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71.
72.
Hiroki Shigehisa 《Tetrahedron letters》2006,47(41):7301-7306
The first total synthesis of a spiro-isoquinoline alkaloid, (±)-annosqualine, was established by employing an enamide-phenol coupling of a 1-methylene-1,2,3,4-tetrahydroisoquinoline derivative with a hypervalent iodine reagent, where the formation of the phenoxide was recognized to be an essential step for the reaction of the phenolic hydroxyl group with the hypervalent iodine reagent leading to the formation of the desired product. 相似文献
73.
We explore the magnetic heat capacity in exchange-biased ferromagnet/antiferromagnet bilayers theoretically. We show that changes in the antiferromagnetic structure due to the reversal of the ferromagnet layer can be detected by distinct features in the heat capacity. This offers a method for probing antiferromagnetic domains in exchange-biased systems. 相似文献
74.
红外目标模拟器由红外目标图像发生器和投影光学系统组成。该红外光学系统是一个要求与2个导引光学系统的光学技术参数相匹配的长焦距、大视场和具有像方远心光路的中红外光学系统。叙述用于红外目标模拟器的红外耦合光学系统的设计原理,提出它与导引光学系统一起可组成放大倍率M=4.5×的红外投影光学系统,并指出IR CRT产生的图像通过红外投影光学系统可成像在导引接收器上。针对给出的红外耦合光学系统的设计特点和技术要求,光学材料选取硅(Si) 锗(Ge) 硅(Si),采用简单的柯克三片式结构完成光学系统设计。设计评价结果表明,该系统的光学性能和成像质量均满足设计指标要求。 相似文献
75.
Surajit Some 《Tetrahedron letters》2006,47(7):1221-1224
A convenient synthetic approach to substituted benzene derivatives by modified Ullmann cross-coupling of 2-bromobenzaldehyde and bromovinylaldehydes followed by intramolecular McMurry coupling has been developed. 相似文献
76.
在常温常压下采用新型旋转电极等离子体反应器,对辉光等离子体作用下的甲烷偶联反应制C2烃进行了研究。结果表明,甲烷偶联反应的主要产物为C2H2,占C2烃的80%以上,能量效率在5.6%~11.2%之间;增加H2含量可以提高CH4转化率和C2烃收率;在500~2200kJ•mol−1的能量密度范围内,CH4转化率随能量密度的增大而线性增加,C2烃收率随着能量密度的增加呈峰形变化趋势。 相似文献
77.
H. Barentzen 《Annalen der Physik》2006,15(9):684-698
The eigenvalues of the weakly coupled T ? t Jahn‐Teller problem are known for several decades, and the same holds also true for the eigenstates. These, however, are only given in the traditional position representation, which proves inconvenient if one attempts to extend the weak‐coupling treatment into the region of stronger coupling. Here the solution of the T ? t eigenvalue problem at weak coupling is derived in terms of creation and annihilation operators. This reformulation of the problem is nontrivial, since the algebraic form of the oscillator eigenvectors, being simultaneous angular‐momentum eigenstates, has been worked out only recently and is probably still widely unknown. The electronic and oscillator eigenstates are then coupled to form eigenvectors of the total angular momentum. Finally, in preparation for an extension of the weak‐coupling treatment, the action of the boson creation and annihilation operators on the oscillator eigenvectors is calculated, thus completing the algebraic approach to the weakly coupled T ? t system. 相似文献
78.
The purpose of this paper is two-fold. First, we introduce a new asymptotic expansion in the exponent for the compound binomial
approximation of the generalized Poisson binomial distribution. The dependence of its accuracy on the symmetry and shifting
of distributions is investigated. Second, for compound binomial and compound Poisson distributions, we present new smoothness
estimates, some of which contain explicit constants. Finally, the ideas used in this paper enable us to prove new precise
bounds in the compound Poisson approximation.
Published in Lietuvos Matematikos Rinkinys, Vol. 46, No. 1, pp. 67–110, January–March, 2006. 相似文献
79.
We investigate linear parabolic systems with coupled nonsmooth capacities and mixed boundary conditions. We prove generalized resolvent estimates in W?1, p spaces. The method is an appropriate modification of a technique introduced by Agmon to obtain Lp estimates for resolvents of elliptic differential operators in the case of smooth boundary conditions. Moreover, we establish an existence and uniqueness result. Copyright © 2007 John Wiley & Sons, Ltd. 相似文献
80.
Alberto Gambi 《Journal of Molecular Spectroscopy》2002,216(2):508-514
The anharmonic force field of difluoromethanimine, F2C NH, has been reinvestigated theoretically using a coupled-cluster singles and doubles approach, augmented for structural optimization and harmonic force field by a contribution of connected triple excitations, CCSD(T). The cubic and quartic force constants have been obtained by numerical derivatives computed from analytical quadratic force constants calculated by second-order Møller-Plesset perturbation theory, MP2. The quadratic force constants and the equilibrium structure of F2C NH have then been scaled by a global least-squares fitting procedure to the spectroscopic data and parameters experimentally determined for this molecule. This force field, obtained in the internal coordinates space and therefore valid for all isotopomers of difluoromethanimine, yields a complete set of spectroscopic molecular constants providing a critical assessment of the experimental rotational and centrifugal distortion constants, fundamentals, overtones, and combination bands determined so far for F2C NH. In addition, the final force field can be used to make predictions of all important vibrational and rotational parameters which should be accurate and useful for new spectroscopic investigations. 相似文献