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971.
972.
973.
Frequency domain (FD) fluorescence lifetime data was collected for a series of 20 crude petroleum oils using a 405 nm excitation
source and over a spectral range of ~426 to ~650 nm. Average fluorescence lifetimes were calculated using three different
models: discrete multi-exponential, Gaussian distribution, and Lorentzian distribution. Fitting the data to extract accurate
average lifetimes using the various models proved easier and less time consuming for the FD data than with Time Correlated
Single Photon Counting (TCSPC) methods however the analysis of confidence intervals to the computed average lifetimes proved
cumbersome for both methods. The uncertainty in the average lifetime was generally larger for the discrete lifetime multi-exponential
model when compared to the distribution-based models. For the lifetime distributions, the data from the light crude oils with
long lifetimes generally fit to a single decay term. Heavier oils with shorter lifetimes required multiple decay terms. The
actual value for the average lifetime is more dependant on the specific fitting model employed than the data acquisition method
used. Correlations between average fluorescence lifetimes and physical and chemical parameters of the crude oils were made
with a view to developing a quantitative model for predicting the gross chemical composition of crude oils. It was found that
there was no significant benefit gained by using FD over TCSPC other than more rapid data analysis in the FD case. For the
FD data the Gaussian distribution model for fluorescence lifetime gave the best correlations with chemical composition allowing
a qualitative correlation to some bulk oil parameters.
相似文献
Alan G. RyderEmail: |
974.
Sakhaii P Haase B Bermel W 《Journal of magnetic resonance (San Diego, Calif. : 1997)》2008,191(2):291-303
A new scheme for obtaining HSQC spectra with improved resolution or in a shorter time called SHARC (Shaped Arrayed data aCquisition protocol) is proposed, which uses region selective RF pulses and allows the sweep width to be adjusted individually for each region. It thus bypasses the problems with the Nyquist theorem associated with other method suggested for this purpose. Assignment of the cross-peaks to their respective region is achieved by manipulating the phases of the RF pulses and/or their frequencies. SHARC NMR can be applied without any previous knowledge of the chemical shift distribution, but can be further optimized on the basis of a quick overview spectrum. 相似文献
975.
Froncisz W Camenisch TG Ratke JJ Anderson JR Subczynski WK Strangeway RA Sidabras JW Hyde JS 《Journal of magnetic resonance (San Diego, Calif. : 1997)》2008,193(2):297-304
A reference arm W-band (94 GHz) microwave bridge with two sample-irradiation arms for saturation recovery (SR) EPR and ELDOR experiments is described. Frequencies in each arm are derived from 2 GHz synthesizers that have a common time-base and are translated to 94 GHz in steps of 33 and 59 GHz. Intended applications are to nitroxide radical spin labels and spin probes in the liquid phase. An enabling technology is the use of a W-band loop-gap resonator (LGR) [J.W. Sidabras, R.R. Mett, W. Froncisz, T.G. Camenisch, J.R. Anderson, J.S. Hyde, Multipurpose EPR loop-gap resonator and cylindrical TE011 cavity for aqueous samples at 94 GHz, Rev. Sci. Instrum. 78 (2007) 034701]. The high efficiency parameter (8.2 GW−1/2 with sample) permits the saturating pump pulse level to be just 5 mW or less. Applications of SR EPR and ELDOR to the hydrophilic spin labels 3-carbamoyl-2,2,5,5-tetra-methyl-3-pyrroline-1-yloxyl (CTPO) and 2,2,6,6,-tetramethyl-4-piperidone-1-oxyl (TEMPONE) are described in detail. In the SR ELDOR experiment, nitrogen nuclear relaxation as well as Heisenberg exchange transfer saturation from pumped to observed hyperfine transitions. SR ELDOR was found to be an essential method for measurements of saturation transfer rates for small molecules such as TEMPONE. Free induction decay (FID) signals for small nitroxides at W-band are also reported. Results are compared with multifrequency measurements of T1e previously reported for these molecules in the range of 2–35 GHz [J.S. Hyde, J.-J. Yin, W.K. Subczynski, T.G. Camenisch, J.J. Ratke, W. Froncisz, Spin label EPR T1 values using saturation recovery from 2 to 35 GHz. J. Phys. Chem. B 108 (2004) 9524–9529]. The values of T1e decrease at 94 GHz relative to values at 35 GHz. 相似文献
976.
