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731.
Jennifer A. Irvin Charles J. Neef Kevin M. Kane Patrick E. Cassidy Gordon Tullos Anne K. St. Clair 《Journal of polymer science. Part A, Polymer chemistry》1992,30(8):1675-1679
A series of fluorinated aromatic polyethers was synthesized via aromatic nucleophilic substitution of highly fluorinated aromatics (1,2,4,5-tetrafluorobenzene, hexafluorobenzene, and decafluorobiphenyl) with bisphenol AF or bisphenol A. Polymerization with 1,2,4,5-tetrafluorobenzene was not observed, and polymerization of hexafluorobenzene with bisphenol proceeded only if the potassium carbonate–bisphenol ratio was carefully controlled. The polymer condensed from decafluorobiphenyl and bisphenol AF was prepared in 77% yield with an inherent viscosity of 1.01 dL/g. The polymer prepared from the condensation of decafluorobiphenyl with bisphenol A was obtained in 48% yield with an inherent viscosity of 0.28 dL/g. These polymers were very soluble in common organic solvents, formed clear, colorless films, and were thermally stable (> 450°C by TGA). The fully fluorinated polymer exhibited low water uptake (0.3%) and dielectric constant (2.17). © 1992 John Wiley & Sons, Inc. 相似文献
732.
Guided submillimeter radiation (=118.8 m) has been focussed by inserting a cylinder lens into the freely propagating beam in front of the incoupling prism. The beam profile at the focal spot has been determined experimentally, the results agree with theoretical predictions. The optical quality of the focus is good. 相似文献
733.
以硝酸锂、偏钒酸铵、硝酸钙、硝酸镁、正硅酸乙酯为原料,采用溶胶-凝胶法低温合成纳米CaMgSi2O6微波介质陶瓷粉体,研究了不同粒径粉体的烧结行为与微波介电性能。结果表明,通过在钙镁硅溶胶中引入锂钒烧结助剂可大大降低陶瓷粉体的晶相合成温度,干凝胶在750 ℃煅烧后可获得主晶相为CaMgSi2O6、分散性良好、粒径为78~98 nm的陶瓷粉体,可满足微型片式元器件用超薄陶瓷介质层的制备要求;该粉体在890 ℃烧结后获得致密结构的陶瓷,具有良好的微波介电性能:介电常数为7.68,品质因数为24 542 GHz,频率温度系数为-57.25×10-6 ℃-1。 相似文献
734.
D. W. Davidson J. E. D. Davies S. R. Gough D. Leaist J. A. Ripmeester 《Journal of inclusion phenomena and macrocyclic chemistry》1990,8(1-2):187-197
Dielectric measurements of SO2 quinol clathrates show that the reorientation of encaged SO2 molecules is very rapid and depends greatly on the degree of cage occupancy. For a-quinol sample of cage occupancy = 0.57, the reorientation rate was 1 MHz at 6 K, with a reorientational activation energy of 673 J/mol. For a sample identified by13C NMR as-quinol, and for a-quinol sample with most cages filled with Xe, SO2 reorientation rates are even greater, with activation energies of only some tens of J/mol. The low temperature dielectric studies show that some ethanol may be enclathrated in-quinol recrystallized from this solvent. The13C NMR spectra confirm the X-ray results that the lattice becomes distorted with increased SO2 content.Dedicated to Dr D. W. Davidson in honor of his great contributions to the sciences of inclusion phenomena. 相似文献
735.
Bollinger Jean-Claude Yvernault Germaine Yvernault Théophile 《Journal of solution chemistry》1978,7(4):317-324
Densities and viscosities have been determined, from 25 to 45°C, as well as the refractive indices and dielectric constants at 25°C, for mixtures of triethylphosphate (TEP) and hexamethylphosphoric triamide (HMPT), in the complete mole fraction interval. As far as steric considerations are concerned, comparison has been made with the properties of the two intermediate organophosphorus compounds, ethoxytetramethylphosphorodiamide (EtO)(Me2N)2PO and diethoxydimethylphosphoramide (EtO)2(Me2N)PO. 相似文献
736.
