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911.
The reaction of fluorenone ethyleneketal (9), diphenic anhydride as well as of biphenyls such as4 with Cr(CO)6 in refluxing di-n-butylether (BE) gives dimethylbenchrotrenes [xylene-Cr(CO)3,7] which are also formed by refluxing pureBE with Cr(CO)6—although with much lower yields. Similarily, from di-n-pentylether and Cr(CO)6 isobutyl- and 1-methyl-3-propyl-benchrotrene (13 and14) were obtained, whilst from di-n-propyl- and-hexylether, resp., and Cr(CO)6 no benchrotrenes could be isolated.Tentative assumptions on the catalytic action of certain functional groups were confirmed by the reaction ofBE and Cr(CO)6 in the presence of carbonamides, such as acetamide, urea and pyrrolidone, where 1,4-dimethylbenchrotrene (7 c) was formed with appreciable yields.Studies using dideuteratedBE showed that—at least for the reaction of9 with Cr(CO)6 (giving a much lower yield of7 than with undeuteratedBE)—a simple bimolecular mechanism can be excluded. 相似文献
912.
A method to analyze human plasma proteins without fractionation, directly applying a plasma-matrix mixture on the target plate of a matrix-assisted laser desorption/ionization-time of flight-mass spectrometer (MALDI-TOF-MS), has been described. Peaks of ionized plasma proteins could not be detected applying a mixture of an undiluted plasma sample and a matrix solution, but they appeared when the plasma was diluted before mixing with the matrix. Tenfold diluted plasma provided well-resolved protein peaks in the m/z range from 4000 to 30,000. The addition of a simple post-crystallization washing procedure performed on the target plate further improved the quality of mass spectra. We numbered 58 peaks in the range of 4-160 kDa and 32 out of which were assigned to the plasma protein species which have been reported. Especially high sensitivity and resolution were obtained in the region < 30 kDa, where multiple isoforms of apolipoprotein A-I, apolipoprotein A-II, apolipoprotein C-I, apolipoprotein C-II, apolipoprotein C-III, and transthyretin could be assigned. Various post-translational modifications are involved in the isoforms, e.g., proteolytic cleavage, glycosylation and chemical modifications. This method will become complementary with the present electrophoretic techniques, especially for the analysis of low-molecular-mass proteins. 相似文献
913.
ZSM-5/Y复合分子筛在烃类催化裂化催化剂中的应用研究 总被引:7,自引:1,他引:7
以大庆减压蜡油为原料,考察了水热脱铝ZSM-5/Y复合分子筛的催化裂化性能,并与经同样条件水热脱铝的ZSM-5和Y型沸石的机械混合分子筛进行了对比研究。结果表明,与机械混合样品相比,复合分子筛具有较大的柴油产率和气体产率,汽油产率降低。从复合分子筛结构和ZSM-5的择形催化两方面分析了复合分子筛和机械混合分子筛裂化性能差别的原因。复合分子筛的聚集体结构不利于大分子进入分子筛结构中进行裂化,有利于汽油组分的裂化。气体数据分析支持了复合分子筛的结构特点。 相似文献
914.
以ZnO纳米柱阵列为模板, 采用溶胶-凝胶法制备出TiO2/ZnO和N掺杂TiO2/ZnO的复合纳米管阵列. 扫描电镜(SEM)、X射线光电子能谱(XPS)和紫外-可见漫反射吸收光谱(UV-Vis)的结果表明: 两种阵列的纳米管均为六角形结构, 直径约为100 nm, 壁厚约为20 nm; 在N-TiO2/ZnO复合纳米管阵列中, 掺入的N离子主要是以N-Ox、N-C和N-N的形式化学吸附在纳米管表面, 仅有少量的N离子以取代式掺杂的方式占据TiO2晶格O的位置; 表面N物种形成的表面态能级和取代式掺杂导致带隙的窄化, 增强了纳米管阵列的光吸收效率, 促进了光生载流子的分离. 光催化实验结果表明, N离子的掺杂有利于N-TiO2/ZnO复合纳米管阵列光催化活性的提高. 相似文献
915.
