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131.
利用大角重位点阵概念建立了AZ91镁合金基体(α相)和镁[0001]对称倾斜晶界原子结构模型,应用实空间的连分数方法计算了体系的结构能,环境敏感镶嵌能以及相互作用能.结果发现,在镁合金基体中,Al和稀土形成团簇时比较稳定,Al,Bi或Sb与稀土形成团簇时不稳定.Bi或Sb和稀土元素同时存在于AZ91镁合金中时,一方面Bi或Sb将可与RE结合形成RE2Bi(RE2Sb)或RE-Bi(RE-Sb)化合物弥散分布于晶界,另一方面镁合金基体中会形成Al11
关键词:
电子理论
晶界偏聚
合金元素
高温性能 相似文献
132.
Zubair Ahmad Tianyu Ma Shan TaoMi Yan 《Journal of magnetism and magnetic materials》2012,324(8):1534-1538
The Fe63B23Nd7Y3Nb3Cr1 nanocomposite magnets in the form of sheets have been prepared by copper mold casting technique. The phase evolution, crystal structure, microstructural and magnetic properties have been investigated in the as-cast and annealed states. The as-cast sheets show magnetically soft behaviors which become magnetically hard by thermal annealing. The optimal annealed microstructure was composed of nanosize soft magnetic α-Fe (19-29 nm) and hard magnetic Nd2Fe14B (45-55 nm) grains. The best hard magnetic properties such as intrinsic coercivity, jHc of 1119 kA/m, remanence, Br of 0.44 T, magnetic induction to saturation magnetization ratio, Mr/Ms=0.61 and maximum energy product, (BH)max of 55 kJ/m3 was obtained after annealing at 680 °C for 15 min. The annealing treatment above 680 °C results in non-ideal phase grains growth, which degrade the magnetic properties. 相似文献
133.
Formation of PdNiZn thin film at oil‐water interface: XPS study and application as Suzuki‐Miyaura catalyst 下载免费PDF全文
Nanosheet of PdNiZn and nanosphere of PdNiZn/reduced‐graphene oxide (RGO) with sub‐3 nm spheres have been successfully synthesized through a facile oil‐water interfacial strategy. The morphology and composition of the films were determined by X‐ray diffraction (XRD), X‐ray photoelectron spectroscopy (XPS), transmission electron microscopy (TEM), scanning electron microscopy (SEM), energy dispersive analysis of X‐ray (EDAX) and elemental mapping. In the present study, we have developed a method to minimize the usage of precious Pd element. Due to the special structure and intermetallic synergies, the PdNiZn and PdNiZn/RGO nanoalloys exhibited enhanced catalytic activity and durability relative to Pd nanoparticles in Suzuki‐Miyaura C‐C cross‐coupling reaction. Compared to classical cross‐coupling reactions, this method has the advantages of a green solvent, short reaction times, low catalyst loading, high yields and reusability of the catalysts. 相似文献
134.
135.
W.O. Rosa L.G. Vivas K.R. Pirota A. Asenjo M. Vázquez 《Journal of magnetism and magnetic materials》2012
The size effects on magnetic properties of nanowires arrays were studied varying the nanowires diameter and maintaining the same periodicity among them, for two different nominal compositions of Co and Ni in the alloy form. The competition among magnetocrystalline and shape anisotropies changes drastically from smallest to biggest diameters altering the easy axis direction. In the case of 75% of Co in alloy, experimental values of the effective anisotropy constant (Keff) vary from positive to negative depending on the diameter, which means a reversal of the easy axis direction. For 50% of Co the shape anisotropy dominates over the magnetocrystalline for all studied diameters. 相似文献
136.
The influence of initial heat treatment on anomalous Cr precipitation within high temperature solubility region of the Fe–9Cr alloy has been investigated using positron lifetime studies. Air-quenched samples with pre-existing dislocations exhibited a distinct annealing stage in positron lifetime between 800 and 1100?K corresponding to Cr-precipitation. During this stage, Transmission Electron Microscopy showed fine precipitates of average size 4 nm, dispersed throughout the sample and from Energy-dispersive X-ray spectroscopy (EDS) analysis they are found to be Cr-enriched. The presence of dislocations is found to be responsible for Cr precipitation. 相似文献
137.
