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11.
Dr. Dingfeng Yang Junzhu Yang Xuejun Quan Bin Zhang Guoyu Wang Xu Lu Xiaoyuan Zhou 《Chemphyschem》2021,22(24):2579-2584
Understanding the correlation between crystal structure and thermal conductivity in semiconductors is very important for designing heat-transport-related devices, such as high-performance thermoelectric materials and heat dissipation in micro-nano-scale devices. In this work, the lattice thermal conductivity ( ) of the cage-like compounds Cu3VSe4 and Cu3NbSe4 was investigated by experimental measurements and first-principles calculations. The experimental of Cu3NbSe4 is approximately 25 % lower than that of Cu3VSe4 at 300 K. The relevant important physical parameters, including the sound velocity, heat capacity, weighted phonon phase space (W), and third-order force constants along with atomic mass were theoretically analyzed. It is found that W is the dominant parameter in determining the , and the other factors only play a minor role. The physical origin is the relatively “soft” lattice of Cu3NbSe4 with heavier atomic mass. This research provides deep insight into the correlation between the thermal conductivity and crystal structure and paves the way for discovering high-performance thermal management device and thermoelectric materials with intrinsically low . 相似文献
12.
A mathematical method to solve structural problems, using parameter-transfer finite elements (P-TFE) was recently proposed by the authors [1] [2] [3]. The proposed transfer finite element approach is able to create a mathematical model of a structure, taking into account directly the whole behaviour of the structure under dynamic, aerodynamic, and thermal actions, and not by assembling, in a separate fashion, the stiffness and the mass matrix on one side and the external load vector as performed by the classical finite element procedure.The purpose of this paper is to apply the above methodology to optimization problems, in particular to obtain the minimum structural weight for a beam, under primary constraints on buckling load or natural frequencies.The use of P-TFE in the field of structural optimization overcomes most difficulties of the usual techniques of solution and the element is particularly useful in the evaluation of the sensitivity matrix.The formulation of the optimization problem based on P-TFE is presented and some applications are studied. The numerical results obtained are compared with other existing methodologies and briefly discussed.
List of Symbols {B} m vector of the generalized state variables - {C} m vector of integration constants - [I] unit matrix - EI bending stiffness - A cross-sectional area - u adimensional thickness - l beam length - M,M bending moment - [N] m shape function ofm-th order - [N*] shape function atx 0 - P axial load - [R] i transfer matrix of thei-th element - T,T shear force - w transverse displacement - x adimensional independent variable - x 0 value ofx at the left of the element - {Y} vector of state variables - {Y*} imposed condition atx 0 - 0m Kronecker delta with the first pedix always set equal to zero - normalized eigenfrequency - normalized buckling load - mass density 相似文献
Sommario Gli autori hanno già proposto un metodo per studiare problemi strutturali [1] [2] [3], introducendo una nuova metodologia di discretizzazione, basata sull'impiego di elementi finiti di trasferimento, funzioni esplicite di un parametro, indicati come P-TFE. Tali elementi sono in grado di rappresentare, in similitudine alla funzione di trasferimento, il comportamento completo dell'elemento strutturale in esame, soggetto ad azioni dinamiche, aerodinamiche e termiche; sono parimenti in grado di produrre, in similitudine al metodo degli elementi finiti, un modello matematico discreto di un continuo.Scopo del presente lavoro è di applicare detta metodologia a problemi di ottimizzazione, in particolare alla ricerca del minimo peso per una trave che mantenga inalterate le sue caratteristiche di carico critico o le frequenze naturali di vibrazione.Vengono quindi presentati alcuni risultati numerici dei casi esaminati e confrontati con quelli ottenuti da altri autori con l'impiego di altre metodologie.
List of Symbols {B} m vector of the generalized state variables - {C} m vector of integration constants - [I] unit matrix - EI bending stiffness - A cross-sectional area - u adimensional thickness - l beam length - M,M bending moment - [N] m shape function ofm-th order - [N*] shape function atx 0 - P axial load - [R] i transfer matrix of thei-th element - T,T shear force - w transverse displacement - x adimensional independent variable - x 0 value ofx at the left of the element - {Y} vector of state variables - {Y*} imposed condition atx 0 - 0m Kronecker delta with the first pedix always set equal to zero - normalized eigenfrequency - normalized buckling load - mass density 相似文献
13.
