全文获取类型
收费全文 | 467篇 |
免费 | 8篇 |
国内免费 | 17篇 |
专业分类
化学 | 255篇 |
晶体学 | 2篇 |
力学 | 32篇 |
综合类 | 1篇 |
数学 | 33篇 |
物理学 | 169篇 |
出版年
2024年 | 1篇 |
2023年 | 8篇 |
2022年 | 12篇 |
2021年 | 2篇 |
2020年 | 16篇 |
2019年 | 6篇 |
2018年 | 5篇 |
2017年 | 14篇 |
2016年 | 10篇 |
2015年 | 7篇 |
2014年 | 29篇 |
2013年 | 22篇 |
2012年 | 22篇 |
2011年 | 22篇 |
2010年 | 31篇 |
2009年 | 33篇 |
2008年 | 32篇 |
2007年 | 33篇 |
2006年 | 29篇 |
2005年 | 27篇 |
2004年 | 17篇 |
2003年 | 25篇 |
2002年 | 10篇 |
2001年 | 13篇 |
2000年 | 10篇 |
1999年 | 7篇 |
1998年 | 5篇 |
1997年 | 7篇 |
1996年 | 7篇 |
1994年 | 7篇 |
1993年 | 3篇 |
1992年 | 6篇 |
1991年 | 2篇 |
1990年 | 2篇 |
1989年 | 5篇 |
1988年 | 2篇 |
1985年 | 1篇 |
1984年 | 1篇 |
1981年 | 1篇 |
排序方式: 共有492条查询结果,搜索用时 250 毫秒
71.
Robert Dinnebier Hans‐Wolfram Lerner Li Ding Kenneth Shankland William I. F. David Peter W. Stephens Matthias Wagner 《无机化学与普通化学杂志》2002,628(1):310-314
The purple colored coordination polymer [1 Cu]n was obtained from 2,5‐bis(pyrazol‐1‐yl)‐1,4‐dihydroxybenzene and CuBr2 in aqueous ammonia. The crystal structure of [1 Cu]n was determined from high resolution X‐ray powder diffraction data using the method of simulated annealing. In the solid state, [1 Cu]n features largely independent linear chains, all of them being oriented parallel to the c‐axis of the crystal. The Cu ions are coordinated in a square‐planar fashion by two nitrogen atoms and two anionic oxygen donors. Magnetic susceptibility and magnetization measurements indicate the Cu ions in [1 Cu]n to be antiferromagnetically coupled with a coupling constant of about 20 K. 相似文献
72.
Iodine‐Catalyzed Production of Noble Metal‐Rich Intermetallics: The Crystal Structures of BePd2 and BePd3 The two Pd‐richest phases of the Be—Pd system are accessible 400 °C below the eutectic temperature within 48 h through an iodine‐catalyzed reaction of the metals. The crystal structures of BePd2 and BePd3 have been determined by means of X‐ray powder diffractometry. BePd3 is isotypic to BRe3. BePd2 adopts a MoSi2 type related structure. 相似文献
73.
《Arabian Journal of Chemistry》2019,12(8):2133-2140
Biologically active compounds with heteroaromatic ring system of cefotaxime sodium have been synthesized via aminomethylation reaction. The aminomethylation of cefotaxime sodium with various biologically potent sulphonamides/secondary amines was carried out and then characterized by elemental analysis and spectral studies – IR, 1H NMR, 13C NMR, Powder X-ray diffraction and Scanning Electron Microscopy. The compounds were screened for their antibacterial activity against various pathogenic bacteria at varying concentrations. The antibacterial activity of cefotaxime sodium derivatives was compared with parent sulphonamides. The toxicity of synthesized cefotaxime sodium derivatives was ascertained by LD50 test. 相似文献
74.
75.
