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111.
112.
Complex formation between a nanoparticle and a weak polyelectrolyte chain: Monte Carlo simulations 总被引:1,自引:0,他引:1
Serge?Ulrich Abohachem?Laguecir Serge?StollEmail author 《Journal of nanoparticle research》2004,6(6):595-603
Understanding the complexation processes between nanoparticles and polyelectrolytes is an essential aspect in many branches of nanotechnology, nanoscience, chemistry, and biology to describe processes such as nanoparticle stabilization/destabilization and dispersion, water treatment, microencapsulation, complexation with biomolecules for example, and evolution of the interface of many natural and synthetic systems. In view of the complexity of such processes, applications are often based on empirical or semiempirical observations rather than on predictions based on theoretical or analytical models. In this study, the complex formation between an isolated weak polyelectrolyte and an oppositely charged nanoparticle is investigated using Monte Carlo simulations with screened Coulomb potentials in the grand canonical ensemble. The roles of the nanoparticle surface charge density , solution pH and ionic concentration Ci are systematically investigated. The phase diagrams of complex conformations are also presented. It is shown that the polyelectrolyte conformation at the surface of the nanoparticle is controlled by the attractive interactions with the nanoparticle but also by the repulsive interactions between the monomers. To bridge the gap with experiments titration curves are calculated. We clearly demonstrate that an oppositely charged nanoparticle can significantly modify the acid/base properties of a weak polyelectrolyte. 相似文献
113.
S. F. King 《Pramana》2004,62(2):307-318
We review experimental and theoretical developments in inflation and its application to structure formation, including the
curvaton idea. We then discuss a particle physics model of supersymmetric hybrid inflation at the intermediate scale in which
the Higgs scalar field is responsible for large scale structure, show how such a theory is completely natural in the framework
extra dimensions with an intermediate string scale. 相似文献
114.
Helmut R. Brand Charles R. Doering Robert E. Ecke 《Journal of statistical physics》1989,54(5-6):1111-1119
A brief introduction to the field is given together with an overview of the lectures given at the workshop on External Noise and its Interaction with Spatial Degrees of Freedom in Nonlinear Dissipative Systems organized by the Center for Nonlinear Studies at Los Alamos, March 28–31, 1988. It is hoped that the publication of papers presented at the workshop in a single issue of theJournal of Statistical Physics will help draw attention to the recent developments in this rapidly area of nonequilibrium phenomena. 相似文献
115.
Heat Kernel Asymptotics of Zaremba Boundary Value Problem 总被引:1,自引:0,他引:1
The Zaremba boundary-value problem is a boundary value problem for Laplace-type second-order partial differential operators
acting on smooth sections of a vector bundle over a smooth compact Riemannian manifold with smooth boundary but with discontinuous
boundary conditions, which include Dirichlet boundary conditions on one part of the boundary and Neumann boundary conditions
on another part of the boundary. We study the heat kernel asymptotics of Zaremba boundary value problem. The construction
of the asymptotic solution of the heat equation is described in detail and the heat kernel is computed explicitly in the leading
approximation. Some of the first nontrivial coefficients of the heat kernel asymptotic expansion are computed explicitly.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
116.
Yee Yee Oo K. N. Nagendra Sharath Ananthamurthy Swarnamala Sirsi R. Vijayashankar G. Ramachandran 《Journal of Quantitative Spectroscopy & Radiative Transfer》2005,90(3-4):343-366
In continuation of our earlier investigation (referred to hereafter as part I) where we considered the mathematically simple case of magnetic field orientation along the Z-axis of the principal axes frame (PAF) of the electric quadrupole field, we take up here the general problem of arbitrary orientation of the magnetic field with respect to the PAF, and investigate the nature of polarized line spectra of an atom making a transition from an upper level with spin Ju to a lower level with spin Jl. Explicit formulae for the emitted Stokes parameters are obtained and we discuss their physical significance by computing numerically the cases of transitions Ju=1→Jl=0 and
. Specific features or signatures of the polarized line spectra are discussed as functions of the relevant physical parameters. The Stokes parameters are also analyzed in terms of the Zeeman term contributions and the cross-term contributions (which arise due to quantum interference). 相似文献
117.
