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51.
Piotr Garbaczewski 《Journal of statistical physics》2006,123(2):315-355
We analyze the functioning of Gibbs-type entropy functionals in the time domain, with emphasis on Shannon and Kullback-Leibler entropies of time-dependent continuous probability distributions. The Shannon entropy validity is extended to probability distributions inferred from L
2(R
n
) quantum wave packets. In contrast to the von Neumann entropy which simply vanishes on pure states, the differential entropy quantifies the degree of probability (de)localization and its time development. The associated dynamics of the Fisher information functional quantifies nontrivial power transfer processes in the mean, both in dissipative and quantum mechanical cases.
PACS NUMBERS: 05.45.+b, 02.50.-r, 03.65.Ta, 03.67.-a 相似文献
52.
By recourse to (i) the Hellmann-Feynman theorem and (ii) the virial one, the information-optimizing principle based on Fisher’s information measure uncovers a Legendre-transform structure associated with Schrödinger’s equation, in close analogy with the structure that lies behind the standard thermodynamical formalism. The present developments provide new evidence for the information theoretical links based on Fisher’s measure that exist between Schrödinger’s equation, on the one hand, and thermodynamics/thermostatistics on the other hand. 相似文献
53.
J. S. Dehesa S. López‐Rosa A. Martínez‐Finkelshtein R. J. Yáñez 《International journal of quantum chemistry》2010,110(8):1529-1548
The analytic information theory of quantum systems includes the exact determination of their spatial extension or multidimensional spreading in both position and momentum spaces by means of the familiar variance and its generalization, the power and logarithmic moments, and, more appropriately, the Shannon entropy and the Fisher information. These complementary uncertainty measures have a global or local character, respectively, because they are power‐like (variance, moments), logarithmic (Shannon) and gradient (Fisher) functionals of the corresponding probability distribution. Here we explicitly discuss all these spreading measures (and their associated uncertainty relations) in both position and momentum for the main prototype in D‐dimensional physics, the hydrogenic system, directly in terms of the dimensionality and the hyperquantum numbers which characterize the involved states. Then, we analyze in detail such measures for s‐states, circular states (i.e., single‐electron states of highest angular momenta allowed within an electronic manifold characterized by a given principal hyperquantum number), and Rydberg states (i.e., states with large radial hyperquantum numbers n). © 2009 Wiley Periodicals, Inc. Int J Quantum Chem, 2010 相似文献
54.
The dimensional analyses of the position and momentum variances‐based quantum mechanical Heisenberg uncertainty measure, as well as the entropic information measures given by the Shannon information entropy sum and the product of Fisher information measures are carried out for two widely used nonrelativistic isotropic exponential‐cosine screened Coulomb potentials generated by multiplying the superpositions of (i) Yukawa‐like, ?Z(e?μr/r), and (ii) Hulthén‐like, ?Zμ(1/(eμr ? 1)), potentials by cos(bμr) followed by addition of the term a/r2, where a and b ≥ 0, μ are the screening parameters and Z, in case of atoms, denotes the nuclear charge. Under the spherical symmetry, all the information measures considered are shown to be independent of the scaling of the set [μ, Z] at a fixed value of μ/Z, a, and b and the other parameters defining the superpositions of the potentials. Numerical results are presented, which support the validity of the scaling properties. © 2007 Wiley Periodicals, Inc. Int J Quantum Chem, 2007 相似文献
55.
The concept of global statistical information in the classical statistical experiment with independent exponentially distributed samples is investigated. Explicit formulas are evaluated for common exponential families. It is shown that the generalized likelihood ratio test procedure of model selection can be replaced by a generalized information procedure. Simulations in a classical regression model are used to compare this procedure with that based on the Akaike criterion. 相似文献
56.
Questions of asymptotic inference are discussed for a point process model in which the conditional intensity function increases monotonically between events and drops by determined (nonrandom) amounts after each event. Parameter estimates are shown to be consistent and, except under the null hypothesis of a Poisson process, normally distributed. Under the null hypothesis, however, the Hessian matrix is not asymptotically constant, and the limiting distribution of the likelihood ratio statistics is not χ2, but has a form related to that of the Cramer-von Mises ω2 statistic for the test of goodness of fit. 相似文献
57.
We highlight the potentiality of a special Information Theory (IT) approach in order to unravel the intricacies of nonlinear dynamics, the methodology being illustrated with reference to the logistic map. A rather surprising dynamic feature→plane-topography map becomes available. 相似文献
58.
59.
Rodolfo O. Esquivel Moyocoyani Molina-Espíritu Juan Carlos Angulo Juan Antolín Nelson Flores-Gallegos Jesús S. Dehesa 《Molecular physics》2013,111(19):2353-2365
In this work, we have investigated the complexity of the hydrogenic abstraction reaction by means of information functionals such as disequilibrium (D), exponential entropy (L), Fisher information (I), power entropy (J) and joint information-theoretic measures, i.e. the I–D, D–L and I–J planes and the Fisher–Shannon and López–Mancini–Calbet (LMC) shape complexities. The analysis of the information-theoretical functionals of the one-particle density was computed in position (r) and momentum (p) space. The analysis revealed that all of the chemically significant regions can be identified from the information functionals and most of the information-theoretical planes, i.e. the reactant/product regions (R/P), the transition state (TS), including those that are not present in the energy profile such as the bond cleavage energy region (BCER), and the bond breaking/forming regions (B–B/F). The analysis of the complexities shows that, in position as well as in the joint space, the energy profile of the abstraction reaction bears the same information-theoretical features as the LMC and FS measures. We discuss why most of the chemical features of interest, namely the BCER and B–B/F, are lost in the energy profile and that they are only revealed when particular information-theoretical aspects of localizability (L or J), uniformity (D) and disorder (I) are considered. 相似文献
60.
In this paper, the Fisher equation is analysed. One of its travelling wave solutionis obtained by comparing it with KdV--Burgers (KdVB) equation. Its amplitude, widthand speed are investigated. The instability for the higher order disturbances to thesolution of the Fisher equation is also studied. 相似文献