全文获取类型
收费全文 | 3135篇 |
免费 | 66篇 |
国内免费 | 294篇 |
专业分类
化学 | 1985篇 |
晶体学 | 4篇 |
力学 | 272篇 |
综合类 | 1篇 |
数学 | 762篇 |
物理学 | 471篇 |
出版年
2024年 | 9篇 |
2023年 | 140篇 |
2022年 | 40篇 |
2021年 | 71篇 |
2020年 | 75篇 |
2019年 | 91篇 |
2018年 | 88篇 |
2017年 | 80篇 |
2016年 | 58篇 |
2015年 | 61篇 |
2014年 | 134篇 |
2013年 | 300篇 |
2012年 | 106篇 |
2011年 | 189篇 |
2010年 | 135篇 |
2009年 | 203篇 |
2008年 | 192篇 |
2007年 | 221篇 |
2006年 | 195篇 |
2005年 | 155篇 |
2004年 | 144篇 |
2003年 | 78篇 |
2002年 | 65篇 |
2001年 | 44篇 |
2000年 | 51篇 |
1999年 | 46篇 |
1998年 | 79篇 |
1997年 | 41篇 |
1996年 | 41篇 |
1995年 | 31篇 |
1994年 | 44篇 |
1993年 | 59篇 |
1992年 | 33篇 |
1991年 | 28篇 |
1990年 | 24篇 |
1989年 | 19篇 |
1988年 | 14篇 |
1987年 | 21篇 |
1986年 | 9篇 |
1985年 | 7篇 |
1984年 | 11篇 |
1983年 | 11篇 |
1982年 | 12篇 |
1981年 | 6篇 |
1980年 | 7篇 |
1979年 | 8篇 |
1975年 | 2篇 |
1972年 | 2篇 |
1970年 | 4篇 |
1968年 | 2篇 |
排序方式: 共有3495条查询结果,搜索用时 15 毫秒
21.
杨力平 《应用数学学报(英文版)》1994,10(3):233-251
FREEBOUNDARYPROBLEMARISINGFROMEVAPORATIONFROMPOROUSMEDIUMYANGLIPING(杨力平)(DepartmentofAppliedMathematics,TsinghuaUniversity,Be... 相似文献
22.
In this note we prove that the prime madicals of some graded rings and the scoles of some graded modules are also graded. The results on the relations between the prime radical and the graded prime radical are also presented. Moreover, the relations between a graded ring and its initial subring are studied. 相似文献
23.
The effect of gamma irradiation in air is investigated on four thermoplastic polyesters (PET, PBT, PEN, PCT-co-ET) in films containing aromatic rings, in order to evaluate the influence of aromatic density and the role of oxygen on radiation resistance. Physical-chemical-nuclear analyses were used to this purpose. EPR measurements were carried out to detect radical stability against oxygen permeation. Viscometric investigations reported a very similar trend for all the investigated polyesters: a chain break effect that decreases at the highest doses. FT-IR analyses focused on the formation of oxidized species. Positron annihilation spectra pointed out a decrease of the intensity of ortho-positronium formation, while its lifetime remains unchanged with radiation dose. 相似文献
24.
We define a classical probability analogue of Voiculescu's free entropy dimension that we shall call the classical probability entropy dimension of a probability measure on Rn. We show that the classical probability entropy dimension of a measure is related with diverse other notions of dimension. First, it can be viewed as a kind of fractal dimension. Second, if one extends Bochner's inequalities to a measure by requiring that microstates around this measure asymptotically satisfy the classical Bochner's inequalities, then we show that the classical probability entropy dimension controls the rate of increase of optimal constants in Bochner's inequality for a measure regularized by convolution with the Gaussian law as the regularization is removed. We introduce a free analogue of the Bochner inequality and study the related free entropy dimension quantity. We show that it is greater or equal to the non-microstates free entropy dimension. 相似文献
25.
