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101.
利用BP神经网络技术建立了电火花线切割加工工况参数与工艺目标间的预测模型.以脉冲宽度、脉冲间隙、峰值电流、间隙电压及工件厚度等工况参数为网络输入,加工效率和表面粗糙度等工艺目标为网络输出,通过用样本数据对网络的训练,实现了对工艺目标的预测.试验结果表明:所建预测模型能较好地反映线切割机床的工艺规律,实现对指定切割条件下加工效率和表面粗糙度的预测,最大预测误差小于10%. 相似文献
102.
103.
To understand the effect of Au and thiol atoms in octane molecule, a structural and charge density analysis has been carried out by high level ab initio quantum chemical calculations using MP2 and B3PW91 methods with the basis sets 6-311G(d,p) and LANL2DZ. The optimized geometries, specifically, the geometry obtained from both levels reveal the effect of S- and Au-atoms in octane molecule. An introduction of sulfur atom in octane molecule lengthen its backbone C–C bond distances, and further adding of Au-atom at the terminals of octane dithiolate stabilizes these distances. The bond densities of the C–C bonds of octane are 1.6 eÅ−3, these values are decreased significantly and the charges are largely depleted, when thiol and Au-atoms added in the octane molecule. The presence of negative Laplacian 2ρ(r) at bond critical points of C–C and C–H bonds, indicate, the charges are concentrated in these bonds, confirm that these bonds exhibit an open shell type interaction. The moderate values of density and the negative Laplacian of S–C bonds confirm the covalent character. The positive 2ρ(r) value of Au–S bonds, characterize, the bonding interaction is a closed shell interaction. The combined observed low value of electron density and the positive Laplacian of Au–S bond comprises, the gold and S interaction is not a covalent interaction, but it is a very weak coordination bond interaction. The small positive value of total energy density in Au–S bond indicates, the charges in these bonds are highly depleted and this is further confirmed by the Laplacian of bond characterization. 相似文献
104.
Hiroshi Morita Anzu Kasai Jan ubrt Zdenk Bastl 《Journal of photochemistry and photobiology. A, Chemistry》2009,206(2-3):205-212
Under UV light irradiation on a gaseous mixture of Fe(CO)5 and Co(CO)3NO, both the crystalline deposits with sizes of 5 and 18 μm and the spherical particles with a mean diameter of 0.3 μm were produced. From FT-IR spectra and SEM–EDS analysis, it was suggested that the chemical structure of the crystalline deposits was the one of Fe2(CO)9 being modified by involving Fe(CO)Co bond. By decreasing a partial pressure of Fe(CO)5 to 0.5 Torr in the gaseous mixture, only the spherical aerosol particles could be produced. Chemical composition of the particles was rich in Co species. From the disappearance of bridging CO band in the FT-IR spectra of the particles and the appearance of CO bands coordinated to a metal atom, Fe atom in Fe(CO)4 was suggested to be coordinated by the O atom in bridging CO bond in Co(CO)Co structure and/or in α-diketone structure which was formed from two CO groups in dicobalt species. Chemical compositions of the crystalline deposits and the spherical particles were influenced differently by the application of a magnetic field. Atomic ratio of Fe to Co atom decreased in the crystalline deposits whereas it increased in the spherical particles with increasing magnetic field up to 5 T. Linearly aggregated particles (i.e., particle wires) as long as 30 μm were produced on the front side of a glass plate placed at the bottom of the irradiation cell. 相似文献
105.
106.
Direct Synthesis of High Purity Silicon Wires by Electrorefining in Molten KF-NaF Eutectic 下载免费PDF全文
The electrochemical synthesis silicon wires by electrorefining metallurgical grade silicon in thermally dried and pre-electrolyzed molten KF-NaF eutectic were studied at temperatures 800-900 oC using cyclic voltammetry and ac impedance. One oxidation peak at -0.14 V could be attributed to the reaction of Si to Si4+. A cathodic peak occurred at -0.56 V in the cyclic voltammogram and one response semicircle in the ac impedance spectrum was observed, supporting a one-step electrochemical reduction process of Si4+→Si. The electrochemical reaction of silicon was controlled by the diffusion process. The purity of electrorefined silicon wires was up to 99.999% by ICP-MS analysis. 相似文献
107.
