多特征波长窗法检测痕量甲醛气体的研究

为了克服化学检测痕量甲醛气体速度慢、有耗材、采样区域局限等缺点,实现快速准确地检测甲醛气体的浓度,设计了一种多特征波长窗的方法。根据甲醛及主要干扰气体的特征光谱选择相干度最小的多组特征波长,特征波长个数分别选用3,4和5个,同时配合相应的多组窄带滤光片。当光源依次通过这些窗口及气室后,由PCI-2TE-13型红外探测器采集,并经相关算法反演样气中的甲醛浓度。实验针对新装修的房屋、建材商场、超市及公园四种环境下采集的样气中的甲醛进行定量分析。实验结果与ARCSpectro-A-MIR型红外光谱仪的检测结果相比较,结果表明,采用多特征波长窗法在10μg.m-3以上的检测结果均与标准值相近,其平均误差均小于5%,满足实际应用的要求,并且具有实时检测、不中毒等优点。     

Spectral target-detecting system using sine-wave modulation

Target detection is one of the key technology of precision chemical application.Previously the digital coding modulation technique was commonly used to emit and receive the optical signal in the target detection systems previously in China.It was difficult to adjust the output power,and the anti-interference ability was weak in these systems.In order to resolve these problems,the target detection method based on analog sine-wave modulation was studied.The spectral detecting system was set up in the aspects ...     

Non-stretch mappings for a sharp estimate of the Beurling–Ahlfors operator

In this paper we identify certain classes of non-stretch mappings that enjoy a sharp estimate of the Beurling–Ahlfors operator. We first make use of a property of subharmonic functions to prove that the Bañuelos–Wang conjecture and the Iwaniec conjecture are true for a class of mappings that satisfy a quasilinear conjugate Beltrami equation. By utilizing the principal solutions of Beltrami equations, we further explicitly construct some classes of non-stretch mappings for which the Bañuelos–Wang conjecture and the Iwaniec conjecture are true.     

Universal prediction-based adaptive fault estimator applied to secure communication

In this paper, a communication scheme that could use a nonlinear dynamical system to create encrypted keys with an additional dimension is proposed, and the scheme could keep encrypted keys not to diverge. Since the divergence of encrypted keys (nonlinear signals) easily happens in non-linear systems coupled with other systems, the adaptive control approach, proposed in this paper, uses the universal state-space adaptive observer-based fault diagnosis/estimator and the high-performance tracker to eliminate the divergence of encrypted keys. At the same time, the receiver of communication retrieves informal messages by the universal state-space adaptive observer-based fault diagnosis/estimator and the high-performance tracker. Thus, this paper takes advantage of the merit of digital redesign methodology for a practical implementation of secure-communication, and the estimator solves the problem of secure communication. Thus developed a new approach could add more dimensions into nonlinear secure-communication systems without having the problem of divergence of encrypted keys.     

An ultra-fast smoothing algorithm for time–frequency transforms based on Gabor functions

Gabor functions, Gaussian wave packets, are optimally localized in time and frequency, and thus in principle ideal as (frame) basis functions for a wavelet, windowed Fourier or wavelet-packet transform for the detection of events in noisy signals or for data compression. A major obstacle for their use is that a tailored efficient operator acting on the transform coefficients for altering the width of the wave packets does not exist. However, by virtue of a curious property of the Gabor functions it is possible to change the width of the wave packets using just one-dimensional convolutions with very short kernels. The cost of a wavelet-type transform based on the scheme presented below is similar to that of a low order wavelet transform for a compact kernel and significantly less than the algorithme à trous. The scheme can hence easily be employed for the processing of signals in real time.     

Chemical Detection Of Selected Hallucinogens In Water

Abstract

A specific and non-destructive test for basic esters of benzilic and α-glycolic acids in water is described. The compounds are collected on a glass fiber filter as water insoluble complexes with sodium tetraphenylboron. The filter is dried and sprayed with a 2-diphenylacetyl-l, 3-indandione-l-imine derivative. A positive test is the visual observation of fluorescence.     

Ultraviolet detection of amino acids based on their on-column conjugation with cupric cation using a disposable electrophoresis microdevice

A method for fast sensitive ultraviolet detection of amino acids was developed with a disposable electrophoresis microdevice. The microdevice was conveniently constructed by fixing a fused-silica capillary with a sampling fracture to a printed circuit board. During the separation process, the on-column conjugation of amino acids with cupric cation led to the ultraviolet absorption at 232 nm that could be directly used for fast analysis of amino acids. Using 20 mM boric acid (pH 5.3) containing 5 mM cupric cation and 0.015% Tween 20 as running buffer, this method could completely separate lysine, glutamine and serine at a sampling time of 2 s at +210 V and a separation voltage of +1800 V (240 V/cm). The theoretical plate numbers were from 140,000 to 205,000 plates/m. The linear ranges were from 10 to 500 μM for lysine, 20-1000 μM for glutamine and serine. The novel protocol had been successfully used to detect amino acids in beverage samples with recovery more than 85.0%, indicating its advantages and potential analytical application in different fields.     

“Turn-on” Fluorescent Detection of 2,5-Di（4＇-carboxylphenyl）-1-phenylpyrrole to Amines

基于水溶性2,5-二（4＇-羧基苯基）-1-苯基吡咯的羧酸钠盐（TPP-2COONa）具有质子化荧光淬灭、去质子化荧光增强的特征.在研究了TPP-2COONa的紫外吸收光谱和荧光发射光谱对pH的响应规律的同时,以此为荧光探针,证实了TPP-2COOH对于多种胺类（氨水、二异丙胺、异丙胺和三乙胺）荧光增强响应明显,而对芳香胺（吡咯、苯胺、吡啶）没有任何荧光响应,其中对于氨水最为敏感,在很窄的pH区间和低浓度范围内荧光强度大幅度增长,体现了该探针对于氨水具有良好的选择性和灵敏度,并可简易实现＂在线裸眼检测＂.