全文获取类型
收费全文 | 3006篇 |
免费 | 347篇 |
国内免费 | 590篇 |
专业分类
化学 | 2509篇 |
晶体学 | 69篇 |
力学 | 76篇 |
综合类 | 72篇 |
数学 | 345篇 |
物理学 | 872篇 |
出版年
2024年 | 9篇 |
2023年 | 81篇 |
2022年 | 144篇 |
2021年 | 141篇 |
2020年 | 130篇 |
2019年 | 128篇 |
2018年 | 98篇 |
2017年 | 148篇 |
2016年 | 147篇 |
2015年 | 138篇 |
2014年 | 159篇 |
2013年 | 267篇 |
2012年 | 207篇 |
2011年 | 194篇 |
2010年 | 165篇 |
2009年 | 244篇 |
2008年 | 176篇 |
2007年 | 215篇 |
2006年 | 154篇 |
2005年 | 130篇 |
2004年 | 131篇 |
2003年 | 95篇 |
2002年 | 102篇 |
2001年 | 84篇 |
2000年 | 92篇 |
1999年 | 64篇 |
1998年 | 57篇 |
1997年 | 50篇 |
1996年 | 34篇 |
1995年 | 22篇 |
1994年 | 27篇 |
1993年 | 19篇 |
1992年 | 21篇 |
1991年 | 7篇 |
1990年 | 7篇 |
1989年 | 8篇 |
1988年 | 14篇 |
1987年 | 6篇 |
1986年 | 3篇 |
1985年 | 6篇 |
1984年 | 2篇 |
1983年 | 3篇 |
1982年 | 6篇 |
1981年 | 2篇 |
1980年 | 1篇 |
1979年 | 4篇 |
1976年 | 1篇 |
排序方式: 共有3943条查询结果,搜索用时 15 毫秒
11.
The blends composed of polyamide 6 (PA6) and polyamide 66 (PA66) were obtained using two different preparation methods, one of which was the melt‐mixing through a twin‐screw extruder and the subsequent injection molding; and the other, the in situ blending through anionic polymerization of ε‐caprolactam in the presence of PA66. For the former, there existed a remarkable improvement in toughness but a drastic drop in strength and modulus; however, for the latter, a reverse but less significant trend of mechanical properties change appeared. Various characterizations were conducted, including the analyses of crystalline morphology, crystallographic form, and crystallization and melting behaviors using polarized optical microscopy (POM), wide‐angle X‐ray diffraction (WAXD), and differential scanning calorimetry (DSC), respectively; observation of morphology of fractured surface with scanning electron microscope (SEM); measurement of glass transition through dynamic mechanical analysis (DMA); and the intermolecular interaction as well as the interchange reaction between the two components by Fourier transform infrared spectrometry (FT‐IR) and 13C solution NMR. The presence and absence of interchange reaction was verified for the in situ and melt‐mixed blends, respectively. It is believed that the transreaction resulted in a drop in glass transition temperature (Tg) for the in situ blends, contrary to an increase of Tg with increasing PA66 content for the melt‐mixed ones. And the two kinds of fabrication methods led to significant differences in the crystallographic form, spherulite size and crystalline content and perfection as well. Accordingly, it is attempted to explain the reasons for the opposite trends of changes in the mechanical properties for these two blends. © 2007 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 1176–1186, 2007 相似文献
12.
An intact auditory system at birth is requisite for the successful accomplishment of many developmental skills. Evoked responses to auditory stimuli have been used as a sensitive test to determine the functional status of the adult and neonatal brain. It has been established that fetuses can hear in utero and respond to external acoustic stimuli. We present an overview of the transmission of sound through the maternal abdomen to the fetal ear and the recordings of an auditory evoked response obtained from the fetus using a non-invasive magnetoencephalography technique. The investigation of cortical activity of the fetus in response to auditory stimulation can help understand and track the neurological development of the fetus. 相似文献
13.
CuX(X=Al, Ga, In)分子的势能函数与稳定性的密度泛函研究 总被引:5,自引:3,他引:2
刘风丽 《原子与分子物理学报》2006,23(5):838-842
根据原子分子反应静力学原理导出了CuX(X=Al,Ga,In) 分子基态电子状态及其离解极限,并在B3LYP/LANL2DZ水平上计算了平衡几何、振动频率和解离能.利用Murrell-Sorbie 函数拟合出了解析势能函数,并计算出光谱参数和力常数.计算结果表明该分子体系是稳定存在的,其稳定性排序为 CuAl>CuGa>CuIn. 相似文献
14.
