干涉成像光谱仪中宽谱段傅氏光学系统设计

设计了一种宽谱段前置光孔远心光学系统,其孔径光阑位于透镜组的焦面上,该设计集宽谱段自动复消色差、长工作距、前置光孔及远心等特点于一体. 讨论了这样一种特殊光组的设计. 选用国产牌号的光学玻璃配对,价格低廉且在校正色差后,自动校正宽谱段二级光谱,并实现了透镜组两侧同时具有长工作距. 设计结果表明,光学系统的残余二级光谱很容易控制在千分之一焦距以内,波面平行差小于0.000 22弧度.     

嫦娥一号卫星干涉成像光谱仪电子学设计

介绍了嫦娥一号卫星用于获取矿物光谱信息的干涉成像光谱仪电子学系统设计.概述了电子学系统的技术指标、系统组成、工作模式、外部接口和设计原则,详细描述了焦平面组件设计、视频处理和时序控制组件设计和EMC设计,给出部分正样产品实物照片以及地面实验和在轨飞行图像.各项地面试验和一年的在轨飞行结果表明该设计达到了预定的技术要求.     

干涉型复合腔激光束相干合成中分束器的相移特性研究

分析了采用分束器构建干涉型复合腔进行激光束相干合成的过程与原理.利用分束器的特征矩阵研究了分束时产生的反射与透射相移,得到了两束相干光经过分束器分束后进行相干叠加时相移满足的普适关系,从相移的角度解释了分束器一侧发生相长干涉时另一侧必然发生相消干涉这一现象.比较了分束器与光纤耦合器在激光束相干合成应用中的一些特性,并验证了所得相移关系式的正确性.     

Coherent combination of two ytterbium fiber amplifier based on an active segmented mirror

To control the phase noise of two ytterbium fiber amplifiers, a coherent combination system based on an active segmented mirror (ASM) has been established in our laboratory. The ASM is controlled by a feed back control loop on the basis of a Peak Rate (PR) algorithm which is realized on a DSP + FPGA hardware control board. Experimental results indicate that when the control loop is off, the far-field interference pattern is blurred and dynamic, while when it is on, the far-field beams interference pattern achieves clear and stable. At two different output powers, the contrasts of the interference stripes are improved from 7% to 19% and 8% to 28% respectively.     

Phase-shifting interferometry with four interferograms using linear polarization modulation and a Ronchi grating displaced by only a small unknown amount

A method to reduce the number of captures needed in phase-shifting interferometry is proposed on the basis of grating interferometry and modulation of linear polarization. The case of four interferograms is considered. A common-path interferometer is used with two windows in the object plane and a Ronchi grating as the pupil, thus forming several replicated images of each window over the image plane. The replicated images, under proper matching conditions, superpose in such a way so that they produce interference patterns. Orders 0 and +1 and −1 and 0 form useful patterns to extract the optical phase differences associated to the windows. A phase of π is introduced between these orders using linear polarizing filters placed in the windows and also in the replicated windows, so two π-shifted patterns can be captured in one shot. An unknown translation is then applied to the grating in order to produce another shift in the each pattern. A second and final shot captures these last patterns. The actual grating displacement and the phase shift can be determined according to the method proposed by Kreis before applying proper phase-shifting techniques to finally calculate the phase difference distribution between windows. Related simulations and experimental results are given.     

