全文获取类型
收费全文 | 12954篇 |
免费 | 1563篇 |
国内免费 | 1126篇 |
专业分类
化学 | 4479篇 |
晶体学 | 138篇 |
力学 | 1821篇 |
综合类 | 123篇 |
数学 | 3690篇 |
物理学 | 5392篇 |
出版年
2024年 | 42篇 |
2023年 | 171篇 |
2022年 | 426篇 |
2021年 | 493篇 |
2020年 | 625篇 |
2019年 | 439篇 |
2018年 | 380篇 |
2017年 | 404篇 |
2016年 | 516篇 |
2015年 | 428篇 |
2014年 | 538篇 |
2013年 | 1030篇 |
2012年 | 520篇 |
2011年 | 617篇 |
2010年 | 521篇 |
2009年 | 776篇 |
2008年 | 748篇 |
2007年 | 785篇 |
2006年 | 747篇 |
2005年 | 557篇 |
2004年 | 538篇 |
2003年 | 533篇 |
2002年 | 505篇 |
2001年 | 426篇 |
2000年 | 466篇 |
1999年 | 368篇 |
1998年 | 392篇 |
1997年 | 213篇 |
1996年 | 187篇 |
1995年 | 185篇 |
1994年 | 115篇 |
1993年 | 111篇 |
1992年 | 111篇 |
1991年 | 84篇 |
1990年 | 71篇 |
1989年 | 57篇 |
1988年 | 68篇 |
1987年 | 58篇 |
1986年 | 48篇 |
1985年 | 85篇 |
1984年 | 65篇 |
1983年 | 28篇 |
1982年 | 43篇 |
1981年 | 28篇 |
1980年 | 17篇 |
1979年 | 21篇 |
1978年 | 9篇 |
1977年 | 15篇 |
1976年 | 9篇 |
1973年 | 7篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
991.
The growth of ultrathin Fe films of various coverages on Ge(1 1 1) at room temperature using molecular beam epitaxy (MBE) was studied via X-ray photoelectron diffraction (XPD or XPED) together with low energy electron diffraction (LEED) and X-ray photoelectron spectroscopy (XPS). All experimentally observed XPD patterns suggested local order structures of the Fe layers for all thicknesses studied. The short-range order of the resulting structures was found to be enhanced for thinner layers whereas the long-range order was gradually lost with increasing Fe thicknesses. At a very low coverage of 0.8 Å Fe and Ge tend to react to the partly ordered structure in which Fe atoms were located in local environments similar to those for higher Fe coverages. Comparison of theoretical and experimental XPD patterns, along with XPS results, showed that intermixing between Fe and Ge occurred during the pseudomorphic growth with a stacking fault near the interface for all Fe coverages under study. Nevertheless, small percentage of domains without the stacking fault was also found to coexist with those with the stacking fault by performing a quantitative analysis of a reliability factor R of the Fe2p pattern for 5.4 Å. The orientation changes of the Ge2p and Ge3d XPD patterns with Fe thickness were unambiguously explained in terms of their different dependencies on the overlayer thickness due to the different inelastic mean free path lengths used in the simulations. Also, Fe got increasingly enriched in the grown layers with increased Fe coverage. The resulting structures and intermixing are discussed in detail. 相似文献
992.
Calculations of the kinetic energy distributions of electrons ejected from plane metal surfaces by Auger neutralization of slow monoatomic ions are reported. A many body theory is used that includes both the band structure of the target material and the Fermi singular response of metal electrons (to the sudden neutralization of the projectile). Application is made to experiments of electron emission from polycrystalline Al by Ar+-ions, at varying incident energies and angles. Adjustment of the broadening parameters of the distribution of shake-up electrons leads to excellent agreement between the theory and the measurements. 相似文献
993.
Uncertainty evaluation of the spectral UV irradiance evaluated by using the UVSPEC radiative transfer model 总被引:1,自引:0,他引:1
The radiative transfer models allow calculating the spectral UV irradiance from some set of measured input quantities linked with the surface reflectivity, the solar zenith angle, the ozone column and the characteristics of clouds and aerosols. The spectral irradiance yielded by a model is influenced by errors in the measurement of the input quantities. In this paper, the influences of these errors are characterized and compared with other systematic effects through an uncertainty analysis. We evaluated the uncertainty of the spectral UV irradiance rendered by the UVSPEC model, under cloudless sky conditions. In order to express the uncertainty of the output quantities (the global, direct and diffuse irradiances) in terms of the standard uncertainties of the input quantities, we used a Monte Carlo-based uncertainty propagation technique. We found that the uncertainty of the irradiance in the UV-B part of the spectrum was strongly influenced by the uncertainty attributed to the ozone column datum. Moreover, the uncertainities associated with the aerosol parameters accounted for most of the UV-A global irradiance uncertainty; the latter increased from about 4% under low aerosol conditions, up to about 14% in case of polluted air. We conclude that the UV irradiance evaluation through radiative transfer models requires paying special attention to the assessment of the aerosols properties. 相似文献
994.
We present a class of examples of nearest-neighbour, bounded-spin models, in which the low-temperature Gibbs measures do not
converge as the temperature is lowered to zero, in any dimension. 相似文献
995.
利用自恰tight-binding 理论,对由phenalenyl分子构成的全对称三电极纳米单分子器件的电子传导特性进行了理论研究. 通过改变电极与分子界面上的耦合,得出了分子与原子线电极间耦合强度变化对电子传输的影响. 结果显示电子通过phenalenyl分子器件的概率随着分子与电极的耦合强度变弱而减小. 当耦合强度变大时,不仅电子通过phenalenyl分子器件的概率变大,而且在较宽的能带内电子都可以通过phenalenyl分子. 所得结果还揭示出在特定的能区,对称三电极phenalenyl分子可以构成一个无源正负能量开关器件的新特性. 相似文献
996.
