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31.
32.
We describe a new experiment for measuring homonuclear-decoupled anisotropic chemical shift patterns in doubly 13C-labeled compounds under magic-angle spinning. The experiment combines a pair of selective and non-selective 180 degrees pulses to suppress the 13C-13C scalar and dipolar interactions. This is combined with the recently developed SUPER technique to recouple the chemical shift anisotropy. Demonstrations on 13Calpha and 13CO-labeled amino acids and peptides show that accurate chemical shift powder patterns can be obtained. This permits the use of chemical shift anisotropy for conformational studies of suitably extensively 13C-labeled peptides and proteins. 相似文献
33.
Price WS Stilbs P Söderman O 《Journal of magnetic resonance (San Diego, Calif. : 1997)》2003,160(2):139-143
The influence of finite length gradient pulses on NMR diffusion experiments on liquids confined to diffuse between two parallel planes is investigated. It is experimentally verified that the pore size decreases when determined using finite gradient pulses if the results are analyzed within the short gradient pulse approximation. The results are analyzed using the matrix formulation. The observed minima in the echo decay profiles are considerably less sharp than theoretical analysis would indicate and we suggest that this is due to the presence of a distribution of pore sizes in the sample. In addition, effects due to the presence of background gradients are discussed. It is argued that effects due to the finite length gradient pulses are relatively minor and in realistic applications the effects due to inhomogeneities in pore sizes and effects due to background gradients will constitute more serious problems in pore size determinations by means of NMR diffusometry. 相似文献
34.
Shen J 《Journal of magnetic resonance (San Diego, Calif. : 1997)》2001,149(2):234-238
Unlike prefocused pulses and shaped pulses based on the linear response theory, delayed-focus pulses (X.-L. Wu et al., 1991, Magn. Reson. Med. 20, 165--170) produce a selective spin echo after a predefined short delay without using a pi refocusing pulse. In this paper, a series of delayed-focus pulses of different flip angles are proposed based on optimization using Fourier series representation and simulated annealing. The resistance of these delayed-focus pulses to T(2) relaxation is also demonstrated using numerical simulation of Bloch equations. 相似文献
35.
Steffen M Vandersypen LM Chuang IL 《Journal of magnetic resonance (San Diego, Calif. : 1997)》2000,146(2):369-374
The rotation of a spin subject to an on-resonance soft pulse and simultaneously to a soft pulse at a nearby frequency may strongly deviate from the desired rotation expected for a single on-resonance pulse. The deviation is the result of transient frequency shifts of the spin caused by the off-resonance irradiation. We show that the resulting error can be corrected by shifting the frequency of the on-resonance pulse in such a way that it tracks the shift of the spin frequency. Experimentally, the effectiveness of this simple and intuitive method is demonstrated for simultaneous inversions at nearby frequencies in the case of both coupled and uncoupled spins. Simulations predict that the correction technique is effective for arbitrary pulse shapes and tip angles and is particularly useful when the frequency window of the shaped pulse is two to eight times the frequency separation between the chemical shifts of the two spins. 相似文献
36.
37.
第四讲 超强激光脉冲与等离子体相互作用中高能离子的产生 总被引:2,自引:0,他引:2
近几年来,由于高功率激光技术的不断发展,利用超强激光脉冲与等离子体相互作用产生高能离子束的研究得到了极大推动.实验和理论模拟均发现,在超强激光脉冲与等离子体相互作用过程中,可以产生高亮度、小尺寸、方向性好的高能质子束和高能重离子束.这种基于超强激光的高能离子源在先进离子束成像技术、惯性约束聚变混合“快点火”、新型台面离子加速器以及医疗等方面都有很诱人的应用前景.文章主要介绍了超强激光与固体靶相互作用中高能离子束(尤其是质子束)的加速机制、高能离子束特性、常用测量方法及其潜在应用,并对最新的研究进展进行了简单介绍. 相似文献
38.
In the present work, we have analyzed the use of elliptical beam shaping along with low numerical aperture focusing optics in order to produce circular cross-section waveguides in different materials at large processing depths by direct femtosecond laser writing (100 fs, 800 nm, 1 kHz). A variable slit located before the focusing optics allows to generate a nearly elliptical beam shape and also to reduce the effective numerical aperture of the beam along the shat axis of the ellipse. The focusing optics allows to focus the beam deep inside the sample, which is translated at a constant speed transversely to the writing beam direction. The influence of several experimental parameters (energy per pulse, slit width, processing depth) on the properties of the produced waveguides has been analyzed. The influence of the intrinsic properties of the material (refractive index, composition) has been analyzed by comparing results obtained in fused silica and Er:Yb co-doped phosphate glass. The results obtained show that this approach leads to the successful production of deep subsurface (up to 7 mm) waveguides with circular cross-sections. Preliminary results using chirped pulses in the phosphate glass suggest that temporal pulse shaping can be used as an additional parameter to optimize the guided mode symmetry. 相似文献
39.
H. Ueba 《Surface science》2007,601(22):5212-5219
Adsorbate motions are discussed with a primary attention focused on the coupling between a vibrational mode excited by ultrafast laser heated hot-electrons or by inelastic tunneling electrons with scanning tunneling microscope and the reaction coordinate (RC) mode. Recent experimental results have demonstrated an efficient reaction pathways involving an indirect excitation of a frustrated translational mode, rather than its direct excitation for adsorbate hopping on surfaces. Elementary processes are briefly described for hopping of CO molecules on a laser heated stepped Pt surface, where excitation of the frustrated rotation mode has been found to plays an indispensable. Calculation of the inelastic tunneling current (ITC) for excitation of the C-O stretch mode of a CO molecule is combined with a theory of anharmonic mode coupling to activate the frustrated translation mode above the barrier. The hopping rate as a function of the bias voltage agrees with the experimental result. An unified theory of single-, and two-electron processes for ITC-induced motions induced by an indirect excitation of the RC-mode via mode coupling is also applied to reproduce a crossover from hopping to desorption of a single NH3 molecule on Cu(1 0 0) with an increase in the tunneling current. 相似文献
40.
The effect of intrapulse Raman scattering (IRS) for the propagation of the femtosecond solitons in an optical fiber is investigated. To factually simulate its influence, a combination of 27 Lorentian lines to fit experimental Raman gain profile is adopted. By using nonlinear Schrödinger equation and finite-difference time domain method, the propagations of femtosecond fundamental solitons in an optical fiber are numerically calculated. When the initial power is suitably enhanced, it is found that the pulse shape is almost the same as initial pulse and the delay Raman response only makes small pulse shift. In other words, when ultrashort soliton is considered, the IRS effect is similarly frozen under the enhanced initial power. 相似文献