低密度聚乙烯光引发交联机理——Ⅱ.BNB自旋捕捉ESR研究 总被引:6,自引:4,他引:2
在光引发剂二苯甲酮(BP)存在下,紫外光辐照低密度聚乙烯(LDPE)所形成的自由基中间体已被自旋捕捉剂2,4,6-三特丁基亚硝基苯(BNB)所捕捉,其自旋加合物自由基已为电子自旋共振(ESR)所特征。现已检测和鉴定到二种自旋加合物:一种是叔碳自由基;另一种是仲碳自由基。它们分别是由BP的激发三重态从LDPE链的支化点和亚甲基团上夺氢所形成的自由基中间体同自旋捕捉剂BNB反应生成的。上述的证据表明:LDPE的光引发交联点主要发生在叔碳和仲碳原子上,且H-型交联点占主导地位。 相似文献
26.
Lucien Stella 《Angewandte Chemie (International ed. in English)》1983,22(5):337-350
Many N-chloroalkylamines with double bond(s) dissociate homolytically to give chlorine atoms and aminyl radicals which undergo intramolecular cyclization reactions. Here, the nature of the aminyl radicals (neutral, protonated, or complexed to metal salts) appears to be important. The reactivity varies strongly from one species to another, and their selectivities can be different towards addition, substitution, abstraction, or dimerization reactions. A good synthetic tool appears to be the “complexed radical”, which is generated under mild conditions. A variety of β-functionalized, substituted, fused, or bridged azaheterocycles with alkaloid part structures thus become easily accessible in high yields, in a regio- and, possibly, stereoselective manner. Many examples are discussed illustrating the synthetic possibilities, limitations, and mechanistic features of this cyclization process. 相似文献
27.
Paolo Zatta Tamas KissMario Suwalsky Guy Berthon 《Coordination chemistry reviews》2002,228(2):271-284
Aluminium has been known as a neurotoxic agent to experimental animals since the last century (Arch. Exp. Pharmacol. 40 (1897) 98). However, great interest arose in it bioinorganic chemistry as well biology when it was demonstrated to be the causative agent in pathologies related to the long-term dialysis treatment of uremic subjects with renal failure (Life Chem. 11 (1994) 197), and as a potential etiopathogenic cofactor for several neurodegenerative diseases. The inorganic biochemistry of aluminium is still largely to be discovered. In this review the pro-oxidative property of aluminium toward biological membrane will be presented and its implications in involvement in human pathology will be discussed in an interdisciplinary frame from the bioinorganic point of view. 相似文献
28.
K. Dimroth A. Berndt F. Br A. Schweig R. Volland 《Angewandte Chemie (International ed. in English)》1967,6(1):34-40
The distribution of the unpaired electron over the oxygen and the 24 carbon atoms in the free 2,4,6-triphenylphenoxy radical was determined by electron spin resonance spectroscopy and quantum-mechanical approximation methods. The hyperfine splitting was evaluated with the aid of the spectra of triphenylphenoxyls deuterated in some or all of the substituent phenyl groups. The results of the quantum-mechanical approximations were checked by recording the ESR spectra of triphenylphenoxyls labeled with 13C in positions 1,2,3, or 4 of the central ring. The spin density distribution permits a first discussion of the 17O-coupling constants of correspondingly labeled triphenylphenoxyl and other organic free radicals. 相似文献
29.
Radical anions of nitrobenzothiazoles: EPR study of conjugative properties of benzothiazolyl systems
Francesco Ciminale 《Tetrahedron letters》2004,45(30):5849-5852
The electrochemical reduction in DMSO of the five isomers of nitrobenzothiazole (NBTZ) gave quite persistent radical anions that could be easily characterised by EPR spectroscopy. By contrast, the chemical reduction in alkaline solution, that is by t-BuOK in DMSO or by glucose and MeOK in MeOH, presented some problems with 6- and 4-NBTZ, and in the case of 2-NBTZ did not provide any detectable paramagnetic species. The internal consistency of coupling constants of the nitrobenzothiazole radical anions is in good agreement with the conjugative properties of the various benzothiazolyl systems and allows rectifying a recent EPR characterisation of 6-NBTZ radical anion. 相似文献
30.