S. Park T. U. Kampen T. Kachel P. Bressler W. Braun D. R. T. Zahn 《Applied Surface Science》2002,190(1-4):376-381
The interaction of Ag and In with a thin film of 3,4,9,10-perylenetetracarboxylic dianhydride (PTCDA) was studied by near-edge X-ray absorption fine structure (NEXAFS). Upon Ag deposition on a PTCDA film of 20 nm thickness the relative intensities and lineshapes, as well as the angular dependence of the spectra remains unchanged, illustrating the formation of a chemically unreactive Ag/PTCDA interface. On the other hand, the adsorption of 0.3 nm In strongly decreases the intensity of the π* resonances in C and O K-edge NEXAFS spectra. This is attributed to a strong charge transfer between In and PTCDA, leading to a redistribution of the charge in the molecule. However, the absence of a strong shift or new features and negligible dependence of peak intensities corresponding to π* resonances on the In thickness indicate that the interaction between In and PTCDA is not accompanied by a covalent bond formation. 相似文献
15.
姜波 《新疆大学学报(理工版)》2004,21(3):325-328
无线资源管理是CDMA蜂窝移动通信系统保证业务质量(QoS)和提高频谱利用率的关键技术,本文提出了CDMA系统中无线资源管理算法的一般模型,阐述了三种重要的无线资源管理算法,即功率控制算法、呼叫接纳控制算法和分组调度算法的主要研究情况,并分析了目前研究中仍然存在和需要解决的问题。 相似文献
16.
In this paper we address the problem of scheduling unit time jobs in a flowshop to minimize makespan under a discrete renewable resource constraint. We propose algorithms having complexityO(n) for special cases of two machine and three machine problems. For the three machineN P-hard problem we develop a branch and bound procedure and several upper and lower bounds. We test the efficiency of the procedure and report our computational experience.Suna Kondakci was a visiting assistant professor at the Industrial Engineering Department, Purdue University, when the paper was revised. 相似文献
17.
用共沉淀法制备了Mg2 + 掺杂的In2 O3 纳米粉 ,研究了镁掺杂对In2 O3 电导和气敏性能的影响 .结果表明 :MgO和In2 O3 间可形成有限固溶体In2 -xMgxO3 (0≤x≤ 0 .40 ) ;MgIn× 电离的空穴对材料导带电子的湮灭 ,使掺镁纳米粉的电导变得很小 ;n(Mg2 + )∶n(In3 + ) =1∶2共沉淀物于 90 0℃下热处理 4h ,用所得的纳米粉制作的传感器在 32 0~ 370℃下 ,对 45 μmol/LC2 H5OH的灵敏度达 10 2 .5 ,为相同浓度干扰气体Petrol的 12倍多 . 相似文献
18.
资源共享方式若干问题的研讨 总被引:3,自引:1,他引:2
社会公用服务系统和工程技术系统,存在共同的资源共享问题。本文通过典例就资源共享方式的若干问题加以探究:讨论广义的多用户系统中人工资源共享方式的分类;阐述常用的共享方式的特点、优缺点;分析系统时间性能及其改进与共享方式的关系等。文章还提出在系统工程范畴里,应对社会公用服务和工程技术两类系统的资源共享方式予以综合研究,并相互借鉴和移植。 相似文献
19.
钯II催化CO/乙烯共聚加压原位红外光谱研究 总被引:1,自引:1,他引:1
聚酿以其优良的物理、化学性能及原料(CO乙烯)简单易得的优点,在世界范围内已引起人们的普遍关注.为寻找价廉的催化剂或改良高效或(11)一双磷催化剂以推动聚酮的工业化进程,必须对共聚机理进行深入的研究.S;,n[’,’1、DrentP]等人根据对产品主链和端基的分析首先 相似文献
20.
HUANG Xi-He SHENG Tian-Lu XIANG Sheng-Chang FU Rui-Biao HU Sheng-Min LI Ya-Min WU Xin-Tao ② 《结构化学》2007,26(2):161-164
The hydrothermal reaction of 1,2-dicyanobenzene with NaN3 in the presence of CuCl2, 2,2′-bipyridine and H2O affords a novel dinuclear copper(II)-ditetrazolate, [Cu(bpy)- (pdtz)]2 (Hpdtz = 5,5′-1,2-phenylene-ditetrazole, bpy = 2,2′-bipyridine). The pdtz ligand is generated in situ through Sharpless 2 3 cycloaddition reaction. Its crystal structure was deter- mined by single-crystal X-ray diffraction method. The crystal crystallizes in the monoclinic system, space group P21/n with a = 8.2096(16), b = 18.580(4), c = 11.838(2) , β = 103.12(3)o, V = 1758.5(6) 3, Z = 2, Mr = 863.83, Dc = 1.631 g/cm3, F(000) = 876 and μ = 1.272 mm-1. In this novel dinuclear structure, the pdtz ligand adopts a peculiar μ2-η1,η2 coordination mode. 相似文献