Role of compositional changes on thermal,magnetic,and mechanical properties of Fe-P-C-based amorphous alloys 下载免费PDF全文
Indah Raya Supat Chupradit Mustafa M Kadhim Mustafa Z Mahmoud Abduladheem Turki Jalil Aravindhan Surendar Sukaina Tuama Ghafel Yasser Fakri Mustafa Alexander N Bochvar 《中国物理 B》2022,31(1):16401-016401
This work aimed to tune the comprehensive properties of Fe-P-C-based amorphous system through investigating the role of microalloying process on the crystallization behavior,glass forming ability(GFA),soft magnetic features,and mechanical properties.Considering minor addition of elements into the system,it was found that the simultaneous microalloying of Ni and Co leads to the highest GFA,which was due to the optimization of compositional heterogeneity and creation of near-eutectic composition.Moreover,the FeCoNiCuPC amorphous alloy exhibited the best anelastic/viscoplastic behavior under the nanoindentation test,which was owing to the intensified structural fluctuations in the system.However,the improved plasticity by the extra Cu addition comes at the expense of magnetic properties,so that the saturation magnetization of this alloying system is significantly decreased compared to the FeCoPC amorphous alloy with the highest soft magnetic properties.In total,the results indicated that a combination of added elemental constitutes,i.e.,Fe69Co5Ni5Cu1P13C7 composition,provides an optimized state for the comprehensive properties in the alloying system. 相似文献
138.
《Physics letters. A》2020,384(20):126418
In this study, Cu-20wt.Sn alloy was produced by powder metallurgy (PM) method by using high purity element powders. The phases in the microstructure of the produced alloy were determined by XRD study. The phase transformation behaviour of the alloy was investigated by DSC and modelling method. Moreover, the Cu-20wt.Sn alloy system was modelled with molecular dynamics (MD) simulation based on modified Embedded Atom Method (MEAM). The radial distribution function (RDF) was calculated to determine the structural properties of system during the phase transformations. The experimental results showed that the transformation () → () occur at temperature above 500°C. The simulation results showed that the phase transformation occurs at 550°C temperature. Our simulation results are in reasonable agreement with the experimental data. 相似文献
139.
ABSTRACT The effect of transition elements, specifically Mn, Cr, V, and Mo, on dispersoid formation and mechanical properties in 6082 aluminum alloy was studied. The elevated-temperature mechanical properties were evaluated based on the compressive yield strength and creep resistance. The results indicated that the addition of Mn to the 6082 alloy resulted in the formation of a large number of the thermally stable α-Al(MnFe)Si dispersoids, thereby significantly improving the elevated-temperature mechanical properties of the alloy. Subsequent additions of Cr, V, and Mo increased the amount of Mn-bearing intermetallic phases, which decreased the supersaturation levels of Mn and Si in the α-Al, and consequently decreased the volume fraction of the dispersoids. The alloys containing Cr, V, and Mo exhibited similar yield strengths at 300°C and higher yield strengths at room temperature compared to the alloy containing only Mn. The size effect of the smaller dispersoids containing Cr, V, and Mo together with the solid-solution hardening of these elements could balance out the strength decrease resulting from the decreased volume fraction of the dispersoids. The additions of Cr, V, and Mo significantly increased the creep resistance of the Mn-containing 6082 alloy. Vanadium induced the highest creep resistance followed by Cr and Mo. Solute atoms of these elements with low diffusivity in the aluminum matrix contributed significantly to increasing the creep resistance at 300°C. 相似文献
140.
Dr. Guang-Lan Li Bei-Bei Yang Xiao-Cun Xu Shuo Cao Prof. Yantao Shi Dr. Yang Yan Dr. Xuedan Song Prof. Ce Hao 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(13):2890-2896
The development of cost-effective and durable oxygen electrocatalysts remains highly critical but challenging for energy conversion and storage devices. Herein, a novel FeNi alloy nanoparticle core encapsulated in carbon shells supported on a N-enriched graphene-like carbon matrix (denoted as FeNi@C/NG) was constructed by facile pyrolyzing the mixture of metal salts, glucose, and dicyandiamide. The in situ pyrolysis of dicyandiamide in the presence of glucose plays a significant effect on the fabrication of the porous FeNi@C/NG with a high content of doped N and large specific surface area. The optimized FeNi@C/NG catalyst displays not only a superior catalytic performance for the oxygen reduction reaction (ORR, with an onset potential of 1.0 V and half-wave potential of 0.84 V) and oxygen evolution reaction (OER, the potential at 10 mA cm−2 is 1.66 V) simultaneously in alkaline, but also outstanding long-term cycling durability. The excellent bifunctional ORR/OER electrocatalytic performance is ascribed to the synergism of the carbon shell and FeNi alloy core together with the high-content of nitrogen doped on the large specific surface area graphene-like carbon. 相似文献