特征线法在求解非线性液相吸附色谱模型中的应用 总被引:1,自引:0,他引:1
本文应用特征线法求解非线性液相吸附色谱分离过程模型,论述了特征线法的原理和步骤,讨论了时间步长和空间步长对模型数值解的影响,并用色谱分离甘露醇和山梨醇以及分离蔗糖和还原糖的实验进行验证,用特征线法计算的理论流出曲线与实验流出线吻合较好。本文还分折了模型中各个参数的灵敏度,结果表明:吸附等温方程Q=Ci*/(ai+biCi*)中参数ai比参数bi以及总传质系数ki有更高的灵敏度。 相似文献
14.
开展正常人体内元素含量的检测研究具有重要生物学意义,不仅可充实我国正常成年人脏器组织元素含量值的基础医学数据,为研究人体内微量元素与健康的关系提供科学依据、也为辐射防护领域内放射性核素的剂量估算提供重要参数。本文从以下五个方面进行了论述:()体内元素含量检测研究的目的、意义及其概况;(2)元素含量检测的重要性及其历史沿革;(3)元素的检测方法及质量控制;(4)人体内脏器组织元素含量的数值;(5)与国外资料相比较。本文着重介绍了我国100例正常成年人20个脏器组织(包括胃、小肠、大肠、心、肝、脾、肺、肾、… 相似文献
15.
新型醋酸乙烯酯/二乙烯苯共聚物的研究(Ⅱ)──醇解物的制备、结构及其性能吴向东,郭贤权,何炳林(南开大学高分子化学研究所,天津,300071)关键词皂化反应,醇解物,芳香族氨基酸,孔结构参数,吸附性能氨基酸失衡是指肝性脑病患者血液中芳香族氨基酸的浓度... 相似文献
16.
The pressure dependence of thelo-to phonons in InAs has been investigated by Raman scattering using the diamond anvil cell. Indium arsenide transforms, presumably
to the rock-salt structure at 70±1 kbar. The mode Grüneisen parameters for thelo-to phonons are γ
lo
=0.99±0.03, γ
to
=1.2±0.03 respectively. The effective charge,e*
T
, for InAs decreases slightly with pressure and this trend is in accordance with the behaviour of other III–V zinc blende
structured semiconductors: The structural phase transition is discussed in the light of theoretical calculations for phase
stability of III–V compounds, as well as recent high pressure x-ray diffraction studies. 相似文献
17.
鞠 《高等学校化学学报》1992,(11)
研究了温度对碳纤维微电极上伏安曲线的影响及温度与电极电位的关系,测定了电极反应的热力学参数.由电流与温度的关系测定了去极剂的扩散活化能E_(al)和D_o,利用微电极具有高速传质的特性,测定了常规电极上为可逆反应的电极反应标准速率常数(?),并通过(?)与温度的关系测定了电极反应的活化能. 相似文献
18.
Molecularly imprinted polymers (MIPs) are tailor-made polymers with high selectivity for the template molecule. This selectivity arises from the synthetic procedure followed to prepare the MIP. In this work, the influence of process parameters on the preparation of vinblastine (VLB) imprinted polymers was presented. In the procedure of polymerization, VLB (0.1 mmol) was used as the template molecule and a commonly used initiator, azobisisobutyronitrile (AIBN), was employed to initiate the reaction at 60 °C. The influence of the following parameters was investigated: the moles of functional monomer (MAA, 0.3-1.0 mmol), the moles of cross-linker (EDMA, 1.5-5.0 mmol) and the porogenic solvent (toluene or acetonitrile). A mathematical method of uniform design was applied to optimize these selected parameters in order to increase the selectivity of MIP for template molecule. The experimental data were analyzed to obtain the regression model and the optimal conditions were achieved by optimization with uniform design software. The MIP was synthesized under the optimal conditions that 1.0 mmol of MAA and 5.0 mmol of EDMA copolymerized in toluene in the presence of 0.1 mmol of VLB. After removal of the template molecule, the obtained MIP was then employed as the sorbents of solid-phase extraction (SPE) to separate VLB from Catharanthus roseus extract. The results showed that the polymer exhibited high affinity to the template molecule and could separate and enrich VLB from C. roseus extract effectively. The recovery of VLB on the optimal MIP was 89.00%, which agreed closely with the predicted recovery. Therefore it is possible to further improve the nature of the polymer by optimizing the polymerization parameters with the method of uniform design. 相似文献
19.
20.