Radiation characteristics and implosion dynamics of tungsten wire array Z-pinches on the YANG accelerator 下载免费PDF全文
We investigated the radiation characteristics and implosion dynamics of low-wire-number cylindrical tungsten wire array Z-pinches on the YANG accelerator with a peak current 0.8-1.1 MA and a rising time ~ 90 ns.The arrays are made up of(8-32)×5 μm wires 6/10 mm in diameter and 15 mm in height.The highest X-ray power obtained in the experiments was about 0.37 TW with the total radiation energy ~ 13 kJ and the energy conversion efficiency ~ 9%(24×5 μm wires,6 mm in diameter).Most of the X-ray emissions from tungsten Z-pinch plasmas were distributed in the spectral band of 100-600 eV,peaked at 250 and 375 eV.The dominant wavelengths of the wire ablation and the magneto-Rayleigh-Taylor instability were found and analyzed through measuring the time-gated self-emission and laser interferometric images.Through analyzing the implosion trajectories obtained by an optical streak camera,the run-in velocities of the Z-pinch plasmas at the end of the implosion phase were determined to be about(1.3-2.1)×10 7 cm/s. 相似文献
108.
We study the electronic transport in quantum wire structures made of graphene. By using the nonequilibrium Green function method, the transmission is studied for varies sizes samples. Our results show that the transmission sensitive depends on the size of the system and exhibits fluctuations due to the mismating of propagating modes between the central region and the leads. The number of resonant transmission peaks increases with the increase of length of the wire, while the width of the leads mainly affect the transmission in the region of low energy. A central energy gap in the transmission spectrum is more likely to appear in the quantum wire system than in the uniform armchair graphene nanoribbons. Moreover, the energy gap can be widened for a certain size of the quantum wire system by changing the width of the leads. These results may have potential applications in designing graphene-based devices. 相似文献
109.
CADS注入器Ⅰ试验装置由中国科学院高能物理研究所承建。其10mA的束流由RFQ结构加速到3.2 MeV,经中能传输段匹配到超导加速结构。为了减小失匹配造成的束流损失,需要测量RFQ出口束流参数,以便调整中能传输段Lattice结构,使束流能匹配进入超导腔。CADS注入器Ⅰ采用丝靶扫四极铁参数的方式测量束流截面并计算RFQ出口Twiss参数。强流加速器在低能段空间电荷力很强,常规的基于矩阵的数据处理方法会带来误差。本文分别用常规的未考虑空间电荷效应的矩阵方法和考虑了空间电荷效应的遗传算法对数据进行处理,得到的结果显示低能强流加速器进行Twiss参数测量时,必须考虑空间电荷效应的影响。 相似文献
110.
This study presents a general approach for the synthesis of carbon‐encapsulated wire‐in‐tube Co3O4/MnO2 heterostructure nanofibers (Co3O4/MnO2@C) via electrospinning followed by calcination. The as‐synthesized Co3O4/MnO2@C is investigated as the sodium‐ion batteries anode material, which not only exhibits a high reversible capacity of 306 mAh g−1 at 100 mA g−1 over 200 cycles, but also shows a cycling stability of 126 mAh g−1 after 1000 cycles at a high current density of 800 mA g−1. The excellent electrochemical performance can be ascribed to the contribution from carbon‐encapsulated outer‐tube Co3O4 and inner‐wire MnO2 heterostructures, which offer a large internal space and good electrical conductivity. The present work can be helpful in providing new insights into heterostructures for sodium‐ion batteries and other applications. 相似文献