磁盘润滑膜全氟聚醚的分子动力学模拟研究

纳米润滑膜全氟聚醚(perfluoropolyether，简称PFPE)在固体表面的结构和迁移特性对于计 算机磁盘磁头驱动系统的可靠性具有重要的作用. 采用基于粗粒珠簧模型的分子动力学模拟 方法，考察了不同壁面和端基极性对于PFPE膜静态特性（如分子构型、单体密度分布、端基 密度分布）以及动态特性（如自扩散系数）的影响. 静态特性的模拟结果表明，非极性PFPE 膜在壁面附近具有单层厚度为一个单体直径的层状结构，而极性PFPE膜则具有复杂的层状结 构. 动态特性的模拟结果表明，PFPE膜的扩散能力因壁面作用而增强并因端基极性作用而减 弱. 关键词： 全氟聚醚膜 分子动力学模拟 薄膜润滑 固液界面结构     

Influence of Si/SiO2 interface properties on electrical performance and breakdown characteristics of ultrathin stacked oxide/nitride dielectric films

In this work, the influence of Si/SiO₂ interface properties, interface nitridation and remote-plasma-assisted oxidation (RPAO) thickness (<1 nm), on electrical performance and TDDB characteristics of sub-2 nm stacked oxide/nitride gate dielectrics has been investigated using a constant voltage stress (CVS). It is demonstrated that interfacial plasma nitridation improves the breakdown and electrical characteristics. In the case of PMOSFETs stressed in accumulation, interface nitridation suppresses the hole traps at the Si/SiO₂ interface evidenced by less negative V_t shifts. Interface nitridation also retards hole tunneling between the gate and drain, resulting in reduced off-state drain leakage. In addition, the RPAO thickness of stacked gate dielectrics shows a profound effect in device performance and TDDB reliability. Also, it is demonstrated that TDDB characteristics are improved for both PMOS and NMOS devices with the 0.6 nm-RPAO layer using Weibull analysis. The maximum operating voltage is projected to be improved by 0.3 V difference for a 10-year lifetime. However, physical breakdown mechanism and effective defect radius during stress appear to be independent of RPAO thickness from the observation of the Weibull slopes. A correlation between trap generation and dielectric thickness changes based on the C-V distortion and oxide thinning model is presented to clarify the trapping behavior in the RPAO and bulk nitride layer during CVS stress.     

The dynamics of random interfaces in phase transitions

A review is given of recent developments involving the dynamics of random interfaces formed in the evolution of metastable and unstable systems. Topics which are discussed include interface growth and nonequilibrium dynamical scaling. The possibility of there being dynamical universality classes in first-order phase transitions is also discussed. There are a large number of systems of experimental interest which include binary alloys, binary fluids, and polymer mixtures. Other systems studied by computer simulation include the kinetic Ising, Potts, andZ _N models.Work supported by NSF grant No. DMR-8013700.     

氢离子轰击对TiC膜结构及界面影响的研究

本文研究荷能氢离子轰击对TiC薄膜的结构及其界面的影响。氢离子源为5A的脉冲离子注入器,能量25keV,脉冲宽度20ms。样品经轰击后发现。与受相同辐照的45~#钢样品相比,TiC薄膜表面无明显的损伤;TiC薄膜内的氢含量较高;薄膜的织构消除;TiC薄膜与基体间的结合力有明显提高。     

Construction of inclusions with vanishing generalized polarization tensors by imperfect interfaces

We investigate the problem of planar conductivity inclusion with imperfect interface conditions. We assume that the inclusion is simply connected. The presence of the inclusion causes a perturbation in the incident background field. This perturbation admits a multipole expansion of which coefficients we call as the generalized polarization tensors (GPTs), extending the previous terminology for inclusions with perfect interfaces. We derive explicit matrix expressions for the GPTs in terms of the incident field, material parameters, and geometry of the inclusion. As an application, we construct GPT-vanishing structures of general shape that result in negligible perturbations for all uniform incident fields. The structure consists of a simply connected core with an imperfect interface. We provide numerical examples of GPT-vanishing structures obtained by our proposed scheme.     

空间轴对称变形界面裂纹尖端的应力奇异性分析

假定位移场,并将位移势函数展开成一系列的特征函数,代入空间轴对称变形的基本方程,推得界面裂纹的特征值理论。把这一理论应用到单向增强的连续纤维复合材料上,建立了纤维断裂、基体开裂等模型下应力奇异性的特征方程,分析了界面裂纹尖端的应力奇异性。     

Interface interactions in modulated phases,and upsilon points

Certain features in Frenkel-Kontorova and other models of phases with a one-dimensional modulation can be analyzed by assuming parallel interfaces separating sets of lattice planes belonging to two different phases, and treating the free energy to create interfaces, as well as the interaction of two, three, or more interfaces, as phenomenological parameters. A strategy employed by Fisher and Szpilka for interacting defects can be extended to the case of interfaces, allowing a systematic study of the phase diagram by ignoring all interface interactions, and then successively taking into account pair, triple, and higher-order terms. The possible phase diagrams which can occur near the point where =0 include: various sorts of endpoints analogous to critical endpoints, an accumulation point of first-order transitions and triple points, and a self-similar structure which we call an upsilon point, which turns out to be an accumulation point of an infinite number of segments of first-order transition lines, each of which terminates in two upsilon points.     

Two Dimensional Interface Problems for Elliptic Equations

We study the structure of solutions to the interface problems for second order quasi-linear elliptic partial differential equations in two dimensional space. We prove that each weak solution can be decomposed into two parts near singular points, a finite sum of functions in the form of cr^α log^m rφ(θ) and a regular one w. The coefficients c and the C^{1,α} norm of w depend on the H¹-norm and the C^{º,α}-norm of the solution, and the equation only.     

Diffraction of a Plane Discontinuos Wave in Layered Anisotropic Elastic Media

The problem of transformation of the front of a plane longitudinal shock wave by curvilinear interfaces of layered anisotropic elastic media with different mechanical properties is considered. To solve the nonlinear Snell equations, the approach based on a synthesis of the Newton method and the algorithm of parametric continuation of a solution is used. The cases of focusing and scattering of rays by convex and concave interfaces of layered composite media and by convex lenses are investigated. Numerical examples are given for various ratios between the parameters of the elastic media.     

FREE BOUNDARY PROBLEM ARISING FROM EVAPORATION FROM POROUS MEDIUM

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