高盐样品中锂的电感耦合等离子体发射光谱法(ICP-OES)测定研究

锂是重要的战略金属和新能源材料,其开发利用受到全球的高度关注。在高盐卤水特别是盐湖卤水和地下卤水中富含巨量的锂资源,在对这些资源进行锂的开发利用过程中,需对锂的含量进行准确测定,然而卤水中共存的高浓度Na+, K+, Ca2+和Mg2+会对微量锂的准确测定产生严重的干扰。电感耦合等离子体发射光谱法(ICP-OES)具有线性范围宽和多元素同步分析能力,针对卤水中锂的快速准确测定,详细开展了高盐样品中锂的ICP-OES分析方法研究。结果表明,锂在610.364 nm处具有较高的信噪比,且Na+, K+, Ca2+, Mg2+和Ar不会对锂的测定产生显著的谱线干扰。然而,样品中大量共存的Na+, K+和Mg2+会对锂的测定产生严重的基体正干扰,而Ca2+产生负干扰。尽管内标法在消除基体干扰方面具有广泛的应用,但传统的以钇和钪为内标元素的内标法不能有效解决该问题。此外,针对标准加入法操作繁琐、不适合批量样品分析问题,以及基体匹配法需多离子匹配,且不适合样品基体组成变化的批量样品分析等问题,考察了采用单一组分进行复杂基体匹配的可行性。由于NaCl广泛存在于卤水中,且对锂的测定具有显著的增敏效应,通过系列研究发现,通过同时向样品和标准溶液中加入10 g·L-1的NaCl,成功解决了总量不超过40 g·L-1的NaCl, KCl和MgCl2所产生的干扰。尽管采用该法或沉淀预分离方式均不能消除Ca2+产生的负干扰,但当样品中Ca2+含量不高于1.8 g·L-1时,对测定不产生显著的影响。通过采用该方法对三种不同基体组成的卤水样品进行加标回收测定,其回收率在96.60%~104.20%范围内。此外,通过与电感耦合等离子体质谱法(ICP-MS)测定结果进行对比,充分论证了该法的准确性和可靠性(相对误差±3.66%)。该法仅以单一的NaCl进行复杂基体匹配,不仅简化了操作,还实现了基体组成变化的批量样品分析,因而在卤水中锂的快速准确测定及锂资源开发利用方面具有重要意义。     

Enhancing optomechanical force sensing via precooling and quantum noise cancellation

We theoretically investigate optomechanical force sensing via precooling and quantum noise cancellation in two coupled cavity optomechanical systems.We show that force sensing based on the reduction of noise can be used to dramatically enhance the force sensing and that the precooling process can eifectively improve the quantum noise cancellation.Specifically,we examine the effect of optomechanical cooling and noise reduction on the spectral density of the noise of the force measurement;these processes can significantly enhance the performance of optomechanical force sensing,and setting up the system in the resolved sideband regime can lead to an optimization of the cooling processes in a hybrid system.Such a scheme serves as a promising platform for quantum back-action-evading measurements of the motion and a framework for an optomechanical force sensor.     

微波消解-电感耦合等离子体发射光谱(ICP-OES)法测生物质中的碱金属和碱土金属

为研究并解决测试生物质样品中碱金属和碱土金属含量的干扰,采用微波消解-电感耦合等离子体发射光谱(ICP-OES)法对生物质中的碱金属和碱土金属钾、钙、钠、镁元素进行测定,考察了样品消解后不同的酸体系,共存元素干扰对钾、钠、钙、镁含量测定的干扰研究。经过研究表明,接近分析标准曲线酸浓度的样品干扰小,铅、铟、钛、锰元素对钠元素测定造成干扰,砷、铜、镉对钙元素测定干扰,铝对钾元素测定有干扰,镁测定不受共存元素干扰影响,运用干扰系数法可以减少共存元素对测定元素的误差。各待测元素标准曲线相关系数大于0.9996,检出限为0.0014~0.023 mg/L,玉米芯各元素的相对标准偏差为0.98%~1.9%,加标回收率为80.2%~106%;西瓜皮的各元素相对标准偏差为0.91%~2.3%,加标回收率为85.3%~106%。方法用于测定国家标准物质GBW07603,各元素结果均在标准值参考范围内。方法用于测定生物质中碱金属和碱土金属的结果,用t检验法与离子色谱测定值进行比对,结果无显著性差异。     

用于测量亚硝酸的长光程吸收光谱仪的研制

This article has been retracted at the request of the authors.     