For the first time electric‐field‐induced atomic displacements (internal strains) in non‐ferroelectric polar BiB3O6 single crystal plates (point symmetry 2) were investigated using X‐ray diffraction technique. The intensity variations of selected Bragg reflections were collected for three different orientations of the applied external electric field vector with respect to the crystal lattice and used for calculating the microscopic structural response of BiB3O6. Due to the limited number of the reflections providing measurable changes in Bragg intensities we restricted ourselves in analyzing the shift of the B3O6 sublattice relative to the Bi one. In addition, we considered the deformation of the Bi‐O, B(1)‐O and B(2)‐O bond lengths and identified the [B(2)O3] group as the most sensitive structural unit to an external electric perturbation. (© 2008 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献
977.
Automatic phasing of MR images. Part I: linearly varying phase 总被引:1,自引:1,他引:0
Larry Bretthorst G 《Journal of magnetic resonance (San Diego, Calif. : 1997)》2008,191(2):184-192
In spin-echo and well shimmed gradient-echo images, the phase of the complex image often varies linearly in both the readout and phase-encode directions. Thus, in principle, it is possible to display an image in absorption mode. However, manually determining the two first-order and one zero-order phase parameters needed to display an absorption-mode image is a formidable task. In this paper, the Bayesian calculations needed to automatically determine these parameters are presented, and the calculations are illustrated using spin-echo images. 相似文献
978.
Náfrádi B Gaál R Sienkiewicz A Fehér T Forró L 《Journal of magnetic resonance (San Diego, Calif. : 1997)》2008,195(2):206-210
We present a newly-developed microwave probe for performing sensitive high-field/multi-frequency electron spin resonance (ESR) measurements under high hydrostatic pressures. The system consists of a BeCu-made pressure-resistant vessel, which accommodates the investigated sample and a diamond microwave coupling window. The probe’s interior is completely filled with a pressure-transmitting fluid. The setup operates in reflection mode and can easily be assembled with a standard oversized microwave circuitry. The probe-head withstands hydrostatic pressures up to 1.6 GPa and interfaces with our home-built quasi-optical high-field ESR facility, operating in a millimeter/submillimeter frequency range of 105–420 GHz and in magnetic fields up to 16 T. The overall performance of the probe was tested, while studying the pressure-induced changes in the spin-relaxation mechanisms of a quasi-1D conducting polymer, KC60. The preliminary measurements revealed that the probe yields similar signal-to-noise ratio to that of commercially available low-frequency ESR spectrometers. Moreover, by observing the conduction electron spin resonance (CESR) linewidth broadening for KC60 in an unprecedented microwave frequency range of 210–420 GHz and in the pressure range of up to 1.6 GPa, we demonstrate that a combination of high-pressure ESR probe and high-field/multi-frequency spectrometer allows us to measure the spin relaxation rates in conducting spin systems, like the quasi-1D conductor, KC60. 相似文献
979.
Jeanette M. Torrescano-Alvarez Michele Curioni Xiaorong Zhou Peter Skeldon 《Surface and interface analysis : SIA》2019,51(12):1135-1143
The effects of applied current density, anodizing time, and electrolyte temperature on the cell and pore morphology of anodic films and the voltage-time response obtained during galvanostatic anodizing of AA2024-T3 alloy in sulphuric acid electrolytes have been studied. Scanning electron microscopy was employed to observe the film morphology. Sponge-like porous structure was promoted by anodizing at relatively low current density and high electrolyte temperature. In contrast, linear porous structure was favoured under the converse conditions. Intermediate conditions resulted in films containing either sequential layers of the 2 morphologies or a morphology incorporating features of the 2 types; such conditions were associated with anodizing voltages in the range 25 to 35 V. The reasons for the morphological differences are proposed to be due to interactions between film growth stresses and stresses arising from oxygen evolution on the development of the alumina cells. 相似文献
980.
蛭石对高钠高钙准东煤结渣特性影响研究 总被引:1,自引:0,他引:1
采用一维沉降炉,辅以灰熔点仪的实验方法,将蛭石与高钠高钙准东煤掺混燃烧,研究其对高钠高钙准东煤结渣特性的影响。结果表明,随着蛭石掺烧量的提高,灰熔点温度呈现先降低后升高的趋势,当掺烧量为6%时灰熔点温度最低;蛭石掺烧量越高,高钠高钙准东煤结渣情况改善越明显,当掺烧量达到4%时,渣样变得疏松多孔,质地变脆,渣样与沉积探针之间的黏附性较弱,极易通过吹灰除去,建议蛭石掺烧量为4%;煤灰中原始矿物质以石英、钙铝黄长石或钙黄长石以及辉石类的低熔点矿物质为主,掺烧蛭石后,含钠的绿辉石矿物质被转化为韭闪石,含铁的斜辉石、赤铁矿等矿物质被转化为铁橄榄石,渣样中的矿物质均以高熔点的镁橄榄石为主;蛭石具有固钠的作用,取样温度越低,蛭石掺混量越高,其固钠效果越明显。 相似文献