Hg2准分子远紫外发射谱带研究

报道在高压汞弧灯中首次观测到Ｈｇ２准分子在２２５－２３５ｎｍ谱区、峰值位于２３０ｎｍ左右的连续发射谱带。实验研究了此发射带随温度的变化，与理论计算的辐射谱相比较，两者十分相符。     

2D Simulations of Short‐Pulsed Dielectric Barrier Discharge Xenon Excimer Lamp

Self‐consistent two‐dimensional (2D) simulations of short‐pulsed dielectric barrier discharge (DBD) in pure xenon have been performed. It is shown that during short current pulse the traversal inhomogeneity of the plasma parameters can be important only at the end of the current pulse as an edge effect close to the side walls. During the current pulse, the gap voltage drops until the ionization wave reaches the cathode so the current in the cathode sheath is the displacement current. This means that almost all of the absorbed power is deposited into excitation of xenon atoms and not to the ion heating in the cathode sheath as in the traditional glow discharges. This fact is one of the reasons of high efficiency of short‐pulsed DBD. The developed model allows one to estimate the temporal position of the plasma‐sheath boundary. (© 2006 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

Computational studies of vinyl-stabilized halonium ions

Conformational studies of 1-halo-2-butenylcations have been carried out by means of density functional and ab initio calculations. The presence of an adjacent vinyl group reduced the importance of bridging by halogen atoms as evidenced by geometric and energetic analyses. Eclipsed forms were found to be minima in several cases.     

Endocrine-disrupting pollutants properties affecting their bioactivity,remediation, and detection

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实现均匀照明的LED系统设计方法

针对医用无影灯的应用要求,提出了一种利用非球面透镜实现对目标平面均匀照明的方法。基于能量守恒定律得到光源出射角与目标面之间的关系,利用Zemax的宏语言编写优化操作数使透镜优化满足上述关系,在非序列模式中对结果进行模拟和优化,并分别对透镜的前表面三种情况进行模拟,提出并模拟了LED球面阵列,并分析了角度及距离的偏移对照明均匀度的影响。结果表明,1m距离处实现了直径为25cm的平面内的均匀照明,均匀度(平均照度/最大照度)达到96%以上;球面阵列的设计可以满足无影灯的光分布要求,照明深度达到1m。     

Synthesis of sulfonyloxy furoxans via hydroxyfuroxan ammonium salts

Furoxans are distinctive heteroaromatic compounds in that they are potentially capable of releasing nitric oxide under physiological conditions. In order to utilize the furoxan scaffold for the development of functional molecules, synthetically relevant functional groups are required for access to diverse furoxans. In this report, a facile route to furoxans with sulfonyloxy groups, which are halide surrogates, has been developed. The key features of this strategy include the synthesis and utilization of bench-stable hydroxyfuroxan salts, the use of sulfonyl anhydrides in the sulfonylation step instead of sulfonyl chlorides, and the photochemical isomerization of one regioisomer to another in order to gain access to both.     

Photodegradation of rhodamine B dye using a microwave electrodeless UV lamp (MWUVL)

The photodegradation of organic dye rhodamine B (RhB) in an aqueous solution was studied using a microwave electrodeless UV lamp (MWUVL). The 185 nm vacuum UV (VUV) intensity of the MWUVL amounted to 12% of the total UV output, about 1.7 times as high as that of the con ventional low-pressure mercury lamp. An acidic condition was preferred for the degradation of RhB. Precipitate was generated during RhB degradation when the initial concentration of RhB solution was above 60 mg · L⁻¹. For 100 mg · L⁻¹ RhB at pH 4.0, the mass of precipitate produced was nearly half of the initial amount of RhB in the solution after irradi ation for 75 min. The corresponding degradation ratio of RhB reached up to 99.4% and COD reduced 77.4%. The photo degradation of RhB is mainly achieved by direct photolysis of RhB by 185 nm and OH radical oxidation. __________ Translated from Journal of Fudan University (Natural Science), 2006, 45(6): 726–731 [译自: 复旦学报 (自然科学版)]     

用合肥800 MeV同步辐射光源标定氘灯的光谱辐射亮度

利用合肥800 MeV电子存储环同步辐射(HESYR)作为紫外真空紫外光谱辐射测量的绝对标准,标定了传递标准氘灯光源的光谱辐亮度。采用德国国家物理技术研究院(PTB)的数据处理及不确定度分析方法,得到了两支氘灯在115~300nm波段的光谱辐亮度数据,其相对定标不确定度为12.1%。详细分析了相关参量对定标不确定度的贡献,指出辐射计量系统偏振特征量的不确定度贡献最大。在164~300 nm波段,德国德国国家物理技术研究院在BESSYⅡ同步辐射装置上标定的绝对光谱辐亮度值与本实验在中国合肥同步辐射装置上标定的绝对光谱辐亮度值之间一致性优于±20%,在给定的不确定度范围内两光谱辐射标准定标结果一致。     

具有红外反射膜的节能卤素灯

研究了节能卤素灯的技术和设计问题.给出了红外反射膜的厚度对近红外波段的反射率分布以及该涂层对2 850 K照明光源在可见光范围内的影响,讨论了灯丝和泡壳的几何形状,以及钨丝对红外反射能量的吸收.实验表明：1）当选用9层膜时,实验数据与计算值偏差很微小.当灯的管径为10 mm,而灯丝外径为1.5 mm时,节能可达12%到13%.2）对圆柱形灯外壳,在不考虑端面影响时,光源的灯丝若处于外壳的中心轴上,则反射的能量会有效地返回灯丝.3）螺旋结构的灯丝比表面光滑的直钨丝有更高的吸收率,灯丝绕成螺旋后在现行的螺距尺寸下吸收率能达到0.6~0.7.     

Gas chromatographic retention of 180 polybrominated diphenyl ethers and prediction of relative retention under various operational conditions

The gas chromatographic (GC) retention times of 180 polybrominated diphenyl ethers (PBDEs) were obtained under different operational conditions on two types of commonly used capillary columns, Restek Rtx-1614 and J&W DB-5MS, of different dimensions. The relative retention times (RRTs) for PBDEs were calculated by normalizing the retention times of individual congeners to the sum of those of BDEs 47 and 183. In clear contrast to polychlorinated biphenyls (PCBs), the elution of PBDEs has few cross-homolog overlaps, and this observation is discussed in terms of molecular conformation with regard to co-planarity. Within a homolog, ortho substitution in PBDEs tends to decrease GC retention, and such an effect is stronger for higher homologs. With the RRT database established in this work, a simple approach is evaluated for the identification of all mono to hepta PBDEs from the RRTs of 39 congeners under various GC conditions to facilitate the identification of unknown PBDE peaks for which chemical standards are not available.