Synthesis and characterization of light‐emitting oligo(p‐phenylene‐vinylene)s and polymeric derivatives containing three‐ and five‐conjugated phenylene rings. II. Electro‐optical properties and optimization of PLED performance

A series of multilayer polymeric light‐emitting diodes (PLEDs) containing an electron‐transporting layer (ETL), that is tris(8‐quinolinolato)‐aluminum(III) (Alq) and 2,2′,2″‐(1,3,5‐phenylene)‐tris[1‐phenyl‐1H‐benzimidazole] (TPBI), were fabricated by doping fluorescent oligo(p‐phenylene‐vinylene)s (BIII and BV) and polymer derivatives (PBV) into poly(N‐vinyl carbazole) (PVK). These PLEDs can be optimized by the design of multilayer device configurations (brightness increased 8–15 times by addition of ETL) and possess greenish electroluminescent (EL) spectra peaked about 500–540 nm. A remarkably high brightness of 56,935 cd/m² with a power efficiency of 3.25 lm/W was obtained in the device of PVK:BVOC₈‐OC₈ (100:20)/Alq (60 nm/60 nm). It suggests that the emission mechanism (including the conjugated and excimer emissions of BVOC₈‐OC₈ emitters) originates from both of BVOC₈‐OC₈ and ETL (Alq and TPBI) by varying the concentration of chromophores and adjusting the thickness of ETL. The concentration effect of the emitters in PVK (i.e. PVK:BVOC₈‐OC₈ = 100:5, 100:20, and 100:100 wt %) and the influence of the ETL (including its thickness) on the EL characteristics are also reported. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 2922–2936, 2006     

Frequency-dependent C(V) spectroscopy of the hole system in InAs quantum dots

The hole system in InAs quantum dots was investigated by frequency-dependent capacitance–voltage spectroscopy. Up to eight distinct charging peaks could be observed and the energy difference between the individual peaks could be estimated. All charging peaks decrease with increasing measurement frequency; however, the lower the energy of the hole level the stronger the decrease. A comparison with the results of the electron system in similar quantum dots yields that for all hole levels the effective mass in the barrier is much larger than in the electron system.     

含三苯胺的1,8-萘酰亚胺衍生物的合成及光谱和电化学性能研究

通过Suzuki偶联反应合成了一系列含三苯胺的1,8-萘酰亚胺衍生物，并进行了表征及光谱和电化学性能研究。研究表明该类化合物的荧光波长在584~610nm，位于橙色区。三苯胺的引入降低了化合物的HOMO值，有利于空穴的注入。     

Synthesis and properties of carbazole‐layered polymers

New aromatic ring‐layered polymers consisting of carbazole as a layered aromatic group and xanthene as a scaffold were designed and synthesized via the Sonogashira–Hagihara coupling reaction. Their optical and electrochemical behaviors were investigated in detail; the results showed that these polymers could be used as hole‐transporting materials. Polymers with nitrobenzene moieties at the polymer chain ends quenched the emission from the layered carbazoles to the nitrobenzene termini; thus, the polymers acted as the molecular wire that transferred photoexcited energy and/or electrons to the polymer termini. © 2009 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 47: 4279–4288, 2009     

Generalizing the Disappearing Act: A Reply to István Aranyosi

In “The Reappearing Act” István Aranyosi postulates a new way of seeing to solve a puzzle posed in “The Disappearing Act;” an object that is exactly shaded can be seen simply by virtue of its contrast with its environment – just like a shadow. This object need not reflect, refract, absorb or block light. To undermine the motive for this heretical innovation, I generalize the puzzle to situations involving inexact shading. Aranyosi cannot extend his solution to these variations because he needs to conserve principles of camouflage. On the bright side, the solution to the puzzle that I propose in my book Seeing Dark Things does extend to these variations.     

Colorability of Planar Graphs with Isolated Nontriangular Faces

By a hole graph we mean a 2-connected planar graph where no two nontriangular faces have a vertex in common. We give necessary and sufficient conditions for a hole graph to be 3-colorable.Acknowledgments. This paper was prepared in framework of the exchange program between the Austrian and Slovak Academies of Sciences. The third author was active at Department of Mathematics, Vanderbilt University and Fakulta prírodných vied, ilinská univerzita v iline.Mathematics Subject Classification (1991): 05C15     

An investigation into melt flow dynamics during repetitive pulsed laser drilling of transparent media

This paper presents an investigation into the dynamics of repetitive pulsed laser drilling of a visually transparent media using a CO₂ laser source. This enabled the use of a high-speed imaging system for observing, in real time, the behaviour of the drilling process in the laser drilled cavity of 1.5 mm diameter holes of up to 18.5 mm in depth. The work revealed that the instantaneous drilling velocity within each laser pulse can vary considerably from the average drilling velocity as a result of the non-uniform temporal pulse shape and the oscillation of the melt ejection rate. During beam breakthrough, both upward and downward melt ejections were observed to occur inside the drilled hole for a short period of time, after which the material was ejected through the exit end of the holes. It has been shown in this work that the downward melt flow velocity increases with hole depth for a positively tapered hole (from 0.09 to 1.43 m/s) and decreases with hole depth for a negatively tapered hole geometry (from 0.4 to 0.1 m/s), as a result of the change in the assist gas velocity inside the drilled hole with respect to the hole taper geometry. The mechanisms of forming the positively and negatively tapered holes in the transparent media have been correlated with the hole geometry and melt flow velocity. The work has demonstrated a new method of studying the melt dynamics in laser drilling.     

Hole diameter effect on flow characteristics of wake behind porous fences having the same porosity

The hole diameter effect on the flow characteristics of wake behind porous fences has been investigated experimentally in a circulating water channel having a test section of 300^w×200^h×1200^l (mm). Three porous fences having different hole diameters of d=1.4,2.1,2.8 mm were tested in this study, but they have the same =38.5% geometric porosity. One thousand instantaneous velocity fields for each fence were measured consecutively by the hybrid PTV system employing a high-speed CCD camera. Free stream velocity was fixed at 10 cm/sec and the corresponding Reynolds number based on the fence height was Re=2,985. Consequently, the fence with the smallest hole diameter d=1.4 mm (d_1.4) decreases the streamwise velocity component and increases the vertical velocity component. Among the three hole diameters tested in this study, the d_1.4 fence has the largest turbulence intensity in the shear layer developed from the fence top. Regardless of the hole diameter, however, all three fences having the same porosity reduce the reduction of turbulent intensity in the lower region below the fence height (y/H<1).     

一种蓝色有机发光材料的合成及性质

一种蓝色有机发光材料的合成及性质;蓝色发光材料; 空穴传导; 电子传导; 咔唑; 邻啡咯啉