2,6‐diyl]‐alt‐5,5′‐(2,2′‐dithiophene)} [P(NDI2OD‐T2), Polyera ActivInk N2200] and two p‐type polymers [poly(3‐hexylthiophene) (P3HT) and a dithiophene‐based polymer (Polyera ActivInk P2100)]. The top‐gate/bottom‐contact (TG/BC) organic field‐effect transistors (OFETs) exhibit well‐balanced and very‐high hole and electron mobilities (μFET) of 0.2–0.5 cm2/Vs, which were enabled by optimization of the inkjet‐printed active features, small contact resistance both of electron and hole injections, and effective control over gate dielectrics and its orthogonal solvent effect (selection of poly(methyl methacrylate) and 2‐ethoxyethanol). Our first demonstrated inkjet‐printed polymeric complementary devices have been integrated to high‐performance complementary inverters (gain >30) and ring oscillators (oscillation frequency ~50 kHz). We believe that the operating frequency of printable organic circuits can be further improved more than 10 MHz by fine‐tuning of the device architecture and optimization of the p‐ and n‐channel semiconductor processing. © 2010 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys, 2010  相似文献   
968.
The ForceFit program package has been developed for fitting classical force field parameters based upon a force matching algorithm to quantum mechanical gradients of configurations that span the potential energy surface of the system. The program, which runs under UNIX and is written in C++, is an easy‐to‐use, nonproprietary platform that enables gradient fitting of a wide variety of functional force field forms to quantum mechanical information obtained from an array of common electronic structure codes. All aspects of the fitting process are run from a graphical user interface, from the parsing of quantum mechanical data, assembling of a potential energy surface database, setting the force field, and variables to be optimized, choosing a molecular mechanics code for comparison to the reference data, and finally, the initiation of a least squares minimization algorithm. Furthermore, the code is based on a modular templated code design that enables the facile addition of new functionality to the program. © 2010 Wiley Periodicals, Inc. J Comput Chem, 2010  相似文献   
969.
研究了二次域Q(√7)中单位Vn+Un√7)=(8+3√7)n所给出的两个递归数列{Vn},{Un}中的三角数问题,找到了{Vn},{Un}中的所有的三角数.作为应用,给出了与其相关的两个不定方程的整数解.  相似文献   
970.
本文得到了体上二次矩阵方程XAY= B有解的充要条件.并给出了当r(A)= r(B)时矩阵方程XAY= B的通解.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号