Andrzej W. Trochimczuk Shoji AokiKazunori Yamabe Akinori Jyo 《European Polymer Journal》2002,38(5):941-945
Four porous vinylnaphthalene/divinylnaphthalene (VN/DVN) polymers having three different nominal crosslinking degrees (60, 80 and 100 wt.%) have been synthesized using the suspension polymerization method in the presence of toluene and decane.The use of various crosslinking levels and inert diluents was aimed at changing the extent of polymeric network-diluent interactions. The resultant polymers have specific surface area in the range 450-700 m2/g depending on the DVN content. Two sets of pores were detected in all resins: one with the diameter of ≈2 nm and the second one in the range of 30-40 nm. Their sorptive properties have been studied using dilute (0.5 mmol/l) solutions of phenol and its derivatives (o-chlorophenol, 2-methylphenol, o-nitrophenol, m-nitrophenol and p-nitrophenol). It has been found that sorption, at low equilibrium concentration, follows the order: o-nitrophenol > o-chlorophenol > m-nitrophenol > o-methylphenol > p-nitrophenol > phenol. Full characteristics of the porous structure of resultant polymers was obtained by nitrogen adsorption at 77 K and their surface properties analyzed using Inverse Gas Chromatography. 相似文献
916.
本文通过酶活性测定,荧光光谱和紫外光谱研究了外加Cu2+与烟草多酚氧化酶(简称PPO)的相互作用。结果表明,微量铜的加入能增加酶的活性,[Cu2+]/[PPO]为0.20左右时酶活性最大,[Cu2+]/[PPO]为0.91时,Cu2+开始表现出对PPO活性的抑制;Cu2+对PPO内源荧光的猝灭机制属于形成络合物所引起的静态猝灭,猝灭常数Ksv为8.0375×103L·mol-1;Cu2+的加入使PPO蛋白质分子构象发生变化,α-螺旋含量增加,多肽链及Trp和Tyr残基的芳杂环进一步向分子内收缩,疏水基团之间的疏水作用增强。 相似文献
917.
Jakubus P. Adamski A. Kurzawa M. Sojka Z. 《Journal of Thermal Analysis and Calorimetry》2003,72(1):299-310
The structure and surface properties of ZrO2 strongly depend on its preparation. In the present work the impact of prolonged aging at basic conditions (pH = 9, T = 100°C, t = 48 h), on the phase composition and textural properties, obtained by calcination of the precipitate, was investigated using
several techniques conjointly (DTA/TG, DSC, XRD, porosimetry). The thermal effects accompanying the ZrO2·xH2O gel formation, the coalescence of the particles and crystallization were evaluated and discussed in terms of the structural
differences between the aged and non-aged samples.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
918.
The main thermodynamic characteristics of the adsorption of haloadamantanes on graphitized thermal carbon black were determined by experimental measurements and by calculations in terms of molecular-statistic theory of adsorption. Using experimental data, the Kovac retention indices were calculated and the optimum conditions for gas-chromatographic separation of haloadamantanes on stationary phases with different polarity were elucidated. The influence of the cage effect in the adamantane unit on the chromatographic properties of haloadamantanes was established. 相似文献
919.
Smetanina O. F. Kuznetzova T. A. Denisenko V. A. Pivkin M. V. Khudyakova Yu. V. Gerasimenko A. V. Popov D. Yu. Il"in S. G. Elyakov G. B. 《Russian Chemical Bulletin》2001,50(12):2463-2465
A pentacyclic tritepenoid, 3-methoxyolean-18-ene (miliacin), was isolated for the first time from the marine fungus Chaetomium olivaceum. Its structure was determined on the basis of 2D NMR spectroscopy and X-ray diffraction data. 相似文献
920.
制备了不同摩尔比的甲基丙烯酸-磷脂酰乙醇甲基丙烯酰胺共聚物,研究了这种共聚物在水面的表面压力(π)-分子面积(A)曲线、共聚物制成的MOS LB膜的电容(C)-电压(V)特性及此LB膜的相变温度。 相似文献