The dielectric properties of the system water/AOT/dodecane are studied as a function of volume fraction of the dispersed phase and molar ration (water/surfactant). Data shows that the spherical model is valid only at lown values or low values. At high concentrations of dispersed phase, one has to consider micellar aggregation or deformation. 相似文献
737.
This paper deals with the shape dependence of the dielectric susceptibility (equivalently defined, in a canonical ensemble, by the mean square fluctuation of the electric polarization or by the second moment of the charge-charge correlation function) of classical Coulomb systems. The concept of partial second moment is introduced with the aim of analyzing the contributions to the total susceptibility of pairs of particles of increasing separation. For a diskshaped one-component plasma with coupling parameter =2 it is shown, numerically and algebraically for small and large systems, that (1) the correlation function of two particles close to the edge of the disk decays as the inverse of the square of their distance, and (2) the susceptibility is made up of a bulk contribution, which saturates rapidly toward the Stillinger-Lovett value, and of a surface contribution, which varies on the scale of the disk diameter and is described by a new law called the arc sine law. It is also shown that electrostatics and statistical mechanics with shape-dependent thermodynamic limits are consistent for the same model in a strip geometry, whereas the Stillinger-Lovett sum rule is verified for a boundary-free geometry such as the surface of a sphere. Some results of extensive computer simulations of one- and two-component plasmas in circular and elliptic geometries are shown. Anisotropy effects on the susceptibilities are clearly demonstrated and the arc sine law for a circular plasma is well confirmed. 相似文献
738.
Jean-François Côté Dany Brouillette Jacques E. Desnoyers Jean-François Rouleau Jean-Marie St-Arnaud Gérald Perron 《Journal of solution chemistry》1996,25(12):1163-1173
The dielectric constants of 1,2-dimethoxyethane, acetonitrile, -butyrolactone, and propylene carbonate were determined from capacitance measurements extrapolated to infinite frequency; ln are reported as a function of pressure up to 80 MPa at 15, 25, 35, 45°C and as a function of temperature in the range 10 to 50°C at 0.10133 MPa. The variation of ln with temperature or pressure can be expressed by a second order polynomial expression. The isothermal compressibilities of the solvents were determined at 25°C from sound velocities, densities, and heat capacities. A simple correlation can be established between ln /P and for most aprotic solvent. 相似文献
739.
Soybean-Phosphatidylcholine Phospholipon® 100 has a stable gel conformation in the as-prepared state. We observed a main phase transition (chain melting) above 30 °C in the first heating run. This transition is marked 1. by a change of the lamellar repeat distance recorded by small angle X-ray diffraction, and 2. by an increase of the imaginary part of the dielectric constant. After the first heating up to + 90 °C the chains melt in a broad temperature range between –60 °C and +90 °C. The high stability of chain conformation in the temperature range –60 °C to +30 °C of the as-prepared state is due to the low water content of the material. 相似文献
740.
A. E. Galashev V. N. Chukanov A. N. Novruzov O. A. Novruzova 《Russian Journal of Electrochemistry》2007,43(2):136-145
Molecular dynamics method is used for studying complex permittivity ɛ and the stability of individual water clusters as a
function of the number of involved molecules (7 ≤ i ≤ 20) and also the corresponding characteristics of water aggregates with a captured CO2 or CH4 molecule. Absorption of the latter molecules leads to considerable changes in dielectric properties and stability of clusters.
In particular, upon the addition of a CO2 molecule to a water cluster, the oscillation parameters of the real and imaginary parts of the permittivity change. Capture
of a CH4 molecule by a water aggregate changes the ɛ(ω) dependence from the relaxation to resonance type. For i ≥ 15, the thermal stability of individual water clusters can be lower than that of aggregates CO2(H2O)
i
and CH4(H2O)
i
. The mechanical stability of (H2O)
i ≥ 13 clusters can exceed that of heteroclusters under consideration. Clusters (H2O)
i
and CO2(H2O)
i
have approximately the same dielectric stability, whereas aggregates CH4(H2O)
i
exhibit lower stability with respect to electric perturbations.
Original Russian Text ? A.E. Galashev, V.N. Chukanov, A.N. Novruzov, O.A. Novruzova, 2007, published in Elektrokhimiya, 2007,
Vol. 43, No. 2, pp. 143–153. 相似文献