全文获取类型
收费全文 | 402篇 |
免费 | 34篇 |
国内免费 | 34篇 |
专业分类
化学 | 84篇 |
晶体学 | 2篇 |
力学 | 5篇 |
综合类 | 1篇 |
物理学 | 378篇 |
出版年
2023年 | 1篇 |
2022年 | 9篇 |
2021年 | 12篇 |
2020年 | 13篇 |
2019年 | 6篇 |
2018年 | 12篇 |
2017年 | 9篇 |
2016年 | 8篇 |
2015年 | 12篇 |
2014年 | 8篇 |
2013年 | 42篇 |
2012年 | 30篇 |
2011年 | 41篇 |
2010年 | 23篇 |
2009年 | 25篇 |
2008年 | 38篇 |
2007年 | 19篇 |
2006年 | 24篇 |
2005年 | 18篇 |
2004年 | 22篇 |
2003年 | 14篇 |
2002年 | 6篇 |
2001年 | 12篇 |
2000年 | 10篇 |
1999年 | 9篇 |
1998年 | 8篇 |
1997年 | 6篇 |
1996年 | 4篇 |
1995年 | 6篇 |
1994年 | 5篇 |
1993年 | 2篇 |
1992年 | 1篇 |
1990年 | 2篇 |
1989年 | 1篇 |
1987年 | 2篇 |
1986年 | 1篇 |
1985年 | 1篇 |
1984年 | 1篇 |
1982年 | 1篇 |
1981年 | 2篇 |
1980年 | 1篇 |
1977年 | 1篇 |
1974年 | 1篇 |
1973年 | 1篇 |
排序方式: 共有470条查询结果,搜索用时 31 毫秒
51.
52.
We present 15-dimensional quantum multiconfiguration time-dependent Hartree calculations of the vibrational levels of the He5I2 van der Waals (vdW) complex employing an ab initio-based potential energy surface (PES). The energies and spatial features of such bound structures are analyzed, providing predictions on the structures and relative stabilities of its three lowest isomers. We found that the most stable isomer corresponds to all five He atoms encircling the I2 molecule, indicating that in this case the anharmonic quantum effects do not stabilize the isomers involving a He atom in a linear configuration as reported previously for the smaller HeNI2 systems. Such finding provides information on the overall structuring of the finite-size-solvent systems, highlighting the intriguing interplay between weak intermolecular interactions and quantum effects. © 2019 Wiley Periodicals, Inc. 相似文献
53.
The present paper concentrates on structure and micro-mechanical properties of the helium-implanted layer on titanium treated by plasma-based ion implantation with a pulsed voltage of −30 kV and doses of 3, 6, 9 and 12 × 1017 ions/cm2, respectively. X-ray photoelectron spectroscopy and transmission electron microscopy are employed to characterize the structure of the implanted layer. The hardnesses at different depths of the layer were measured by nano-indentation. We found that helium ion implantation into titanium leads to the formation of bubbles with a diameter from a few to more than 10 nm and the bubble size increases with the increase of dose. The primary existing form of Ti is amorphous in the implanted layer. Helium implantation also enhances the ingress of O, C and N and stimulates the formations of TiO2, Ti2O3, TiO, TiC and TiN in the near surface layer. And the amount of the ingressed oxygen is obviously higher than those of nitrogen and carbon due to its higher activity. At the near surface layer, the hardnesses of all implanted samples increases remarkably comparing with untreated one and the maximum hardness has an increase by a factor of up to 3.7. For the samples implanted with higher doses of 6, 9 and 12 × 1017 He/cm2, the local displacement bursts are clearly found in the load-displacement curves. For the samples implanted with a lower dose of 3 × 1017 He/cm2, there is no obvious displacement burst found. Furthermore, the burst width increases with the increase of the dose. 相似文献
54.
