也谈《高分子化学》课程教学的工科特色

《高分子化学》课程是大部分工科化工、材料类专业的必修课程,如何在工科专业高分子化学课程教学中体现工科特色,成为大家关注的热点.针对什么是工科特色,提出了本人的见解.并就如何在教学过程中体现工科特色介绍了本人的探索与尝试.     

A comparison of measured room acoustics metrics using a spherical microphone array and conventional methods

The traditional microphone configuration used to measure room impulse responses (IRs) according to ISO 3382:2009 is an omnidirectional and figure-8 microphone pair. IRs measurements were taken in a 2500-seat auditorium to determine how the results from a spherical microphone array (an mh acoustics Eigenmike-em32) compare to those from the traditional microphone setup (a Brüel & Kjær Type-4192 omnidirectional microphone and a Sennheiser MKH30 figure-8 microphone). Measurements were obtained at six receiver locations, with three repetitions each in order to first evaluate repeatability. The metrics considered in this study were: reverberation time (T30), early decay time (EDT), clarity index (C80), strength (G), lateral energy fraction (J_LF) and late lateral energy level (L_J). Before calculating these quantities, the IRs were filtered to equalize the frequency response of the microphones and sound source. For the spherical array measurements, the omnidirectional (monopole) and figure-8 (dipole) patterns were extracted using beamforming. In terms of repeatability, the average standard deviation of the three measurements at each receiver location averaged across all metrics, receivers, and octave bands was found to be 0.01 just noticeable differences (JNDs). The analysis comparing the measurements from the two microphone configurations yielded differences which were less than 1 JND for the majority of metrics, with a few exceptions of EDT and C80 slightly above 1 JND. Based on this case study, these results indicate that spherical microphone arrays can be used to obtain valid room IR measurements, which will allow for the development of new metrics utilizing the higher spatial resolution made possible with spherical arrays.     

Achieving Enhanced Photochromic Properties of Diarylethene through Host-Guest Interaction in Aqueous Solution

Diarylethene (DTE) has been widely used in fluorescence probes, molecular logic gates, optical data-storage devices owing to the excellent photochromic property, while constructing high-performance photochromic DTE in aqueous media remains a big challenge. Herein we present several host-guest systems formed between cucurbit[n]uril (CB[n], n=7, 8, 10) and two water-soluble DTE derivatives 1 and 2 . It was found that host-guest interactions not only affect the photophysical properties of photochromic guests, but also make great differences on the photoreaction process. Different host-guest binding behaviors also lead to different effects on the photochromic properties of guests. In the presence of CB[n], both 1 and 2 showed enhanced emission and higher fluorescence quenching ratio at photostationary state. Besides, CB[10] ⋅1 exhibited faster response rate in cyclization reaction and better photofatigue resistance than free 1 in aqueous solution, while the supramolecular assembly of (CB[8])_n ⋅ ( 2 )_n showed slower response rate in both directions of the reversible photoreaction. Besides, the photofatigue resistance of 2 can be greatly improved through binding with CB[7]. Our results suggest that host-guest interactions could be an efficient way to improve photochromic properties of DTE in aqueous solution.     

晶硅太阳电池原位光老化及热致输运机理

为研究晶体硅太阳电池在标准模拟光条件下的输出特性变化规律和电池内部载流子输运特性,采用原位光老化技术对被测电池进行光照处理,按标准测试实验流程测量电池的伏安特性及光谱响应等参量,发现原位光老化后太阳电池伏安特性各项参量衰减,导致电池效率降低;短波段光谱响应微量下降,是由于原位光老化过程中电池表面产生极微量的面缺陷导致经过硅表面的微量载流子被复合;而长波段响应明显降低,是由于晶硅内大量体缺陷被激活导致长波载流子在经过硅材料内部时被复合.随后将光老化后电池退火并测量比对电池各项特性参量,结果表明,退火对光老化后电池内部深层体缺陷具有较好的修复功能,但对浅层面缺陷没有修复功能,最终造成电池伏安特性参量和光谱响应只得到部分恢复.     

Verification of the Usefulness of Radiotracing Methods in Hydrodynamic Investigations

In the paper comparison of accuracy of two methods used for investigations of hydrodynamic in continuous flow tanks has been made. Basis for the comparison is the experimental work performed for big industrial wastewater concentration equalization tank. The first method is based on the radiotracer experiment while the second one uses the analysis of response on sudden change of the technological parameters. The radiotracer method has better accuracy connected with the shorter sampling period.

