Rheologische Untersuchungen an Polyacrylnitril-Spinnlösungen: Erweiterung des Viskosimeters HV 6 für höhere Temperaturen

Zusammenfassung Das Hochdruckkapillarviskosimeter HV 6 wurde für Messungen bei höheren Temperaturen adaptiert; dadurch konnten konzentrierte Lösungen von Polyacrylnitril in Dimethylformamid bis zu 120°C vermessen werden. Die erhaltenen Resultate wurden nach der Methode Vinogradov-Malkin normiert; gewisse Abweichungen, die hierbei auftraten, konnten durch Einführung eines empirischen Zusatzverschiebungsfaktors korrigiert werden.

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Summary The high pressure capillary viscometer HV 6 has been adapted for measurements at high temperatures. Concentrated solutions of polyacrylonitrile in dimethylformamide could be measured up to 120°C. The results were plotted by the Vinogradov-Malkin mastercurve method. Deviations could be corrected by introducing an empirical additional shift factor.

Mit 17 Abbildungen     

The Experimental Approach to Effective Stress Law of Coal Mass by Effect of Methane

Effective stress law of all kinds of coal samples, including steam coal, fat coal, corking coal, thin coal and anthracite, under pore pressure of gas, is experimentally studied using a newly developed test machine. These samples are taken from Coal Mines in Wuda, Hebi, Yanzhou, Yangquan, Qingshui, and Gujiao in China. The experiment results show that, under pore pressure of gas, the tested coal samples comply with Biots effective stress law, where the Biots coefficient is not a constant, and is bilinear function of volumetric stress () and pore pressure (p), that is, We define four areas according to the numerical feature of , that is, functionless area of pore pressure, normal function area, fracturing function area, and quasi-soil function area. The effective stress law of coal mass introduced by this paper is a constitutive equation in the study of coupled solid and fluid. This has significance in the drainage and outburst of methane in coal seam.     

Shear Failure of Inconel 718 under Dynamic Loads

Kinetics of deformation and fracture of nickel–iron alloy Inconel 718 under dynamic shear loading was measured using a split torsional Hopkinson bar facility and high-speed photography. Tubular specimens with a reduced gage length and a starter notch were sheared at strain rates up to 6 × 10³ s⁻¹. High-speed photographs of fiducial lines scribed on the specimen surface showed the development of local strains and cracking. This paper describes the experimental and analytical procedures, illustrates average and local plastic strain evolution, and presents shear crack initiation times and propagation speeds.     

锦屏水电站解放沟反倾高边坡变形机制的探讨

通过对锦屏水电站某一反倾高边坡的野外调查、室内测试实验及数值模拟计算分析 ,对其变形机制有了进一步的认识。对以往的结论重新进行论证 ,用证据说明问题 ,最终得出新的研究成果。本文认为解放沟左岸深层变形是由河谷快速下切过程中边坡发生深部卸荷松弛和倾内层状体斜坡的深部岩层弯曲倾倒共同作用所引起     

Deformation and failure mechanism in AISI 4340 steel under ballistic impact

Deformation and failure mechanism in quench-hardened AISI 4340 steel under ballistic impact is investigated. The influence of microstructure on damage evolution is also evaluated. Strain localization and shear failure along adiabatic shear bands are the dominant deformation and failure mechanisms. The time and critical strain for the commencement of strain localization is influenced by strain rate and microstructure. The microstructure of the steel sample also influenced the type of adiabatic shear bands formed during impact. Failure mechanism involves nucleation of micro-voids, which clusters to form bigger pores. Extremely fine micro-cracks are initiated adjacent to the pores and in shear flow direction along the shear bands. These micro-cracks become interconnected and grow to macro-cracks, which cause fracture of some of the investigated cylindrical steel samples under impact. The susceptibility of the adiabatic shear bands to cracking increases with decreasing tempering temperature of the steel.     

关于三峡永久船闸高边坡快速施工地质超前预报的几个问题

文中就三峡永久船闸高边坡快速施工地质超前预报的几个问题进行了讨论。分别研究了三峡永久船闸高边坡施工地质超前预报的必要性，提出了超前预报技术思路，最后就高边坡岩体反分析及反馈设计问题、施工地质超前预报问题以及与监测相适应的超前处理及防护进行了分析。     

Structural transitions under high-pressure in a langasite-type multiferroic Ba3TaFe3Si2O14

The iron containing langasite family compound Ba₃Ta⁵⁷Fe₃Si₂O₁₄ was studied at high pressure up to 30 GPa at room temperature by means of in situ X-ray diffraction, Raman and Mössbauer spectroscopies in diamond anvil cell. Two structural transitions at pressures ∼5 and ∼20 GPa are observed. At ∼5 GPa, the low-pressure trigonal P321 phase undergoes phase transition to the most likely P3 structure as manifested by slight increase in the c/a ratio and by anomalies of the Mössbauer and Raman spectra parameters. At ∼20 GPa, the first order phase transition to monoclinic structure occurred with a drop of unit cell volume by 9%. The appearance of the ferroelectric state at such transitions is discussed in connection with the multiferroic properties.     

Preparation of a monolith functionalized with zinc oxide nanoparticles and its application in the enrichment of fluoroquinolone antibiotics

This study describes the enrichment ability of ZnO‐modified methacrylic acid‐co‐ethylene dimethacrylate polymer monoliths as stationary phases for the simultaneous determination of antibiotics (ofloxacin, ciprofloxacin, enoxacin, and pefloxacin) combined with high‐performance liquid chromatography. The prepared monolith was characterized by scanning electron microscopy, X‐ray photoelectron spectroscopy, Fourier‐transformed infrared spectroscopy, and thermogravimetric analysis. The polymer monolith microextraction method has been applied to the enrichment of fluoroquinolone antibiotics and satisfactory results were obtained in the analysis of water samples. Compared with the conventional methacrylic acid based monolith, the developed monolith exhibited a higher enrichment capacity because of the introduction of zinc oxide into the preparation process.     

Separation of five compounds from leaves of Andrographis paniculata (Burm. f.) Nees by off‐line two‐dimensional high‐speed counter‐current chromatography combined with gradient and recycling elution

An off‐line two‐dimensional high‐speed counter‐current chromatography method combined with gradient and recycling elution mode was established to isolate terpenoids and flavones from the leaves of Andrographis paniculata (Burm. f.) Nees. By using the solvent systems composed of n‐hexane/ethyl acetate/methanol/water with different volume ratios, five compounds including roseooside, 5,4′‐dihydroxyflavonoid‐7‐O‐β‐d ‐pyranglucuronatebutylester, 7,8‐dimethoxy‐2′‐hydroxy‐5‐O‐β‐d ‐glucopyranosyloxyflavon, 14‐deoxyandrographiside, and andrographolide were successfully isolated. Purities of these isolated compounds were all over 95% as determined by high‐performance liquid chromatography. Their structures were identified by UV, mass spectrometry, and ¹H NMR spectroscopy. It has been demonstrated that the combination of off‐line two‐dimensional high‐speed counter‐current chromatography with different elution modes is an efficient technique to isolate compounds from complex natural product extracts.