宽谱光源光谱相干度的仿真研究

以傅里叶变换为基础 ,研究了具有任意谱形的宽谱光源的相干函数并实现了通用的宽谱光源相干特性仿真算法。计算了应用于干涉式光纤陀螺的各种宽谱光源的相干特性 ,分析了不同谱形以及光谱平滑度对光谱时间相干性的影响。对于宽谱光源 ,此法可以全面准确地仿真其相干特性。     

ICP-AES分析铁基样品

采用标准和样品基体匹配的分析条件(1?溶液),有效克服ICP-AES分析时样品中铁基体的光谱干扰,相对标准偏差均小于5%,准确度及精确度均达到满意结果。     

The problem of arsenic interference in the analysis of Cd to evaluate its extractability in soils contaminated by arsenic

The arsenic (As) spectral interference observed in the determination of cadmium (Cd) by inductively coupled plasma atomic emission spectrometry (ICP-AES) was studied in atomic absorption spectrometry (AAS) using flame (FAAS) and graphite furnace (GFAAS) as atomizers. The soils of 15 kitchen gardens located near two smelters in the North of France were selected according the ratio As/Cd. Four different extracting solutions usually used to evaluate the mobility of Cd were chosen to extract Cd from these soil samples: citric acid 0.11 M, acetic acid 0.11 M, calcium chloride 0.01 M and water. The quantitative determinations of Cd in the 15 soils for each solvent were investigated by ICP-AES at two lines (228.802 and 214.438 nm) and by FAAS or GFAAS with two-way background compensation. Compared to the Cd concentrations measured in the acid solutions and in the CaCl₂ solution after the addition of a chemical modifier, it was clearly demonstrated that the high-speed self-reversal background compensation (HSSR-method) was the method of choice to eliminate the spectral interference of As during Cd determination by FAAS and by GFAAS. In water, it was shown that the deuterium lamp used for the background compensation (D₂-method) was able to eliminate the most of the As interference. In comparison with Cd concentrations in water after adding a chemical modifier, those obtained with the HSSR-method were similar and a very good correlation was obtained between these two methods (R² = 0.995). It was therefore established that the HSSR-method would be able to replace the chemical modifiers to eliminate As interference in the determination of Cd-extractable from As contaminated soils.     

Resonance Rayleigh scattering study on the interaction of gold nanoparticles with berberine hydrochloride and its analytical application

A heavy metals enzymatic-based assay using papain was developed. Papain was assayed using the Casein-coomassie-dye-binding assay. The assay is sensitive to several heavy metals. The IC₅₀ (concentration of toxicant giving 50% inhibition) of Hg²⁺, Ag²⁺, Pb², Zn²⁺ is 0.39, 0.40, 2.16, 2.11 mg l⁻¹, respectively. For Cu²⁺ and Cd²⁺ the LOQ (limits of quantitation) is 0.004 and 0.1 mg l⁻¹, respectively. The IC₅₀ and LOQ values were found to be generally comparable to several other enzymatic and bioassays tests such as: immobilized urease, 15-min Microtox™, 48 h Daphnia magna, and 96 h Rainbow trout. The papain assay is xenobiotics tolerant, has a wide pH for optimum activity, is temperature stable, and has a relatively quick assay time. The papain assay was used to identify polluted water samples from industrial sources in Penang, Malaysia. We found one site where the assay gave a positive toxic response. The toxicity of the site was confirmed using Atomic Emission Spectrometry analysis.     

一种光谱分辨率可调的新型空间调制傅里叶变换光谱仪

调整光谱仪的光谱分辨率,可使光谱仪在满足不同目标测量需求的同时,减少数据采集、处理和存储的时间,提高仪器的整体性能。为克服传统傅里叶变换光谱仪的光谱分辨率固定的缺点,提出了一种分辨率可调的空间调制傅里叶变换光谱仪。介绍了该新型光谱仪及其干涉仪的工作原理,利用光线追迹的方法推导了光程差和横向剪切量的计算公式,并分析了新型干涉仪的光程等效模型。在此基础上,分析了光谱分辨率的调节原理。结果表明,该光谱分辨率可调的新型空间调制傅里叶变换光谱仪克服了传统光谱仪分辨率固定、稳定性差等缺点,具有分辨率可调、高稳定性、结构灵活和易于装调等特点。该研究内容为分辨率可调的干涉光谱仪的设计提供了理论基础,扩展了傅里叶变换光谱仪的实用范围。