Graham King Lora M. Wayman Patrick M. Woodward 《Journal of solid state chemistry》2009,182(6):1319-2406
We have prepared 14 new AA′BB′O6 perovskites which possess a rock salt ordering of the B-site cations and a layered ordering of the A-site cations. The compositions obtained are NaLnMnWO6 (Ln=Ce, Pr, Sm, Gd, Dy, and Ho) and NaLnMgWO6 (Ln=Ce, Pr, Sm, Eu, Gd, Tb, Dy, and Ho). The samples were structurally characterized by powder X-ray diffraction which has revealed metrically tetragonal lattice parameters for compositions with Ln=Ce, Pr and monoclinic symmetry for compositions with smaller lanthanides. Magnetic susceptibility vs. temperature measurements have found that all six NaLnMnWO6 compounds undergo antiferromagnetic ordering at temperatures between 10 and 13 K. Several compounds show signs of a second magnetic phase transition. One sample, NaPrMnWO6, appears to pass through at least three magnetic phase transitions within a narrow temperature range. All eight NaLnMgWO6 compounds remain paramagnetic down to 2 K revealing that the ordering of the Ln3+ cations in the NaLnMnWO6 compounds is induced by the ordering of the Mn2+ sub-lattice. 相似文献
76.
A number of new, layered nitride mixed halides have been synthesised in the quaternary phase systems Sr-N-Cl-Br and Sr-N-Br-I. The variation in structure with composition has been investigated by powder X-ray and powder neutron diffraction techniques and the structure of strontium nitride iodide, Sr2NI, has been determined for the first time (rhombohedral space group R-3m, , , Z=3). A continuous solid solution exists between Sr2NCl and Sr2NBr with intermediate compounds adopting the same anti-α-NaFeO2 structure (rhombohedral space group R-3m) as the ternary end members. A similar smooth and linear relationship between structure and composition is seen from Sr2NBr to Sr2NI and hence cubic close packing of metal-nitrogen layers is adopted regardless of halide, X (X′). While nitride and halide anions occupy distinct crystallographic sites, there is no ordering of the halides in the quaternary materials irrespective of stoichiometry or temperature (between 3 and 673 K). 相似文献
77.
Two novel noncentrosymmetric borates oxides, MBi2B2O7 or MBi2O(BO3)2 (MCa, Sr), have been synthesized by solid-state reactions in air at temperatures in the 600-700 °C range. Their crystal structures have been determined ab initio and refined using powder neutron diffraction data. CaBi2B2O7 crystallizes in the orthorhombic Pna21 space group with a=8.9371(5) Å, b=5.4771(3) Å, c=12.5912(7) Å, Z=4, Rwp=0.118, χ2=2.30. SrBi2B2O7 crystallizes in the hexagonal P63 space group with a=9.1404(4) Å, c=13.0808(6) Å, Z=6, Rwp=0.115, χ2=4.15. Large displacement parameters suggest the presence of disorder in SrBi2B2O7 as also revealed by diffuse 2×a superstructure reflections in electron diffraction patterns. Both structures are built of identical (001) neutral layers of corner-sharing BO3 triangles and MO6 trigonal prisms forming six-membered rings in which Bi2O groups are located. Adjacent layers are stacked in a staggered configuration and connected through weak Bi-O bonds. A moderate efficiency for second harmonic generation (SHG) has been measured for a powder sample of CaBi2B2O7 (deff=2deff(KDP)). 相似文献
79.
《Ultrasonics sonochemistry》2014,21(5):1658-1665
The effect of shear on the solubilization of a range of dairy powders was investigated. The rate of solubilization of low solubility milk protein concentrate and micellar casein powders was examined during ultrasonication, high pressure homogenization and high-shear rotor–stator mixing and compared to low-shear overhead stirring. The high shear techniques were able to greatly accelerate the solubilization of these powders by physically breaking apart the powder agglomerates and accelerating the release of individual casein micelles into solution. This was achieved without affecting the structure of the solubilized proteins. The effect of high shear on the re-establishment of the mineral balance between the casein micelles and the serum was examined by monitoring the pH of the reconstituted skim milk powder after prior exposure to ultrasonication. Only minor differences in the re-equilibration of the pH were observed after sonication for up to 3 min, suggesting that the localized high shear forces exerted by sonication did not significantly affect the mass transfer of minerals from within the casein micelles. 相似文献
80.