Phasenbeziehungen und Natriumionenleitung im quasi-binären System Na2SiF6/Na3AlF6

Phase Relations and Sodium Ion Conductivity within the Quasi-binary System Na₂SiF₆/Na₂AIF₆ . The phase diagram of the Na₂SiF₆/Na₃AlF₆ system has been determined by means of x-ray powder diffraction, thermal analysis and conductivity measurements in the sub-solidus region. Na₃AlF₆ accomodates up to 73 mol.-% Na₂SiF₆ maintaining the crystal structure type. The sodium ion conductivity increases by about five orders of magnitude upon doping Na₃AlF₆ with Na₂SiF₆.     

A possible counterexample to well posedness of entropy solutions and to Godunov scheme convergence

A particular case of initial data for the two-dimensional Euler equations is studied numerically. The results show that the Godunov method does not always converge to the physical solution, at least not on feasible grids. Moreover, they suggest that entropy solutions (in the weak entropy inequality sense) are not well posed.

     

Roles of SiH4 and SiF4 in growth and structural changes of poly-Si films

The structural properties of polycrystalline silicon films, prepared by plasma enhanced chemical vapor deposition system, with different flow rates of SiH₄/SiF₄ mixtures at 300 °C were investigated. This study indicates that the low hydrogen coverage on the growing surface, under optimum fluorine radicals, will be leaded to an improvement of crystallized area as compared with case of high hydrogen coverage surface. Moreover, the studies of the role of SiH₄ and SiF₄ radicals show that the SiH₄ radicals are important in the nucleation and growth of grains. However, SiF₄ radicals are effective in the structural change of grain boundaries regions and by this way, in the present system, establish the growth of grains under the dominant 〈1 1 0〉 direction. The stress investigation indicates that addition of high flow rate of SiF₄ in amorphous film, results in the nearly stress free films. Finally, we found that the changes in g-value reflect the changes in the intrinsic compressive and tensile stress in the both polycrystalline and amorphous silicon films.     

Colloidal ZnO nanostructures and functional coatings: A survey

The past research work devoted to ZnO nanocolloidal sol-gel route is reviewed. It highlights the cluster chemistry of alcoholic ZnAc₂ solutions and the results of ZnO colloid growth investigations performed worldwide. Moreover, the role of doping and co-doping in the processing of functional ZnO coatings is discussed. The possibilities of tuning the optical properties are also reported with a particular attention to luminescence. The last part of this paper deals with electrical and photoelectrochemical properties of ZnO nanocrystals and their aggregates. This contribution is dedicated to the 80th birthday of Prof. Arnim Henglein from the Hahn-Meitner-Institut in Berlin and to the memory of Prof. Jacques Mugnier from the Université Claude-Bernard Lyon 1 in France.     

Two-component model of solar plages

By use of the 2-m Mcmath-Pierce telescope at Kitt Peak, the high-quality spectra of a plage with moderate brightness near the center of solar disk were obtained. The data include seven spectral lines, which are Hα, Hβ, CaII H and K lines and the infrared triplet. With the consideration of fine structures of solar plages, a two-component atmospheric model is constructed by keeping the cool component to be the quiet atmosphere. Three cases of the hot component are given for different filling factors where the temperature and density distribution are adjusted in order to reproduce the seven observed spectral profiles. We also briefly discuss the influence of the column density at the base of the corona, m0, and the macro-turbulent velocity on the required filling factor and computed profiles. The two-component model is compared with precious one-component semi-empirical models. The limitation of the model is pointed out and further improvement is indicated.     

基于校园网的实验管理系统的设计

主要讨论了应用实验室管理系统的必要性,并从用户需求分析、系统总体设计、功能模块的设计等方面对B/S实验室管理系统的开发进行了详细的阐述。     

High-throughput screening of fuel cell electrocatalysts

The drawbacks of our earlier report of preparing fuel cell catalyst arrays by borohydride reduction of inkjet prepared arrays of metal salts are discussed along with the need for inclusion of state-of-the-art metrics in all array screening. An alternative method for screening of hydrogen/air cathode catalysts, direct methanol fuel cell (DMFC) anode catalysts, and catalyst loading studies is provided. State-of-the-art Johnson Matthey catalysts were used in control experiments to demonstrate the utility of the array fuel cell for high throughput screening of fuel cell catalysts in the 3-4 mg/cm² range. This report lays out hard learned rules for high throughput screening and demonstrates that the array fuel cell can be used for very precise screening of libraries of membrane electrode assembly (MEA) components without the pitfalls discussed in the introduction.     

An investigation on planar dielectric light collectors for illumination and solar energy applications

In this paper the performances of inhomogeneous dielectric slabs as solar light collectors for both illumination and solar energy applications are analysed.