Ks wird die Genauigkeit zweier Methoden zur Untersuchting der Hydrodynamik von kontinuierlich arbeitenden Flüssigkeitsbehältern verglichen. Grundlage dafür sind experimentelle Untersuchungen an groβen Industrieabwasser-Ausgleichsbehältern. Die erste Methode bedient sich der Radiotracertechnik, während die zweite Methode auf einer plötzlichen Veränderung der technologischcn Parameter beruht. Es zeigt sich, daβ die Radiotracermethoden die besseren Ergebnisse liefert, wobei auβerdem noch kürzere Probenaltmeperioden von Vorteil sind.     

Solvent replacement to thermo‐responsive nanoparticles from long‐subchain hyperbranched PSt grafted with PNIPAM for encapsulation

Long‐subchain hyperbranched polystyrene (lsc‐hp PSt) with uniform subchain length was obtained through copper‐catalyzed azide‐alkyne cycloaddition click chemistry from seesaw macromonomer of PSt having one alkynyl group anchored at the chain centre and two azido group attached to both chain ends [alkynyl‐(PSt‐N₃)₂]. After precipitation fraction, different portions of lsc‐hp PSt having narrow overall molecular weight distribution were obtained for further grafting with alkynyl‐capped poly(N‐isopropylacrylamide) (alkynyl‐PNIPAM), which was obtained via single‐electron transfer living radical polymerization of NIPAM with propargyl 2‐bromoisobutyrate as the initiator and grafted onto the peripheral azido groups of lsc‐hp PSt via click chemistry. Thus, amphiphilic lsc‐hp PSt grafted with PNIPAM chains (lsc‐hp PSt‐g‐PNIPAM) was obtained and would have star‐like conformation in tetrahydrofuran (THF). By replacing THF with water, lsc‐hp PSt‐g‐PNIPAM was dissolved at molecular level in aqueous solution due to the hydrophilicity of PNIPAM and exhibited thermal induced shrinkage of PNIPAM arms. The water‐insoluble lsc‐hp PSt would collapse densely and could be served as a reservoir to absorb hydrophobic chemicals in aqueous solution. The influence of overall molecular weight of lsc‐hp PSt on the absorption of pyrene was studied. © 2013 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2013     

Optimal feedback gains of a delayed proportional-derivative (PD) control for balancing an inverted pendulum

In the dynamics analysis and synthesis of a con-trolled system, it is important to know for what feedback gains can the controlled system decay to the demanded steady state as fast as possible. This article presents a sys-tematic method for finding the optimal feedback gains by taking the stability of an inverted pendulum system with a delayed proportional-derivative controller as an example. First, the condition for the existence and uniqueness of the stable region in the gain plane is obtained by using the D-subdivision method and the method of stability switch. Then the same procedure is used repeatedly to shrink the stable region by decreasing the real part of the rightmost charac-teristic root. Finally, the optimal feedback gains within the stable region that minimizes the real part of the rightmost root are expressed by an explicit formula. With the optimal feedback gains, the controlled inverted pendulum decays to its trivial equilibrium at the fastest speed when the initial val-ues around the origin are fixed. The main results are checked by numerical simulation.     

Simulation of near-infrared photodiode detectors based on β-FeSi_2/4H-SiC heterojunctions

In this paper,we propose a near-infrared p-type β-FeSi2/n-type 4H-SiC heterojunction photodetector with semiconducting silicide(β-FeSi2) as the active region for the first time.The optoelectronic characteristics of the photodetector are simulated using a commercial simulator at room temperature.The results show that the photodetector has a good rectifying character and a good response to near-infrared light.Interface states should be minimized to obtain a lower reverse leakage current.The response spectrum of the β-FeSi2/4H-SiC detector,which consists of a p-type β-FeSi2 absorption layer with a doping concentration of 1×1015cm-3 and a thickness of 2.5 μm,has a peak of 755 mA/W at 1.42 μm.The illumination of the SiC side obtains a higher responsivity than that of the β-FeSi2 side.The results illustrate that the β-FeSi2/4H-SiC heterojunction can be used as a near-infrared photodetector compatible with near-infrared optically-activated SiC-based power switching devices.