The Rank of a Direct Power of a Small-Cancellation Group

We construct an example of a finitely generated group G such that rank((G )ⁿ)=2 for all n1. For each n, we construct a finitely presented group G _n such that rank((G _n )ⁿ)=2. We conjecture that if G is a word-hyperbolic group then rank(G ⁿ ) as $ n. For each m we give an example of a residually finite group K _m such that K _m has exactly two relators, but K _m has no proper subgroups of index $ m. We construct a finitely generated group D such that there is an epimorphism DD×D.     

A study of multi-beam DICANNE system

I.IntroductionTheprob1cmofsuppressingstrongpointinterferencesourceisavcryimportantthesisinsonardesign.Fortheana1ogsonar,thesolutionofthisprob1emisquitedifficu1t.Untilthedevelopmentofdigitalsonar,thereissomerescarchreportsaboutsuppressingstrongpointin-terferencesource.Theear1ierworkin1969,dedicatcdbyV.C.Anderson,istheconccptofDICANNE(DigitalInterfcrcnceCance1lingAdaptiveNu1lNetworkEquipment)['l.Thisisadoublecompensatormulti-bcamsystcm.Oneisusedtoformintcrfercncebeamandanothcrisusedtofor…     

Partially coherent multiple-beam interference

The general formula for multiple-beam interference due to regular slit arrays illuminated with partially coherent quasi-monochromatic light is derived. The correlation functions chosen for partially coherent light assume Gaussian, sinc and besinc forms of correlation. The intensity distribution in the interference patterns is presented and discussed as a function of the spatial coherence condition. It is shown that spatial coherence of the illumination largely affects the features of multiple-beam interference patterns.     

用于投影显示的分色合色膜系的消偏振设计

由于斜入射时,光学薄膜存在一定的偏振效应,将产生S-和P-偏振光的光谱分离.在Philips棱镜系统中,分色合色膜系通常分色时对S-光应用,合色时则对P-光应用.从提高光能利用率、减少杂散光和增加系统对比度等因素综合考虑,要求分色合色膜系的S-和P-偏振光的分离尽可能小.新设计方法采用宽带法布里－珀罗薄膜干涉滤光片中心波长两侧的干涉带作为长波通或短波通截止滤光片,可实现S-和P-偏振分量的分离几乎为零.     

Dedekind Complete Commutative BCK-algebras

We study Dedekind complete commutative BCK-algebras with the relative cancellation property and their connection with corresponding universal groups. We shall characterize Dedekind orthogonally complete atomic and Archimedean BCK-algebras, generalizing results of Jakubík known for MV-algebras. Finally, we characterize those Dedekind complete and atomic commutative BCK-algebras that are isomorphic to direct products of basic BCK-chains, generalizing a result of Cignoli for MV-algebras.     

基于经验模式分解的拖曳式声纳拖船噪声抵消研究

拖曳式线列阵声纳的拖船噪声具有多途角扩展等特点，并且是一个非平稳过程，使得对该噪声的消除或抑制是一大难点。经验模式分解是一种用于分析非线性非平稳信号的新方法，该方法自适应地将嵌于数据内部的多个固有模式函数逐一分解开来。本文尝试利用经验模式分解方法分离出水听器接收信号中的拖船干扰噪声，从而达到消除干扰的目的。海上试验数据的处理结果充分验证了这种方法的可行性。