排序方式: 共有37条查询结果,搜索用时 9 毫秒
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渐进因子分析—分光光度法测定Fe^3+—SCN^—络合物的稳定常数 总被引:2,自引:0,他引:2
本文利用渐进因子分析与化学平衡相结合的方法迭代求解逐级生成络合物的各级稳定常数,对Fe^3+-SCN^-体系在水溶液及50%丙酮溶液中的配体浓度-波长的两维双线性吸光度数据矩阵进行处理,求得水溶液中该络合物第一、二级稳定常数为1gk1=2.26,1gk2=1.30。同时该法还可确定各种组分的存在区间及吸收光谱,本文还对丙酮的存在对Fe^3+-SCN^-络合物的影响作了研究,结果表明丙酮,对高配位络 相似文献
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GC-MS与正交投影法或渐进窗口正交投影法用于羌活挥发油成分的测定 总被引:5,自引:0,他引:5
中药化学组成的定性定量测定是药物活性理论的基础,联用色谱及其相关的化学计量学方法为中药复杂体系的分离和分辨提供了强有力的工具.采用GC-MS法对传统中药羌活中的挥发油成分进行了分离测定,并对其中重叠色谱峰根据其重叠程度,采用迭代的正交投影法(OPA)和非迭代的渐进窗口正交投影法(EWOP)进行了分辨,得到每个组分的纯色谱和光谱曲线,共分辨出98个色谱峰,通过质谱库检索得到其中65个组分的定性定量结果,占总含量的92.13%. 相似文献
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Many social and biological networks consist of communities–groups of nodes within which links are dense but among which links are sparse. It turns out that most of these networks are best described by weighted networks, whose properties and dynamics depend not only on their structures but also on the link weights among their nodes. Recently, there are considerable interests in the study of properties as well as modelling of such networks with community structures. To our knowledge, however, no study of any weighted network model with such a community structure has been presented in the literature to date. In this paper, we propose a weighted evolving network model with a community structure. The new network model is based on the inner-community and inter-community preferential attachments and preferential strengthening mechanism. Simulation results indicate that this network model indeed reflect the intrinsic community structure, with various power-law distributions of the node degrees, link weights, and node strengths. 相似文献
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Inspired by scientific collaboration networks (SCN), especially our empirical analysis of econophysicists network, an evolutionary model for weighted networks is proposed. Besides a new vertex added in at every time step, old vertices can also attempt to build up new links, or to reconnect the existing links. The number of connections repeated between two nodes is converted into the weight of the link. This provides a natural way for the evolution of link weight. The path-dependent preferential attachment mechanism with local information is also introduced. It increases the clustering coefficient of the network significantly. The model shows the scale-free phenomena in degree and vertex weight distribution. It also gives well qualitatively consistent behavior with the empirical results. 相似文献
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We propose a new framework called Evolving Systems to describe the self-assembly, or autonomous assembly, of actively controlled dynamical subsystems into an Evolved System with a higher purpose. Autonomous assembly of large, complex flexible structures in space is a target application for Evolving Systems. A critical requirement for autonomous assembling structures is that they remain stable during and after assembly. The fundamental topic of inheritance of stability, dissipativity, and passivity in Evolving Systems is the primary focus of this research. In this paper, we develop an adaptive key component controller to restore stability in Nonlinear Evolving Systems that would otherwise fail to inherit the stability traits of their components. We provide sufficient conditions for the use of this novel control method and demonstrate its use on an illustrative example. 相似文献