Synthesis and photoluminescence characteristics of AlN nanocrystalline solids

A new condensed form of AlN nanocrystalline solids was obtained directly from reactions of metal Al and (NH₄Cl+NH₄I) in liquid ammonia at 550 °C, without the subsequent consolidation process as in the conventional method. The synthesized product is a transparent bulk solid, while the constituted nanocrystals have an average size of about 18 nm and possess the same wurtzite structure as bulk AlN. (NH₄Cl+NH₄I), which plays a role of a catalyst in the present synthetic route, is indispensable. The photoluminescence spectrum of the AlN nanocrystalline solids shows a broad blue band centered at 400 nm. Received: 20 June 2000 / Accepted: 22 June 2000 / Published online: 9 August 2000     

Photorefractive measurements on electron-irradiated semi-insulating GaAs

We present photorefractive measurements at 1.06 m and 1.3 m performed in electron-irradiated GaAs. Irradiation with electrons of kinetic energies 1 MeV introduces intrinsic electrically active defects which modify the Fermi-level position and allow to modify the electron-hole competition mechanism of the photorefractive effect. Furthermore, it is shown that the optical absorption in the 1.3–1.5 m spectral range can be increased, which might allow to enlarge the useful spectral range of GaAs towards optical telecommunication windows. The native and irradiation-induced defects are assessed by electron paramagnetic resonance and optical absorption spectroscopy conducted at T=300 K and 77 K. The direct influence of an irradiation-induced mid-gap defect on the photorefractive effect is experimentally and theoretically demonstrated.     

Reverse Monte Carlo simulations of an amorphous Cr25Nb75 alloy produced by mechanical alloying

The local atomic structure of an amorphous Cr₂₅Nb₇₅ alloy produced by mechanical alloying was determined using only one X-ray total structure factor S(K) as input data for reverse Monte Carlo simulations. The results showed that the amorphous alloy has a local atomic structure similar to that predicted by the additive hard sphere model for a Cr and Nb mixture with same composition of the alloy, and quite different of those found in the cubic and hexagonal Cr₂Nb crystals.     

Fabrication of surface relief gratings on transparent dielectric materials by two-beam holographic method using infrared femtosecond laser pulses

Fabrication of surface relief-type gratings in transparent dielectrics, which are hard to machine, has been achieved by a holographic technique using two infrared femtosecond (fs) pulses from a mode-locked Ti:sapphire laser. The present method can be applied for a variety of transparent dielectrics, Al₂O₃ (sapphire), TiO₂, ZrO₂, LiNbO₃, SiC, ZnO, CdF₂, MgO, CaF₂ crystals, and SiO₂ glass. It is found that the grating formation is due primarily to laser ablation processes. Planar surface relief gratings can be fabricated by colliding two fs laser pulses on the surface of substrates which move at a constant speed, synchronized with the laser repetition rate. Received: 1 March 2000 / Published online: 7 June 2000     

A biaxial nematic gel phase in aqueous vanadium pentoxide suspensions

Aqueous suspensions of V₂O₅ ribbons are one of the very few examples of mineral liquid crystals. In the concentrated regime, we show that these ribbons organize in a biaxial nematic gel phase. A Couette shear cell was used to produce a well oriented sample for in situ synchrotron X-ray scattering studies. We observed two perpendicular anisotropic sections of reciprocal space, which proves the biaxial symmetry of the nematic order. The thermodynamic and flow properties of the biaxial nematic are well described by hard-core theories. We suggest the use of a shear geometry to produce and investigate single domains of other biaxial nematics, reported but still questioned in the literature. Received 26 May 1999     

Structural evidence of charge renormalization in semi-dilute solutions of highly charged polyelectrolytes

We show experimentally that Manning counterion condensation also leads to a renormalization of the charge density at high concentrations of highly charged, flexible, hydrophilic polyelectrolytes. Investigations by small angle neutron and X-ray scattering of semi-dilute solutions of poly(acrylamide-co-sodium-2-acrylamido-2-methylpropane sulfonate) at different charge densities above the condensation threshold, show that the scattering function is invariant with the charge density. Received 16 June 1998     

Dynamic polarization potential of 12C+12C system at molecular-resonance energies

The nuclear reaction dynamics leading to the formation of recently discovered resonance in the mutual-0₂ ⁺ channel of the ¹²C+¹²C inelastic scattering around E _c.m.≃ 32 MeV is studied in terms of the dynamic polarization potential (DPP) induced by the channel coupling among various excited states in ¹²C. The microscopic 3α cluster-model wave functions are used to generate the ¹²C−¹²C diagonal and coupling potentials in the double-folding model. It is found that DPP for the 0₂ ⁺+ 0₂ ⁺ channel is an unusually strong attractive potential which even exceeds the zeroth-order folding-model potential of this channel around the nuclear surface region and that the strong coupling between the 0₂ ⁺ and 2₂ ⁺ states is predominantly responsible for the unusual DPP in this channel. The effective potential, the sum of the original folding-model potential and the attractive DPP, is found to generates resonance states in the same energy region as that of the resonance states generated by the original folding-model potential but the former states are found to be higher-nodal states having four additional radial nodes. Similar but more moderate property of DPP is also found in the entrance (elastic) channel. These results suggest that the reaction dynamics of generating the resonance in the ¹²C(0₂ ⁺) +¹²C(0₂ ⁺) channel may rather differ from that of the simple crossing of the zeroth-order molecular band generated by the potentials in the entrance and exit channels suggested by the standard band-crossing model. Received: 17 December 1998 / Revised version: 1 March 1999     

Electronic structure and impurity states in GaN quantum dots

We study the electronic structure of spherical GaN quantum dots (QD's) with a substitutional acceptor impurity at the center. The size-dependent energy spectra are calculated within the sp³s* tight-binding model, which yields a good agreement with the confinement-induced blue shifts observed in undoped QD's. The acceptor binding energy is strongly enhanced in a QD and decreases with increasing size following a scaling law that extrapolates to the bulk experimental value. The size-dependent average radius of the hole orbit is also calculated. The results are in agreement with the available experimental data for Mg impurity in bulk GaN.     

Equation of state of aluminum carbide Al4C3

Quasi-hydrostatic compression of aluminum carbide, Al₄C₃ has been studied to 6 GPa at room temperature using energy-dispersive X-ray powder diffraction with synchrotron radiation. A fit of the experimental p-V data to the Birch equation of state yields the values of the bulk modulus, B₀, of 130(5) GPa and the first pressure derivative of the bulk modulus, B′₀, of 4.6(9). The compression is found to be anisotropic, with the a-axis being more compressible than the c-axis.