Cleveland ZI Pavlovskaya GE Stupic KF Wooten JB Repine JE Meersmann T 《Magnetic resonance imaging》2008,26(2):270-278
Despite the importance of the tobacco smoke particulate matter in the lungs to the etiology of pulmonary disease in cigarette smokers, little is currently known about the spatial distribution of particle deposition or the persistence of the resulting deposits in humans, and no satisfactory technique currently exists to directly observe tobacco smoke condensate in airways. In this proof-of-principle work, hyperpolarized (hp) 83Kr MRI and NMR spectroscopy are introduced as probes for tobacco smoke deposition in porous media. A reduction in the hp-83Kr longitudinal (T1) relaxation of up to 95% under near-ambient humidity, pressure and temperature conditions was observed when the krypton gas was brought into contact with surfaces that had been exposed to cigarette smoke. This smoke-induced acceleration of the 83Kr self-relaxation was observed for model glass surfaces that, in some experiments, were coated with bovine lung surfactant extract. However, a similar effect was not observed with hp-(129)Xe indicating that the 83Kr sensitivity to smoke deposition was not caused by paramagnetic species but rather by quadrupolar relaxation due to high adsorption affinity for the smoke deposits. The 83Kr T1 differences between smoke-treated and untreated surfaces were sufficient to produce a strong contrast in variable flip angle FLASH hp-83Kr MRI, suggesting that hp-83Kr may be a promising contrast agent for in vivo pulmonary MRI. 相似文献
55.
56.
本特种工程车用空调器采用蒸气压缩制冷原理,即利用液态制冷剂吸热汽化产生制冷效应,利用车上的发动机作为驱动源,通过皮带传动带动压缩机工作,使制冷剂在系统内产生循环,通过换热器与空气进行热交换,从而实现车室的降温要求。制冷剂采用新型环保制冷剂R134 a,整机结构紧凑、性能可靠、换热效率高。 相似文献
57.
Comprehensive performance of a ball-milled La0.5Pr0.5Fe11.4Si1.6B0.2Hy/Al magnetocaloric composite
下载免费PDF全文
![点击此处可从《中国物理 B》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Jiao-Hong Huang 《中国物理 B》2022,31(4):47503-047503
Due to the hydrogen embrittlement effect, La(Fe,Si)13-based hydrides can only exist in powder form, which limits their practical application. In this work, ductile and thermally conductive Al metal was homogeneously mixed with La0.5Pr0.5Fe11.4Si1.6B0.2 using the ball milling method. Then hydrogenation and compactness shaping of the magnetocaloric composites were performed in one step via a sintering process under high hydrogen pressure. As the Al content reached 9 wt.%, the La0.5Pr0.5Fe11.4Si1.6B0.2Hy/Al composite showed the mechanical behavior of a ductile material with a yield strength of ~44 MPa and an ultimate strength of 269 MPa accompanied by a pronounced improvement in thermal conductivity. Due to the ease of formation of Fe-Al-Si phases and the several micron and submicron sizes of the composite particles caused by ball milling process, the magnetic entropy change of the composites was substantially reduced to ~1.2 J/kg· K-1.5 J/kg· K at 0 T-1.5 T. 相似文献
58.
59.
Tatiana Korona Bogumil Jeziorski Robert Moszynski Geerd H. F. Diercksen 《Theoretical chemistry accounts》1999,101(4):282-291
Symmetry-adapted perturbation theory is extended to the (quasi) degenerate, open-shell case. The new formalism is tested
in calculations of the interaction energies for a helium atom in the ground state interacting with an excited hydrogen atom.
It is shown that the method gives satisfactory results if the coupling with higher Rydberg states of the dimer is small, as
is the case for the A2Σ+,B2Π,E2Π,32Π, and 12Δ states of HeH. For the C2Σ+ state convergence of the method is very slow, but it can be improved by including the n=3 states in the model space.
Received: 3 June 1998 / Accepted: 9 September 1998 / Published online: 7 December 1998 相似文献
60.
D. F. Brewer 《Physica B: Condensed Matter》2000,280(1-4):4-10
Experiments with helium in thin films and small pores show that the bulk properties are greatly modified. With 4He, the onset of superfluidity is depressed and the specific heat anomaly is rounded and also depressed to lower temperatures. With 3He new features are found such as surface magnetism and free path effects. Bulk superfluid 4He is shown to have a sharp transition to turbulence, and bulk 3He the characteristics of a Fermi fluid. 相似文献