解联立方程组法校正火焰原子吸收光谱干扰

本文用解联立方程组法校正了火焰原子吸收分析中镓４０３．３０ｎｍ谱线对锰４０３．３１ｎｍ谱线的重叠干扰。实验结果表明：解联立方程组法是解决原子吸收光谱干扰的可能方法，该法在应用于合成的锰和镓测定中结果令人感到满意。     

Translation of a sphere in a rotating viscous fluid: A numerical study

The translation of a sphere moving along the axis of a rotating viscous fluid is studied by the finite difference method at moderate Reynolds (up to R = 500) and Taylor (up to T = 100) numbers. Suppression of the separation is observed with increasing rotation parameter T. The drag coefficient is also presented. It is observed that the drag coefficient is less than that with no rotation in the range 0<N<0·7, where N = 2T/R is the inverse Rossby number. The same phenomenon was observed experimentally by Maxworthy in the range 0<N<0·75±0·03.     

Gyrotron travelling wave amplifier: I. Analysis of oscillations

The operation of the gyrotron travelling wave amplifier is based on the convective cyclotron maser instability. It is found that this convective instability may become absolute (nonconvective) at a sufficiently high current level, resulting in oscillation instead of amplification. This threshold current for the transition depends sensitively on the applied magnetic field. The axial wavelength and the characteristic frequency of oscillation at the onset of absolute instability are given. It is found that momentum spread has virtually no effect on the threshold current. A small amount of resistive wall loss, however, raises the threshold current significantly. Oscillations due to partial reflection at the ends of the system are also examined. Preliminary experimental results on both types of oscillations are reported and are found to be in good agreement with the theory.     

Improved directional couplers for overmoded waveguide systems

The performance of multihole directional couplers can be considerably improved by placing a second hole structure to the existing one. The improvement may be aimed at directivity or at suppression of certain unwanted modes propagating either in forward or backward direction.     

相对论性核碰撞中φ介子增强

用强子和弦级联模型LUCIAE系统地研究了相对论性p+p和Pb+Pb碰撞中φ介子产生.在模型框架内实验测得的158AGeV/cPb+Pb碰撞中φ介子产额相对于同能量p+p碰撞的增强现象,依赖于弦发射胶子的集体效应和奇异夸克压低约化两机制,在一定程度内能得到解释.     

Overlapping voltammetric peaks—an analytical procedure for simultaneous determination of trace metals. Application to food and environmental matrices

Voltammetric methods are very suitable, versatile and rapid techniques for simultaneous determination of metals in complex matrices. The present work, determination of Cu(II), Sn(II), Sb(III), Tl(I), and Pb(II) by square-wave anodic-stripping voltammetry and Cr(VI) by square-wave adsorptive-stripping voltammetry, is an interesting example of the possibility of simultaneous determination of each single element in food and environmental samples, even in the presence of reciprocal interference. Dibasic ammonium citrate, pH 6.3 or 8.2, was employed as supporting electrolyte. The voltammetric measurements were carried out using a stationary hanging mercury drop electrode as working electrode and a platinum electrode and an Ag|AgCl|KCl_sat electrode as auxiliary and reference electrodes, respectively. The analytical procedure was verified by analysis of standard reference materials—wholemeal BCR-CRM 189, wheat flour NIST-SRM 1567a, rice flour NIST-SRM 1568a, estuarine sediment BCR-CRM 277, river sediment BCR-CRM 320, and Montana soil with moderately elevated traces NIST-SRM 2711. Precision and accuracy, expressed as relative standard deviation and relative error, respectively, were generally below 6% whereas limits of detection for each element were below 0.069 g g^–1. In the presence of reciprocal interference the standard addition method considerably improved the resolution of the voltammetric technique, even for very high element concentration ratios. After being set up on the standard reference materials the analytical procedure was transferred and applied to commercial samples of meal and soil samples taken from sites devoted to agricultural practice. A critical comparison with graphite furnace atomic-absorption spectroscopy is also discussed. Work partially presented at Euroanalysis XIII, Salamanca, Spain, 5–10 September 2004     

新型电谐振人工异向介质抑制阵列天线单元间互耦

基于电谐振原理和镜像原理设计了一种周期性接地边耦合SRRs(split ring resonators)结构的新型电谐振人工异向介质,进而将该人工异向介质应用于抑制微带阵列天线元间的互耦.与传统微带阵列天线中的用于抑制互耦的电磁结构相比,该人工电磁结构不仅体积小(厚度仅为0·005λ0),而且能获得优异的阵列单元间互耦抑制性能(抑制度达16·8dB).该研究成果表明人工异向介质在高密度高性能微带天线阵列设计中具有良好的应用潜能.     

级联电磁带隙结构对双频微带天线互耦的影响

一种均匀面片尺寸的图钉型电磁带隙结构只能实现一个表面波带隙,而将不同参数的图钉型电磁带隙结构级联可以实现多个或宽带的表面波带隙。利用不同金属面片尺寸的图钉型电磁带隙结构级联的方法实现双带的表面波带隙。设计两种均匀的电磁带隙结构,使其带隙范围分别覆盖天线的两个工作频带,然后将这两种结构级联起来,加载于两个缝隙天线单元之间。仿真分析和实验结果表明,级联型的电磁带隙结构可以有效抑制表面波,在两个频率带内同时减小互耦。     

利用光纤法布里-珀罗谐振器干涉透射波长同时测量混合溶液中多溶质浓度(英文)

为了同时探测混合溶液中多种溶质的浓度,提出一种用光纤法布里-珀罗谐振器作为传感器测量混合溶液中多溶质浓度的测量系统.从理论上分析了光纤法布里-珀罗谐振器干涉透射波长与混合溶液浓度之间的关系,采用光纤法布里-珀罗谐振器干涉透射波长实现了高准确度同时测量混合溶液中多溶质浓度的原理和可行性.构建了由InGaAs发光二极管光源、光纤耦合器、FFPR传感器、光电信号转换和放大器、光谱分析仪等组成的测量系统.对乙醇和甘油的9组标准混合溶液进行测量实验,并用测量结果标定了混合溶液中各溶质浓度与光纤法布里-珀罗谐振器传感器干涉透射波长之间的数学解析关系式.根据数学关系式用Action Script 2.0脚本语言编写程序,计算机实时监控了混合溶液中各溶质浓度的变化过程.     

微型平像场近红外光谱仪的消杂散光设计

设计和研制了结构紧凑、杂散光低的微型平像场近红外光谱仪。在分光系统设计中不采用附加杂散光遮挡装置的常规方法,而是在准直物镜前设置一块直径为8．5mm的平面反射镜,通过调节平面反射镜改变入射光束的空间角,使光束全部被准直镜接收,不再产生旁光,从而有效地消除系统内的杂散光,使仪器整体杂散光水平降低了1．13％。另外,该光谱仪选择线阵CCD作为探测器件,不再设置冷却系统也避免了平面光栅带有扫描旋转机构。由于使用CCD作探测器和新的消杂散光设计方法,该光谱仪实现了微型化。