A model for polar filaments interacting via molecular motor complexes is investigated which exhibits bifurcations to spatial
patterns. It is shown that the homogeneous distribution of filaments, such as actin or microtubules, may become either unstable
with respect to an orientational instability of a finite wave number or with respect to modulations of the filament density,
where long-wavelength modes are amplified as well. Above threshold nonlinear interactions select either stripe patterns or
periodic asters. The existence and stability ranges of each pattern close to threshold are predicted in terms of a weakly
nonlinear perturbation analysis, which is confirmed by numerical simulations of the basic model equations. The two relevant
parameters determining the bifurcation scenario of the model can be related to the concentrations of the active molecular
motors and of the filaments, respectively, which both could be easily regulated by the cell. 相似文献
118.
Considering the SM Higgs boson mass in the range of (95–235) GeV, we present here a mechanism for indirect searches of this scalar in UHE cosmic rays interactions. The mechanism is the decay of Higgs bosons which are produced through bubble formation due to vacuum excitation in an UHE cosmic rays interactions with air nuclei. We develop a model of hadronic interaction based on algorithms of the GENCL code of the UA5 experiment of CERN and some physics of CORSIKA code (Karlsruhe report), incorporating a fraction of energy transfer to bubble formation through vacuum excitation and subsequent multiparticle production via conversion of Higgs boson to heavy fermion pairs. Such events are expected to have high multiplicity and excess muons. This mechanism has significant effect starting from E
P 1018eV. It is found that the average muon number decreases gradually upto 175 GeV Higgs boson mass and remain practically constant thereafter for all primary energies (E
P) above 1018 eV and for all fractions of energy transfer (f
e 0.01–0.5). The fluctuation of muon multiplicity decreases with E
P and increases very slowly with Higgs mass upto 175 GeV, remaining practically invariant thereafter. 相似文献
119.
Ignition enhancement by addition of NO and NO2 from a N2/O2 plasma torch in a supersonic flow 总被引:1,自引:0,他引:1
Kenichi Takita Naoyuki Abe Goro Masuya Yiguang Ju 《Proceedings of the Combustion Institute》2007,31(2):2489-2496
The effects of NO and NO2 produced by using a plasma jet (PJ) of a N2/O2 mixture on ignition of hydrogen, methane, and ethylene in a supersonic airflow were experimentally and numerically investigated. Numerical analysis of ignition delay time showed that the addition of a small amount of NO or NO2 drastically reduced ignition delay times of hydrogen and hydrocarbon fuels at a relatively low initial temperature. In particular, NO and NO2 were more effective than O radicals for ignition of a CH4/air mixture at 1200 K or lower. These ignition enhancement effects were examined by including the low temperature chemistry. Ignition tests by a N2/O2 PJ in a supersonic flow (M = 1.7) for using hydrogen, methane, and ethylene injected downstream of the PJ were conducted. The results showed that the ignitability of the N2/O2 PJ is affected by the composition of the feedstock and that pure O2 is not the optimum condition for downstream fuel injection. This result of ignition tests with downstream fuel injection demonstrated a significant difference in ignition characteristics of the PJ from the ignition tests with upstream fuel injection. 相似文献
120.
Dunxi Yu Minghou Xu Hong Yao Jiancai Sui Xiaowei Liu Yun Yu Qian Cao 《Proceedings of the Combustion Institute》2007,31(2):1921-1928
The chemical composition of particles generated during pulverized coal combustion is the consequence of their formation processes. This work aims to use the size resolved elemental composition of coal-derived particles to identify their formation modes. A size-classified bituminous coal is burnt in a laboratory drop tube furnace at 1150, 1250, and 1350 °C, respectively. The elemental composition of the size-segregated particles from coal combustion is analyzed and the total mass fraction size distributions of Si and Al are obtained. Three particle formation modes are observed in these distribution profiles. The coarse mode has the highest value of the total mass fraction of Si and Al while the ultrafine mode has the lowest one. The total mass fraction of Si and Al in these two modes is nearly independent of particle size. It is believed that the coarse mode is formed by the mineral coalescence mechanism and the ultrafine mode by the vaporization–condensation mechanism. The difference in the total mass fraction of Si and Al between the central mode and the other two indicates that the central mode is formed by different mechanisms. Based on the observation that the total mass fraction of Si and Al in this mode increases with increasing particle size, heterogeneous condensation of vaporized species on existing fine residual ash particles is proposed to account for the formation of these particles. The study of the elemental composition of the three modes represented in five categories verifies the proposed formation mechanisms for them to some extent. 相似文献