We describe and demonstrate both our newest projection method (fully implicit) for the incompressible Navier-Stokes equations via the finite element method and our newest turbulence model - a somewhat sophisticated nonlinear (cubic) eddy viscosity model that does not employ wall functions or normal distances to walls - the combination providing a method and a model that is each applicable in arbitrary geometry. We demonstrate both via a flow simulation past an automobile-like body at a Reynolds number of 4.3 million. 相似文献
997.
John S. Lomas 《Magnetic resonance in chemistry : MRC》2013,51(1):32-41
The proton NMR spectra of several 1,2‐diols in benzene have been analysed so as to associate each magnetically nonequivalent proton with its chemical shift. The shifts and coupling constants of the OH and methylene protons of ethane‐1,2‐diol have been determined in a wide range of solvents. The conformer distribution and the proton NMR shifts of these 1,2‐diols in benzene have been computed on the basis of density functional theory. The solvent is included using the integral–equation–formalism polarizable continuum model implemented in Gaussian 09. Relative Gibbs energies for all stable conformers are calculated at the Perdew, Burke and Enzerhof (PBE)0/6‐311 + G(d,p) level, and shifts are calculated using the gauge‐including atomic orbital method with the PBE0/6‐311 + G(d,p) geometry but using the cc‐pVTZ basis set. Previous calculations on ethane‐1,2‐diol and propane‐1,2‐diol have been corrected and extended. New calculations on tert‐butylethane‐1,2‐diol, phenylethane‐1,2‐diol, butane‐2,3‐diols (dl and meso) and cyclohexane‐1,2‐diols (cis and trans) are presented. Overall, the computed NMR shifts are in good agreement with experimental values for the OH protons but remain systematically high for CH protons. Some results based on the Gaussian 03 solvation model are included for comparison. Copyright © 2012 John Wiley & Sons, Ltd. 相似文献
998.
Michael Danquah Tomoko Fujiwara Ram I. Mahato 《Journal of polymer science. Part A, Polymer chemistry》2013,51(2):347-362
Our objective was to synthesize and evaluate lactic acid‐ and carbonate‐based biodegradable core‐ and core‐corona crosslinkable copolymers for anticancer drug delivery. Methoxy poly(ethylene glycol)‐b‐poly(carbonate‐co‐lactide‐co‐5‐methyl‐5‐allyloxycarbonyl‐1,3‐dioxane‐2‐one) [mPEG‐b‐P(CB‐co‐LA‐co‐MAC)] and methoxy poly(ethylene glycol)‐b‐poly(acryloyl carbonate)‐b‐poly(carbonate‐co‐lactide) [mPEG‐b‐PMAC‐b‐P(CB‐co‐LA)] copolymers were synthesized by ring‐opening polymerization of LA, CB, and MAC using mPEG as an macroinitiator and 1,8‐diazabicycloundec‐7‐ene as a catalyst. These amphiphilic copolymers which exhibited low polydispersity and critical micelle concentration values (0.8–1 mg/L) were used to prepare micelles with or without drug and stabilized by crosslinking via radical polymerization of double bonds introduced in the core and interface to improve stability. mPEG114‐b‐P(CB8‐co‐LA35‐co‐MAC2.5) had a higher drug encapsulation efficiency (78.72% ± 0.15%) compared to mPEG114‐b‐PMAC2.5‐b‐P(CB9‐co‐LA39) (20.29% ± 0.11%).1H NMR and IR spectroscopy confirmed successful crosslinking (~70%) while light scattering and transmission electron microscopy were used to determine micelle size and morphology. Crosslinked micelles demonstrated enhanced stability against extensive dilution with aqueous solvents and in the presence of physiological simulating serum concentration. Furthermore, bicalutamide‐loaded crosslinked micelles were more potent compared to non‐crosslinked micelles in inhibiting LNCaP cell proliferation irrespective of polymer type. Finally, these results suggest crosslinked micelles to be promising drug delivery vehicles for chemotherapy. © 2012 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2013 相似文献
999.
Holding costs are traditionally determined from the investment in physical stock during a cycle. An alternative approach instead derives holding costs from Net Present Value (NPV) functions. It is known that applying both frameworks to the same system can lead to different holding cost valuations, but little explanation has been offered. By introducing the Anchor Point in a model, this paper shows, for four different systems, that traditional holding cost models (implicitly) assume pull conditions, while current NPV approaches model push conditions. This explains in part the differences between the methods. It is shown that the Anchor Point concept allows the construction of NPV models under pull conditions, giving results in better correspondence with traditional models. The traditional framework is restricted to pull conditions and important considerations could be easily overlooked, leading to wrong valuations of holding costs. NPV seems superior as such considerations are automatically incorporated. The application to multi-echelon inventory systems provides interesting insights on the roles of echelon stocks and lead-times, and offers potential for future research. 相似文献
1000.
Ugur Gven 《Acta Mechanica Solida Sinica》2011,24(6):506-509
In this work a bi-material beam exhibiting partly bilinear behaviour under a uniform temperature change is analyzed. The essence of solution is based on the approach of Timoshenko’s mechanics of materials. The main aim of the present analysis is to understand the effect of the bilinear behaviour on the peeling moment. This theoretical mechanics model mentioned here can give us useful insights to improve the resistance against the delamination. 相似文献